Review on MXenes-Based Electrocatalysts for High-Energy-Density Lithium–Sulfur Batteries DOI Creative Commons

Xintao Zuo,

Yanhui Qiu,

Mengmeng Zhen

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: April 10, 2025

Abstract Lithium–sulfur batteries (LSBs) hold significant promise as advanced energy storage systems due to their high density, low cost, and environmental advantages. However, despite recent advancements, practical density still falls short of the levels required for commercial viability. The is critically dependent on both sulfur loading amount electrolyte used. High-sulfur coupled with lean conditions presents several challenges, including insulating nature Li 2 S, insufficient absorption, degradation cathode structure, severe lithium polysulfide shuttling, slow redox reaction kinetics, instability metal anode. MXenes-based materials, metallic conductivity, large polar surfaces, abundant active sites, have been identified promising electrocatalysts improve reactions in LSBs. This review focuses significance challenges associated high-sulfur electrolytes LSBs, highlighting advancements aimed at optimizing cathodes anodes. It provides a comprehensive discussion MXenes materials substrates goal enhancing understanding regulatory mechanisms that govern conversion plating/stripping behavior. Finally, explores future opportunities electrocatalysts, paving way application

Language: Английский

Lightweight Materials for High Energy Density Lithium–Sulfur Batteries DOI Open Access

Yifan Li,

Zhengran Wang,

Qi Zhang

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 28, 2025

Abstract At present, electronic devices such as electric vehicles and mobile phones have increasing requirements for battery energy density. Lithium–sulfur batteries (LSBs) a high theoretical density are considered potential choice realizing the next generation of (2600 W h kg −1 ) batteries. However, actual LSBs is much lower than due to poor conductivity sulfur, serious LiPSs shuttle, low sulfur utilization, so on. Many lightweight materials characterized by surface area designability. The reasonable design modify can reduce proportion inactive substances optimizing electrochemical performance, which crucial improving LSBs. few reviews discuss effect on from perspective whole system. Herein, application in six aspects: liquid electrolyte, solid cathode, anode, separator, current collector discussed. significance use further improvement summarized prospected.

Language: Английский

Citations

0

Review on MXenes-Based Electrocatalysts for High-Energy-Density Lithium–Sulfur Batteries DOI Creative Commons

Xintao Zuo,

Yanhui Qiu,

Mengmeng Zhen

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: April 10, 2025

Abstract Lithium–sulfur batteries (LSBs) hold significant promise as advanced energy storage systems due to their high density, low cost, and environmental advantages. However, despite recent advancements, practical density still falls short of the levels required for commercial viability. The is critically dependent on both sulfur loading amount electrolyte used. High-sulfur coupled with lean conditions presents several challenges, including insulating nature Li 2 S, insufficient absorption, degradation cathode structure, severe lithium polysulfide shuttling, slow redox reaction kinetics, instability metal anode. MXenes-based materials, metallic conductivity, large polar surfaces, abundant active sites, have been identified promising electrocatalysts improve reactions in LSBs. This review focuses significance challenges associated high-sulfur electrolytes LSBs, highlighting advancements aimed at optimizing cathodes anodes. It provides a comprehensive discussion MXenes materials substrates goal enhancing understanding regulatory mechanisms that govern conversion plating/stripping behavior. Finally, explores future opportunities electrocatalysts, paving way application

Language: Английский

Citations

0