Ionic liquid-integrated aqueous electrolyte regulation on solvation chemistry and electrode interface for reversible dendrite-free zinc anodes DOI
Huijuan Guo, Xiaojiang Chen, Rui Shu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 627 - 636

Published: Aug. 30, 2024

Language: Английский

Stress Release of Zincophilic N‐Doped Carbon@Sn Composite on High‐Curvature Surface of Zinc Foam for Dendrite‐Free 3D Zinc Anode DOI Open Access
Yunhui Lin, Lin Fang, Ming Zhang

et al.

Small Methods, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Abstract Commercial 3D zinc foam anodes with high deposition space and ion permeation have shown great potential in aqueous batteries. However, the local accumulated stress from its high‐curvature surface exacerbates Zn dendrite issue, leading to poor reversibility. Herein, we employed zincophilic N‐doped carbon @ Sn composites (N‐C@Sn) as nano‐fillings effectively release of curvature foams toward dendrite‐free anode battery (AZIB). These electronegative conductive N‐C@Sn supporters can provide a highly channel for initial nucleation reduce current density regulating deposition. Uniform further assists homogenous distribution on platting surface, which gives positive feedback loop improve As result, composite (ZCSn Foam) symmetric cell achieves long cycle lifespan 1100h at 0.5 mA cm −2 , much more than that Foam (∼80 h lifespan). The full ZCSn Foam||MnO 2 exhibits remarkable reversibility 67% retention after 1000 cycles 0.8 A g −1 76% 1600 Ag . This 3D‐constructing strategy may offer promising practical pathway metal application.

Language: Английский

Citations

1
In situ engineering of a glutathione-derived hydrophobic layer for durable and dendrite-free Zn anodes DOI

Mengxi Bai,

Qiufen Li, Xiang Wang

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137430 - 137430

Published: March 1, 2025

Language: Английский

Citations

0
Interfacial micro-electric field induced by phosphorus-doped g-C3N4 for highly reversible dendrite-free zinc metal anode DOI
Ya Xiao, Tongming Su, Tian Wang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162391 - 162391

Published: April 1, 2025

Language: Английский

Citations

0
Quaternary Alloy Interfaces for Stable Zinc Anodes for High‐Performance Aqueous Zinc‐Ion Batteries With Long‐Term Cycling Stability DOI
Xin Yan,

Yunnian Ge,

Huanhuan Xie

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: May 2, 2025

Abstract Aqueous zinc‐ion batteries (AZIBs) have emerged as a promising energy storage solution owing to their intrinsic safety, low cost, environmental friendliness, and high theoretical specific capacity. However, practical application is hindered by uncontrollable dendrite growth side reactions at the zinc metal anode. To address these challenges, simple cost‐effective electrodeposition strategy proposed construct quaternary Zn‐Cu‐Sn‐Bi alloy artificial interface layer on foil (ZCSB@Zn) anode of AZIBs. Density functional theory (DFT) calculations in situ optical observation confirm that this dense reduces migration barrier weakens hydrogen adsorption, facilitating uniform deposition while effectively suppressing formation. The symmetric ZCSB@Zn cell exhibits extraordinary cycle stability exceeding 8000 h. Furthermore, assembled ZCSB@Zn//CSB‐MnO 2 full demonstrates capacity 199 mAh g −1 1 A , maintaining even under loading 10 mg cm −2 temperature conditions (50 °C). This study presents scalable for constructing layers anodes, highlighting potential AZIB applications.

Language: Английский

Citations

0
In situ constructing artificial interfacial layer enables dendrite-free zinc anode in aqueous batteries DOI
Canglong Li, Changding Wang, Jie Huang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163458 - 163458

Published: May 1, 2025

Language: Английский

Citations

0
Bifunctional Ion Rectification Layer Separators Toward Superior Reversible Dendrite‐Free Zinc Metal Anodes DOI
Jia Yao, Jingying Li, Chi Chen

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 28, 2024

Abstract The slow transport dynamics and poor dendritic growth significantly hinder the performance of zinc metal batteries. Here, a unique difunctional ion rectification strategy is developed using vacuum evaporation technology to design coated separator for efficient transport. highly conductive Cu‐coated acts as an redistributor, ensuring homogenized electric field distribution. excellent znophilicity copper coating accelerator, promoting facilitating face‐to‐face deposition on separator. Consequently, this synergy enables stable battery operation at high current densities (cumulative capacity up 10 800 mAh cm −2 8 mA ) depth discharge (over 200 h 94% DOD). exhibits reversible plating/stripping life over 2400 with average coulombic efficiency 99.88%. Notably, enhances rate cycle Zn||V 6 O 13 Zn||MnO 2 full cells. This functional presents promising solution challenge anodes.

Language: Английский

Citations

2
Stabilization strategies for zinc anode interfaces under high discharge depth DOI
Ruoyu Wang, Yong Jia,

Zimeng Kong

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 105, P. 114642 - 114642

Published: Nov. 20, 2024

Language: Английский

Citations

0
Ionic liquid-integrated aqueous electrolyte regulation on solvation chemistry and electrode interface for reversible dendrite-free zinc anodes DOI
Huijuan Guo, Xiaojiang Chen, Rui Shu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 627 - 636

Published: Aug. 30, 2024

Language: Английский

Citations

0