Designing catalysts to formic acid oxidation reaction: From nanoscale to single atoms DOI
Jiaxin Gong,

Shouyao Hu,

Yu Xiong

et al.

Journal of Central South University, Journal Year: 2024, Volume and Issue: 31(12), P. 4586 - 4600

Published: Dec. 1, 2024

Language: Английский

Preparation of Pd(Mo2C) composites by palladium deposition under open-circuit conditions, their corrosion resistance and catalytic activity DOI
В. В. Кузнецов,

B. I. Podlovchenko,

Д. А. Ханин

et al.

Journal of Electroanalytical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 118913 - 118913

Published: Jan. 1, 2025

Language: Английский

Citations

0
Recent advances in platinum group metallenes: From synthesis to energy-related electrocatalytic application DOI

Zi‐Han Yuan,

Tianjiao Wang,

Bin Sun

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125041 - 125041

Published: Jan. 1, 2025

Language: Английский

Citations

0
P-d orbital hybridization and lattice strain induced by B,Co-co-doped Cu promote the electrocatalytic nitrate reduction to Ammonia DOI

Qianling Wei,

Yuexuan He,

Guopeng Ding

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161014 - 161014

Published: Feb. 1, 2025

Language: Английский

Citations

0
Symmetric bimetallic active sites Prussian blue catalysts for photo-reforming biomass to formic acid DOI Creative Commons
Junming Shi, Can Jin, Shuai Chen

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2025, Volume and Issue: 8(2)

Published: March 1, 2025

Language: Английский

Citations

0
In situ transformation of Pd to metal–metalloid alloy Pd2B for alkyne semi-hydrogenation DOI Creative Commons

Shuaiwen Xu,

Lei Wang, Pengfei Tian

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(9), P. 6847 - 6853

Published: Jan. 1, 2025

Transformation of Pd to 2 B enhances the selectivity alkene for alkyne hydrogenation.

Language: Английский

Citations

0
Effect of the built-in electric field in Pd/PdO-SnO2 hollow nanosphere electrocatalyst for formic acid electrooxidation DOI
Anders Lei, Binbin Fan, Yongjin Zou

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106239 - 106239

Published: March 1, 2025

Language: Английский

Citations

0
Efficient Photogenerated Carrier‐Assisted COads Removal via Schottky Barrier of PdSn/WO3 for Formic Acid Oxidation Reaction DOI
Wenhao Lu, Tingting Du, Shijie Jia

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: April 27, 2025

Abstract Limiting the formation of CO adsorbed species (CO ads ) or promoting its removal during formic acid oxidation reaction (FAOR) is essential to improving activity and stability Pd‐based catalysts. In this work, an innovative strategy proposed adjust Schottky barrier height (SBH) through band structure design for effective utilization photogenerated carriers remove , thereby FAOR performance Specifically, electronic Pd adjusted by loading on WO 3 nanosheets incorporating different amounts Sn reduce Fermi level pinning SBH. The accelerated migration electrons promotes accumulation holes valence . constructed effectively regulates catalyst optimizes adsorption energy intermediate CO, thus inhibiting indirect pathway. Therefore, optimal 1 /WO provides higher efficiency carrier‐assisted electrocatalytic FAOR, with a mass 2262.3 mA mg −1 outperforming most This work offers novel approach designing catalysts, combining modulation carrier assistance advance performance.

Language: Английский

Citations

0
Constructing Palladium‐Based Crystalline@Amorphous Core–Shell Heterojunctions for Efficient Formic Acid Oxidation DOI Creative Commons
Hui-Ling Li,

Jingkun Yu,

Yongming Sui

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: April 30, 2025

Constructing crystalline@amorphous heterostructures allows nanomaterials to maintain high electrical conductivity of crystalline structures while acquiring abundant active sites from amorphous structure. This emerging strategy has attracted considerable attention in electrochemical and photoelectrochemistry applications. However, achieving based on palladium (Pd) remains challenging due the difficulties balancing transformation between these two phases. Here, a feasible is developed manufacture Pd-based core-shell through non-metallic element doping. The obtained exhibit outstanding catalytic performance for formic acid oxidation (FAO) with mass activity up 2.503 A mg-1 Pd. Detailed theoretical experimental analyses reveal that construction increase surface sites, lowers energy barrier, enhances selectivity direct pathway, thereby effectively facilitating FAO process. work demonstrates feasibility constructing efficient catalysts using provides new platform platinum-group metals (PGMs) crystalline-amorphous heterostructures.

Language: Английский

Citations

0
Exclusive Formate Reaction Route over Pd/NiN4Cl for High-Performance Formic Acid Oxidation DOI
Xuewen Zhao,

Chenjia Liang,

Xiaoxia Hou

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: April 7, 2025

Language: Английский

Citations

0
Activating colloidal synthesized Au catalyst by the electrochemical strategy: Gas atmosphere, electrolyte and electrochemical technique DOI

Rui Xu,

Yunxia Li,

Kaimin Du

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 569, P. 114548 - 114548

Published: Sept. 16, 2024

Language: Английский

Citations

1