Multilayer Separator-Driven Interface Stabilization and Dendrite Suppression for Long-Cycling Lithium Metal Batteries

Published: Jan. 1, 2025

Language: Английский

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Covalently anchoring silsesquioxanes layer onto fiber separator for high-rate-charging and long-cycling lithium metal battery

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 120, P. 116413 - 116413

Published: April 2, 2025

Language: Английский

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Erecting Stable Lithium Metal Batteries: Comprehensive Review and Future Prospects

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Abstract As the global energy structure transforms and renewable rapidly develops, rechargeable batteries are increasingly focus on high density, rapid charge/discharge rates, enhanced safety performance, particularly in extreme environments. Lithium metal (LMBs) have emerged as a significant research area recent years owing to capacity low electrochemical potential of lithium (Li). However, challenges, uncontrolled Li dendrite growth, unstable solid electrolyte interface separator puncture/interface incompatibility, greatly impact battery life lead failure, thus impeding commercialization. This review presents thorough analysis key challenges facing stable LMBs from multiple perspectives, alongside regulatory strategies. The methods include anode, interface, solid/liquid electrolytes, separators, pressure artificial intelligence. An in‐depth discussion operational mechanism, advantages/drawbacks is provided. Additionally, it offers succinct overview anticipated future trends challenges. A comprehensive numerous documents studies has been conducted summarize number published papers unique characteristics corresponding provides valuable recommendations for practical application other high‐energy‐density (Sodium, Potassium, Magnesium, Zinc), thereby contributing effectively implementation national strategic planning new sector.

Language: Английский

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Multilayer Separator-Driven interface stabilization and dendrite suppression for Long-Cycling lithium metal batteries

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 693, P. 137586 - 137586

Published: April 12, 2025

Language: Английский

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Unveiling Mechanistic Material Manipulation in Functional Separators for Metal Sulfur Batteries: Progress and Prospects

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

Abstract Metal‐sulfur batteries (MSBs) are emerging energy storage candidates due to their high density, cost‐effective nature, and environmental compatibility. However, polysulfide shuttling, slow kinetics, dendritic issues severely plague nexus stage from academic commercial applications. Inspired by the low cost higher capacity of metal sulfur batteries, numerous strategies, electrode design separator modification, developed eliminate these challenges on practical grounds. Among them, functionalizing separators hold great promise stabilize battery operation mechanistically in terms safety, stability, electrochemical benchmarks, as existing polyolefin designs cannot fully satisfy complex chemistry polysulfides. This review first discusses critical with associated mechanistic approaches better describe requirement for material manipulation design. Furthermore, role modulated functional materials is critically highlighted screened synergistically achieve an advanced recent four‐year plethora separators. Finally, future directions outlined research. will offer a comprehensive reference new paths designing modulating advancing high‐energy‐density systems.

Language: Английский

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Transport Kinetics: A New Perspective on Failure of Garnet Solid Electrolytes

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Abstract Solid‐state rechargeable lithium‐metal batteries with garnet‐type (Li 7 La 3 Zr 2 O 12 ) solid electrolytes (SEs) represent promising candidates of the next‐generation high‐energy yet their practical use are hindered by a short cycle life usually due to dendrite nucleation and penetration through garnet. In previous works, is ascribed poor wettability Li metal at alkaline‐residue‐covered garnet surface, high electronic conductivity that invites + ‐electron recombination grain boundary. this work, it showed constructing mathematical model on residue‐free particles, size has profound influence transport kinetics, therefore, nucleation. Smaller grains tend show faster in bulk they also involve higher flux diffusing across boundaries Li‐garnet interface, which considered kinetically more sluggish. As result, Li‐ions accumulate boundary accounts for unstable local environment sharply reduced electron migration barrier, together invite Based findings, new asymmetric SE proposed features ionic suppression ability.

Language: Английский

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Polypropylene oxide-modified cellulose separators for high-rate Na+ transport via a dual-pathway mechanism in sodium-ion batteries

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162839 - 162839

Published: April 1, 2025

Language: Английский

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Integrated design of polysulfide shuttling and lithium dendrite suppressing framework: In2O3-In2S3 embedded carbon cloth for lithium-sulfur full batteries

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161241 - 161241

Published: March 1, 2025

Language: Английский

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One-step pyrolysis route to N, O, S co-doped hierarchical carbon as multi-functional separator for lithium-sulfur batteries

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177268 - 177268

Published: Oct. 1, 2024

Language: Английский

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A polysulfides adsorption strategy through cation-anion interactions for achieving high-safety lithium-sulfur batteries in multiple scenarios

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 500, P. 157314 - 157314

Published: Nov. 1, 2024

Language: Английский

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