Molten Salt Synthesis of Single-Crystalline Sr2MgSi2O7: Eu2+, Dy3+ Nanoplates: Breaking the Afterglow-Size Trade-off DOI
Lang Pei,

Yingqiang Yu,

Zhanfeng Ma

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

Sr2MgSi2O7/Eu2+, Dy3+ (SMSED) phosphors show promise for persistent luminescence applications due to their long afterglow and robust chemical stability. However, a trade-off exists between achieving precise size shape control of SMSED maintaining prolonged intensity duration during synthesis. Herein, we unveil molten-salt method that successfully produces uniform single-crystalline plate-like the first time. This synthesis significantly reduces both sintering temperature time compared classic solid-state reaction (SSR) method. Owing nanoplates structure, distribution, single-crystal nature, resulting exhibited excellent performance thermal stability, with sustained blue exceeding 24 h retaining >70% its initial up 523 K, outperforming most reported phosphors. These remarkable properties underscore considerable potential in fingerprint detection. work unlocks new synthetic frontier controllable phosphors, paving way future optimizations aimed at development advanced luminescent

Language: Английский

Multicolor Rare‐Earth Film with Ultra‐Long Afterglow for Diverse Energy‐Saving Applications DOI Open Access
Xinyi Lin,

Hui Han,

Meifang Yang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Abstract Rare‐earth afterglow materials, with their unique light‐storage properties, show great promise for diverse applications. However, broader applicability is constrained by challenges such as poor solvent compatibility, limited luminescent efficiency, and monochromatic emissions. In this study, these limitations are addressed blending ZnS various rare‐earth phosphors including (Sr 0.75 Ca 0.25 )S:Eu 2+ ; SrAl 2 O 4 :Eu , Dy 3+ Sr MgSi 7 to modulate deep trap mechanisms significantly enhance both the light capture capabilities. Using electrospinning, a large‐area (0.4 m × 3 m) film successfully fabricated tunable colors an extended duration exceeding 30 h. This demonstrates thermoluminescence, enabling potential integration into fire‐rescue protective clothing enhanced emergency visibility. greenhouse settings, it effectively supports chlorophyll synthesis optimizes conditions plant growth over 24‐h cycle. For tunnel garage applications, captures stores from vehicle headlights at distances of up 70 meters. The scalability cost‐effectiveness underscore its considerable real‐world applications across multiple fields, marking significant advancement in sustainable illumination technology.

Language: Английский

Citations

0
Molten Salt Synthesis of Single-Crystalline Sr2MgSi2O7: Eu2+, Dy3+ Nanoplates: Breaking the Afterglow-Size Trade-off DOI
Lang Pei,

Yingqiang Yu,

Zhanfeng Ma

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

Sr2MgSi2O7/Eu2+, Dy3+ (SMSED) phosphors show promise for persistent luminescence applications due to their long afterglow and robust chemical stability. However, a trade-off exists between achieving precise size shape control of SMSED maintaining prolonged intensity duration during synthesis. Herein, we unveil molten-salt method that successfully produces uniform single-crystalline plate-like the first time. This synthesis significantly reduces both sintering temperature time compared classic solid-state reaction (SSR) method. Owing nanoplates structure, distribution, single-crystal nature, resulting exhibited excellent performance thermal stability, with sustained blue exceeding 24 h retaining >70% its initial up 523 K, outperforming most reported phosphors. These remarkable properties underscore considerable potential in fingerprint detection. work unlocks new synthetic frontier controllable phosphors, paving way future optimizations aimed at development advanced luminescent

Language: Английский

Citations

0