Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 2, 2025
Growing
global
population,
escalating
energy
consumption,
and
climate
change
threaten
future
security.
Fossil
fuel
combustion,
primarily
coal,
oil,
natural
gas,
exacerbates
the
greenhouse
effect
driving
warming
through
CO
Dalton Transactions,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
MIL-100(Fe)/TiO
2
/CoO
x
was
synthesized
through
a
facile
microwave-assisted
hydrothermal
method
followed
by
atomic
layer
deposition
and
exhibits
exceptional
photocatalytic
OER
performance.
Molecules,
Journal Year:
2025,
Volume and Issue:
30(5), P. 1127 - 1127
Published: Feb. 28, 2025
The
global
imperative
for
clean
energy
solutions
has
positioned
photocatalytic
water
splitting
as
a
promising
pathway
sustainable
hydrogen
production.
This
review
comprehensively
analyzes
recent
advances
in
TiO2-based
systems,
focusing
on
materials
engineering,
source
effects,
and
scale-up
strategies.
We
recognize
the
advancements
nanoscale
architectural
design,
engineered
heterojunction
of
catalysts,
cocatalyst
integration,
which
have
significantly
enhanced
efficiency.
Particular
emphasis
is
placed
crucial
role
chemistry
system
performance,
analyzing
how
different
sources-from
wastewater
to
seawater-impact
evolution
rates
stability.
Additionally,
addresses
key
challenges
scaling
up
these
including
optimization
reactor
light
distribution,
mass
transfer.
Recent
developments
artificial
intelligence-driven
discovery
process
are
discussed,
along
with
emerging
opportunities
bio-hybrid
systems
CO2
reduction
coupling.
Through
critical
analysis,
we
identify
fundamental
propose
strategic
research
directions
advancing
technology
toward
practical
implementation.
work
will
provide
comprehensive
framework
exploring
advanced
composite
developing
efficient
scalable
multifunctional
simultaneous
Inorganic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 7, 2025
MOF@CeO2
composites
with
good
interfacial
compatibility
have
garnered
significant
attention
in
the
field
of
third-order
nonlinear
optics
(NLO).
However,
interaction
between
MOFs
and
CeO2
is
commonly
weak,
which
severely
weakens
NLO
properties
composites.
In
this
study,
we
chose
parent
Zn-MOF
({[Zn(BPAN)0.5(ndcpa)]·DMA·H2O}n)
(BPAN
=
9,10-bis(4-pyridyl)anthracene
H2ndcpa
naphthalene-2,6-dicarboxylicacid)
synthesized
bimetallic-MOFs
(ZnNi-MOF
ZnCo-MOF)
by
solvent-assisted
metal-ion
exchange.
The
defect
sites
originating
from
exchange
make
interface
bimetallic-MOF@CeO2
(ZnNi-MOF@CeO2
ZnCo-MOF@CeO2)
stronger.
results
indicate
display
enhanced
reverse
saturable
absorption
self-defocusing
refraction
compared
to
Zn-MOF@CeO2,
can
be
attributed
efficient
charge
transfer
at
interfaces.
Transient
spectra
theoretical
calculation
revealed
that
significantly
reduced
energy
loss,
electron
efficiency,
positively
modulated
properties.
This
study
provides
new
insights
methodologies
for
design
development
novel
