
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 29, 2025
Abstract Perovskite solar cells (PSCs) have rapidly gained prominence as a leading candidate in the realm of solution‐processable third‐generation photovoltaic (PV) technologies. In high‐efficiency inverted PSCs, self‐assembled monolayers (SAMs) are often used hole‐selective layers (HSLs) due to advantages high transmittance, energy level matching, low non‐radiative recombination loss, and tunable surface properties. However, SAMs been recognized suffer from some shortcomings, such incomplete coverage, weak bonding with substrate or perovskite, instability, so on. The combination different so‐called co‐SAM is an effective strategy overcome this challenge. Perspective, latest achievements molecule design, deposition method, working principle, application discussed. This comprehensive overview milestones advancing research field, coupled in‐depth analysis improved interface properties using approach, aims offer valuable insights into key design principles. Furthermore, lessons learned will guide future development SAM‐based HSLs perovskite‐based optoelectronic devices.
Language: Английский