Incorporation of Organic Benzoquinone Framework Into rGO via Strong π–π Interaction for High‐Performance Aqueous Ammonium‐Ion Battery DOI
Xinlei Tang, Shuyan Zhang,

Haohao Sun

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Abstract Aqueous ammonium‐ion batteries (AAIBs) are promising candidates for next‐generation energy storage devices. However, organic materials as suitable anodes face severe challenges due to their structural instability and poor conductivity, which hinder the development of AAIBs. Herein, an innovative approach is introduced by incorporating benzoquinone framework, 5,7,11,14‐tetraaza‐6,13‐pentacenequinone (TAPQ), with reduced graphene oxide (rGO) using a solvent exchange method. Benefiting from π – interaction electron delocalization, TAPQ/rGO features enhanced cycling stability ion/electron transportation. Consequently, composite electrode delivers reversible capacity 181.7 mAh g −1 at 0.5 A achieves ultrahigh retention 94.5% over 10 000 cycles 5 , surpassing most reported in Combining density functional theory (DFT) calculation ex situ electrochemical characterizations, unique mechanism chelation coordination between NH 4 + N, O revealed. Furthermore, high‐performance ‐based full cell, assembled anode copper hexacyanoferrate (Cu‐HCF) cathode, demonstrates long‐term 93.95% after 500 cycles. This work pioneers concept interactions significantly improve performance, presenting novel strategy advancement AAIBs research.

Language: Английский

Advanced Polymeric Binders in Aqueous Zinc Ion Batteries: Dynamic Diselenide Bonds as Unique Cofactors for Improving Redox Kinetics DOI
Xiaoyan Feng,

Xuewu Gao,

Xiaoyu Zhou

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Aqueous zinc ion batteries (AZIBs) show significant advantages in the field of current energy storage. This work has focused on binder, which is one components cathode, enhances electrochemical behavior sustainable high-capacity batteries. The polyurea-containing diselenide or disulfide units have been synthesized as a binder for AZIBs, are named PICSe and PICS. Compared with PVDF, critical contents polyurea binders diselenide/disulfide units, act cofactors to coordinate cation charge carriers, facilitate Zn2+ transfer, improve redox kinetics. Furthermore, achieve physical cross-linking through free-radical-mediated mechanisms hydrogen bonding interactions, result high mechanical properties cathodes. Therefore, resultant AZIBs based that discharge specific capacity can be stabilized at about 100 mA h g–1 after 500 cycles 1 C, retention rate 84.9%.

Language: Английский

Citations

0
Towards ultra-stable aqueous zinc-ion batteries via electrochemical polymerization of phthalimido-anchored benzoquinone DOI
Dan Wang, Yuxuan Bai,

ZIQING zhou

et al.

Green Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Phthalimido anchored benzoquinone is selected as monomer for electropolymerization to fabricate the cathode of aqueous ZIBs with ultralong cycling stability.

Language: Английский

Citations

0
Fabrication of Phthalocyanine Polymers with Abundant Nitrogen Active Sites as the Cathode Materials for Aqueous Zinc-Organic Batteries DOI
Shuai Yan, Zhonglin Li,

Yongyao Liu

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: 6(20), P. 12823 - 12831

Published: Oct. 9, 2024

Phthalocyanine (Pc), a macrocyclic aromatic compound, has attracted extensive attention in energy storage due to its large π-conjugated structure and abundant nitrogen sites. However, the poor solubility of Pc monomers leads rigorous polymerization conditions, which hinder application development Pc-based polymers. Herein, 1,4,5,8,9,11-hexaazatriphenylenehexacarbonitrile (HAT(CN)6) is used as precursor construct conjugated polymers (Pc-COPs) via molten salt assisted strategy. The physical–chemical properties resulting Pc-COPs at different synthesis temperatures were systematically studied, indicates that Pc-COP-350 (at temperature 350 °C) exhibits complete while maintaining redox activity active centers. As cathode material for aqueous zinc-ion batteries, exhibited best electrochemical performance, achieving specific capacity 269 mA h g–1 0.05 A g–1. Coulombic efficiency up nearly 100% even after long cycles current density 1 This work provides pathway designing synthesizing compounds.

Language: Английский

Citations

1
In Situ Electrochemical Polymerized Bipolar-Type Poly(1,5-diaminonaphthalene) Cathode for High-Performance Aqueous Zinc-Organic Batteries DOI
Yanrong Wang, Chenxi Zheng,

Mengfan Zhao

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Language: Английский

Citations

1
Stable Radical Polymers as New Electroactive Materials: Synthesis, Properties, and Emerging Applications DOI Creative Commons

Yufeng Xiong,

Yingjiang Li, X. Z. Cui

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 15, 2024

Abstract Extensive research over recent decades has demonstrated the feasibility of producing stable radical polymers (SRPs) by exploring structure–stability relationships. Owing to their excellent redox activities and inherent paramagnetic characteristics, SRPs are emerging as key functional materials with considerable potentials for various applications such in organic electrodes, semiconductors, magnetic materials, quantum information technologies. Accordingly, this review provides a comprehensive summary most widely investigated representative families SRPs. Innovative strategies design synthesis relationship among physicochemical properties, electronic structures, resulting functionalities these discussed. Moreover, advancements highlighted. Finally, challenges chemistry material functionalization, offering insights into transformative potential future applications, emphasized.

Language: Английский

Citations

0
Incorporation of Organic Benzoquinone Framework Into rGO via Strong π–π Interaction for High‐Performance Aqueous Ammonium‐Ion Battery DOI
Xinlei Tang, Shuyan Zhang,

Haohao Sun

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Abstract Aqueous ammonium‐ion batteries (AAIBs) are promising candidates for next‐generation energy storage devices. However, organic materials as suitable anodes face severe challenges due to their structural instability and poor conductivity, which hinder the development of AAIBs. Herein, an innovative approach is introduced by incorporating benzoquinone framework, 5,7,11,14‐tetraaza‐6,13‐pentacenequinone (TAPQ), with reduced graphene oxide (rGO) using a solvent exchange method. Benefiting from π – interaction electron delocalization, TAPQ/rGO features enhanced cycling stability ion/electron transportation. Consequently, composite electrode delivers reversible capacity 181.7 mAh g −1 at 0.5 A achieves ultrahigh retention 94.5% over 10 000 cycles 5 , surpassing most reported in Combining density functional theory (DFT) calculation ex situ electrochemical characterizations, unique mechanism chelation coordination between NH 4 + N, O revealed. Furthermore, high‐performance ‐based full cell, assembled anode copper hexacyanoferrate (Cu‐HCF) cathode, demonstrates long‐term 93.95% after 500 cycles. This work pioneers concept interactions significantly improve performance, presenting novel strategy advancement AAIBs research.

Language: Английский

Citations

0