Unsaturated Coordination Co-BDC Nanosheets with Numerous Potential Binding Sites for Sodium Ions DOI

Gongjing Song,

Yan Shi,

Biao Yang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 16, 2025

Since the radius of sodium ions is larger compared to that lithium ions, it more likely lead structural instability electrode material during embedding and de-embedding process or even trigger collapse. Due ability unsaturated coordination metal–organic framework materials expose metal active centers provide additional sodium-ion binding sites, these have great potential as anode for batteries. In this study, we obtained coordinated Co-terephthalic acid via a simple hydrothermal method using an adjusted metal-to-ligand ratio. The rigid structure benzene ring presence –COO– group ensures both high-strength stability increase in intercalation sites Na ions. Therefore, based on MOF demonstrates long lifespan high capacity 191 mA h g–1 at 100 g–1. preparation pure by constructing provides ideas application MOF-based

Language: Английский

Unsaturated Coordination Co-BDC Nanosheets with Numerous Potential Binding Sites for Sodium Ions DOI

Gongjing Song,

Yan Shi,

Biao Yang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 16, 2025

Since the radius of sodium ions is larger compared to that lithium ions, it more likely lead structural instability electrode material during embedding and de-embedding process or even trigger collapse. Due ability unsaturated coordination metal–organic framework materials expose metal active centers provide additional sodium-ion binding sites, these have great potential as anode for batteries. In this study, we obtained coordinated Co-terephthalic acid via a simple hydrothermal method using an adjusted metal-to-ligand ratio. The rigid structure benzene ring presence –COO– group ensures both high-strength stability increase in intercalation sites Na ions. Therefore, based on MOF demonstrates long lifespan high capacity 191 mA h g–1 at 100 g–1. preparation pure by constructing provides ideas application MOF-based

Language: Английский

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