Synergistic Effects in the Electrochemical Carbon Dioxide Reduction Reaction for Multi‐Carbon Product Formation DOI

Xiaoqin Xu,

Jingqi Guan

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Abstract The synergistic effects in electrocatalysis can significantly enhance catalyst performance by improving catalytic activity, selectivity, and stability, optimizing reaction mechanisms electron transfer processes. This review summarizes recent advancements the of electrochemical reduction CO 2 (eCO RR) to multi‐carbon (C 2+ ) products. Starting with fundamental principles eCO RR for C product formation, paper outlines producing , 3 4 5 A comprehensive discussion is provided on critical impact structure–performance relationship production Subsequently, observed are classified various electrocatalysts different properties, including single/dual‐atom catalysts, multi‐centric single‐atom alloys, metal‐organic frameworks, heterojunction catalysts. Finally, challenges achieving selective formation through discussed, along corresponding strategies overcome obstacles.

Language: Английский

Rational Construction of Cu Active Sites for CO2 Electrolysis to C2+ Product DOI Open Access

Chaofeng Zheng,

Libing Zhang,

Xinning Song

et al.

Chemistry - An Asian Journal, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Electrocatalytic CO 2 reduction reaction (CO RR) has emerged as a promising approach in advancing towards carbon neutrality and addressing renewable energy intermittency. Copper‐based catalysts have received much attention due to their high catalytic activity convert into value‐added C 2+ products. However, RR exhibits diversity of products unavoidable hydrogen precipitation side reactions the moderate adsorption strength *CO on copper surface fact that electrode potential for is very close reduction. Here, we summarize recent advances structural design active site construction copper‐based RR, investigate effects improvement performance, with aim deepening understanding catalyst structure sites, thereby facilitating more efficient sustainable production chemicals.

Language: Английский

Citations

0
Synergistic Effects in the Electrochemical Carbon Dioxide Reduction Reaction for Multi‐Carbon Product Formation DOI

Xiaoqin Xu,

Jingqi Guan

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Abstract The synergistic effects in electrocatalysis can significantly enhance catalyst performance by improving catalytic activity, selectivity, and stability, optimizing reaction mechanisms electron transfer processes. This review summarizes recent advancements the of electrochemical reduction CO 2 (eCO RR) to multi‐carbon (C 2+ ) products. Starting with fundamental principles eCO RR for C product formation, paper outlines producing , 3 4 5 A comprehensive discussion is provided on critical impact structure–performance relationship production Subsequently, observed are classified various electrocatalysts different properties, including single/dual‐atom catalysts, multi‐centric single‐atom alloys, metal‐organic frameworks, heterojunction catalysts. Finally, challenges achieving selective formation through discussed, along corresponding strategies overcome obstacles.

Language: Английский

Citations

0