Journal of Energy Chemistry, Journal Year: 2020, Volume and Issue: 54, P. 528 - 554
Published: June 16, 2020
Language: Английский
Energy & Environmental Science, Journal Year: 2020, Volume and Issue: 13(10), P. 3361 - 3392
Published: Jan. 1, 2020
Metal oxide-based materials are emerging as a promising family of hydrogen evolution reaction (HER) electrocatalysts.
Language: Английский
Citations
550
Advanced Functional Materials, Journal Year: 2020, Volume and Issue: 30(45)
Published: Sept. 6, 2020
Abstract Developing highly efficient and stable electrocatalysts plays an important role in energy‐related electrocatalysis fields. Transition‐metal phosphides (TMPs) possess a series of advantages, such as high conductivity, earth‐abundance reserves, good physicochemical properties, therefore arousing wide attention. In this review, the electrochemical activity origin TMPs, allowing rational design construction toward various energy‐relevant reactions is first discussed. Subsequently, their unique nature hydrogen evolution reaction (HER), oxygen (OER), reduction (ORR), oxidation (HOR), carbon dioxide (CO 2 RR), nitrogen (NRR), urea (UOR), methanol (MOR), others highlighted. Then, TMPs’ synthetic strategies are analyzed summarized systematically. Finally, existing key issues, countermeasures, future challenges TMPs briefly
Language: Английский
Citations
473
International Journal of Hydrogen Energy, Journal Year: 2021, Volume and Issue: 46(63), P. 32284 - 32317
Published: July 30, 2021
Language: Английский
Citations
454
Nano Letters, Journal Year: 2021, Volume and Issue: 21(4), P. 1555 - 1565
Published: Feb. 11, 2021
With many apparent advantages including high surface area, tunable pore sizes and topologies, diverse periodic organic–inorganic ingredients, metal–organic frameworks (MOFs) have been identified as versatile precursors or sacrificial templates for preparing functional materials advanced electrodes high-efficiency catalysts electrochemical energy storage conversion (EESC). In this Mini Review, we first briefly summarize the material design strategies to show rich possibilities of chemical compositions physical structures MOFs derivatives. We next highlight latest advances focusing on composition/structure/performance relationship discuss their practical applications in various EESC systems, such supercapacitors, rechargeable batteries, fuel cells, water electrolyzers, carbon dioxide/nitrogen reduction reactions. Finally, provide some our own insights into major challenges prospective solutions MOF-derived EESC, hoping shed light future development highly exciting field.
Language: Английский
Citations
450
Green Chemistry, Journal Year: 2021, Volume and Issue: 23(12), P. 4228 - 4254
Published: Jan. 1, 2021
HMF electrooxidation is emerging as a powerful and promising method to produce wide range of high-value chemicals on account mild operation conditions, controllable selectivity, scalability.
Language: Английский
Citations
351
Coordination Chemistry Reviews, Journal Year: 2021, Volume and Issue: 439, P. 213953 - 213953
Published: April 18, 2021
Language: Английский
Citations
342
Green Chemistry, Journal Year: 2020, Volume and Issue: 23(1), P. 119 - 231
Published: Nov. 12, 2020
This review presents a comprehensive roadmap for the production of HMF from biomass and upgradation toward fuels, chemicals materials.
Language: Английский
Citations
333
Angewandte Chemie International Edition, Journal Year: 2020, Volume and Issue: 60(11), P. 5984 - 5993
Published: Dec. 11, 2020
Abstract Electrochemical water splitting for H 2 production is limited by the sluggish anode oxygen evolution reaction (OER), thus using hydrazine oxidation (HzOR) to replace OER has received great attention. Here we report hierarchical porous nanosheet arrays with abundant Ni 3 N‐Co N heterointerfaces on foam superior hydrogen (HER) and HzOR activity, realizing working potentials of −43 −88 mV 10 mA cm −2 , respectively, achieving an industry‐level 1000 at 200 HzOR. The two‐electrode overall (OHzS) electrolyzer requires cell voltages 0.071 0.76 V 400 respectively. powered a direct fuel (DHzFC) commercial solar are investigated inspire future practical applications. DFT calculations decipher that simultaneously optimize adsorption free energy (Δ G H* ) promote dehydrogenation kinetics. This work provides rationale advanced bifunctional electrocatalysts, propels energy‐saving generation techniques.
Language: Английский
Citations
329
eScience, Journal Year: 2021, Volume and Issue: 1(1), P. 69 - 74
Published: Sept. 21, 2021
Electrochemical water splitting is a sustainable and feasible strategy for hydrogen production but hampered by the sluggish anodic oxygen evolution reaction (OER). Herein, an effective approach introduced to significantly decrease cell voltage replacing OER with urea oxidation (UOR). A Ni2P/NiMoP nanosheet catalyst hierarchical architecture uniformly grown on nickel foam (NF) substrate through simple hydrothermal phosphorization method. The achieves impressive HER activity, low overpotential of only 22 mV at 10 mA cm–2 Tafel slope 34.5 dec–1. In addition, reduced from 1.49 V 1.33 after introduction 0.33 M urea. Notably, two-electrode electrolyzer employing as bifunctional exhibits current density 1.35 excellent long-term durability 80 h.
Language: Английский
Citations
324
Energy & Environmental Science, Journal Year: 2021, Volume and Issue: 14(10), P. 5228 - 5259
Published: Jan. 1, 2021
This review summarizes the recent progress of atomic heterointerface engineering to overcome activity limitation electrocatalysts for water splitting and elaborates its electron effect ensemble effect, etc.
Language: Английский
Citations
323