Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 9, 2024

Rechargeable lithium metal batteries (LMBs) are promising next-generation energy storage systems due to their high theoretical density. However, practical applications hindered by dendrite growth and various intricate issues associated with the cathodes. These challenges can be mitigated using organosulfur-based mediators (OSMs), which offer advantages of abundance, tailorable structures, unique functional adaptability. features enable rational design targeted functionalities, enhance interfacial stability anode cathode, accelerate redox kinetics electrodes via alternative reaction pathways, thereby effectively improving performance LMBs. Unlike extensively explored field organosulfur cathode materials, OSMs have garnered little attention. This review systematically summarizes recent advancements in for LMB systems, including lithium-sulfur, lithium-selenium, lithium-oxygen, lithium-intercalation batteries, other systems. It briefly elucidates operating principles these regulatory mechanisms corresponding OSMs, fundamentals activity. Ultimately, strategic optimizations proposed designing novel advanced mechanism investigation, expanded applications, development safe battery providing directions narrow gap between modulation compounds implementation batteries.

Language: Английский