Chemical Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 26, 2024
Organic
photoelectrochemical
transistor
(OPECT)-based
sensors
that
use
light-sensitive
semiconductor
materials
as
the
gate
have
recently
garnered
increasing
interest
in
various
fields
ranging
from
biological
analysis
to
environmental
monitoring.
Excessive
hole-accumulation-induced
photocorrosion
is
considered
a
key
factor
that
limits
the
activity
of
photoelectrochemical
water
splitting
reaction.
In
this
study,
heterogeneous
catalyst
was
prepared
by
simple
impregnation
method,
i.e.,
modification
different
ratios
heterometallic
oxyhydroxides
(FexCo1-xOOH)
on
in
situ
photoreduction-treated
BiVO4
(Bi-BVO).
This
work
demonstrates
for
first
time
adjusting
FeCo
ratio
can
greatly
enhance
separation,
transport,
and
directional
control
electron-hole
pairs,
thus
inhibiting
photocorrosion.
The
Bi-BVO/Fe0.7Co0.3OOH
composite
exhibited
photocurrent
density
0.243
mA
cm-2
at
1.23
VRHE
(4.5
times
pure
under
1.5
G
AM
illumination)
sacrificial
agent-free
Na2SO4
electrolyte.
After
20
h
continuous
illumination,
optimized
samples
showed
negligible
attenuation
(7.2%).
strong
stability
light
conditions
be
attributed
to
Fe
Co
acting
as
hole
shuttling
mediators,
which
efficiently
match
generation
rate
Bi-BVO
transport
surface
active
sites.
Furthermore,
formation
Co-O-V
bonds
passivation
states,
immobilize
V5+
lattice,
further
inhibit
bimetallic
oxyhydroxide
strategy
provides
valuable
insights
into
mitigating
offers
an
optimization
approach
splitting.
Processes,
Journal Year:
2024,
Volume and Issue:
12(8), P. 1765 - 1765
Published: Aug. 21, 2024
To
address
the
problem
of
suboptimal
performance
in
deep
eutectic
solvents
displayed
by
traditional
TiO2
photoelectrodes
and
Cu2O
that
have
undergone
simplistic
modifications
result
a
mismatch
with
battery
discharge
capacity,
method
combining
hydrothermal
dip-coating
techniques
was
developed
to
create
Fe2O3-CuO
heterojunction
structure
on
FTO
surface.
Then,
impact
solar
flow
batteries
investigate
this
study.
The
experimental
findings
reveal
formation
effectively
mitigates
recombination
rate
photogenerated
carriers
within
photoelectrode.
Furthermore,
meticulously
adjusting
CuO
loading,
harmonious
balance
between
charging
discharging
currents
achieved,
thereby
enhancing
overall
redox
batteries.
In
comparison
standalone
Fe2O3
photoelectrodes,
innovative
approach
significantly
broadens
spectrum
sunlight
utilization.
Notably,
fabricated
Fe2O3/CuO-2
photoelectrode
demonstrates
remarkable
photocharging
performance,
far
surpassing
both
commercial
photoelectrodes.
Specifically,
boosts
an
average
current
density
598.68
μA∙cm−2,
its
being
2.74
5.15
larger,
respectively,
than
Chemical Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 26, 2024
Organic
photoelectrochemical
transistor
(OPECT)-based
sensors
that
use
light-sensitive
semiconductor
materials
as
the
gate
have
recently
garnered
increasing
interest
in
various
fields
ranging
from
biological
analysis
to
environmental
monitoring.