2,5-Furandicarboxylic acid production via catalytic oxidation of 5-hydroxymethylfurfural: Catalysts, processes and reaction mechanism DOI
Chunlin Chen,

Lingchen Wang,

Bin Zhu

et al.

Journal of Energy Chemistry, Journal Year: 2020, Volume and Issue: 54, P. 528 - 554

Published: June 16, 2020

Language: Английский

Metal oxide-based materials as an emerging family of hydrogen evolution electrocatalysts DOI
Yinlong Zhu, Qian Lin, Yijun Zhong

et al.

Energy & Environmental Science, Journal Year: 2020, Volume and Issue: 13(10), P. 3361 - 3392

Published: Jan. 1, 2020

Metal oxide-based materials are emerging as a promising family of hydrogen evolution reaction (HER) electrocatalysts.

Language: Английский

Citations

550

Transition‐Metal Phosphides: Activity Origin, Energy‐Related Electrocatalysis Applications, and Synthetic Strategies DOI
Zonghua Pu, Tingting Liu, Ibrahim Saana Amiinu

et al.

Advanced Functional Materials, Journal Year: 2020, Volume and Issue: 30(45)

Published: Sept. 6, 2020

Abstract Developing highly efficient and stable electrocatalysts plays an important role in energy‐related electrocatalysis fields. Transition‐metal phosphides (TMPs) possess a series of advantages, such as high conductivity, earth‐abundance reserves, good physicochemical properties, therefore arousing wide attention. In this review, the electrochemical activity origin TMPs, allowing rational design construction toward various energy‐relevant reactions is first discussed. Subsequently, their unique nature hydrogen evolution reaction (HER), oxygen (OER), reduction (ORR), oxidation (HOR), carbon dioxide (CO 2 RR), nitrogen (NRR), urea (UOR), methanol (MOR), others highlighted. Then, TMPs’ synthetic strategies are analyzed summarized systematically. Finally, existing key issues, countermeasures, future challenges TMPs briefly

Language: Английский

Citations

473

Recent development in electrocatalysts for hydrogen production through water electrolysis DOI
Shams Anwar, Faisal Khan, Yahui Zhang

et al.

International Journal of Hydrogen Energy, Journal Year: 2021, Volume and Issue: 46(63), P. 32284 - 32317

Published: July 30, 2021

Language: Английский

Citations

454

Metal–Organic Frameworks Derived Functional Materials for Electrochemical Energy Storage and Conversion: A Mini Review DOI Creative Commons
Xue Feng Lu, Yongjin Fang, Deyan Luan

et al.

Nano Letters, Journal Year: 2021, Volume and Issue: 21(4), P. 1555 - 1565

Published: Feb. 11, 2021

With many apparent advantages including high surface area, tunable pore sizes and topologies, diverse periodic organic–inorganic ingredients, metal–organic frameworks (MOFs) have been identified as versatile precursors or sacrificial templates for preparing functional materials advanced electrodes high-efficiency catalysts electrochemical energy storage conversion (EESC). In this Mini Review, we first briefly summarize the material design strategies to show rich possibilities of chemical compositions physical structures MOFs derivatives. We next highlight latest advances focusing on composition/structure/performance relationship discuss their practical applications in various EESC systems, such supercapacitors, rechargeable batteries, fuel cells, water electrolyzers, carbon dioxide/nitrogen reduction reactions. Finally, provide some our own insights into major challenges prospective solutions MOF-derived EESC, hoping shed light future development highly exciting field.

Language: Английский

Citations

450

Electrochemical oxidation of biomass derived 5-hydroxymethylfurfural (HMF): pathway, mechanism, catalysts and coupling reactions DOI

Yuechao Yang,

Tiancheng Mu

Green Chemistry, Journal Year: 2021, Volume and Issue: 23(12), P. 4228 - 4254

Published: Jan. 1, 2021

HMF electrooxidation is emerging as a powerful and promising method to produce wide range of high-value chemicals on account mild operation conditions, controllable selectivity, scalability.

Language: Английский

Citations

351

Heterojunction catalyst in electrocatalytic water splitting DOI
Zhenxing Li,

Mingliang Hu,

Ping Wang

et al.

Coordination Chemistry Reviews, Journal Year: 2021, Volume and Issue: 439, P. 213953 - 213953

Published: April 18, 2021

Language: Английский

Citations

342

Biorefinery roadmap based on catalytic production and upgrading 5-hydroxymethylfurfural DOI
Qidong Hou, Xinhua Qi,

Meinan Zhen

et al.

Green Chemistry, Journal Year: 2020, Volume and Issue: 23(1), P. 119 - 231

Published: Nov. 12, 2020

This review presents a comprehensive roadmap for the production of HMF from biomass and upgradation toward fuels, chemicals materials.

Language: Английский

Citations

333

Artificial Heterointerfaces Achieve Delicate Reaction Kinetics towards Hydrogen Evolution and Hydrazine Oxidation Catalysis DOI

Qizhu Qian,

Jihua Zhang,

Jianming Li

et al.

Angewandte Chemie International Edition, Journal Year: 2020, Volume and Issue: 60(11), P. 5984 - 5993

Published: Dec. 11, 2020

Abstract Electrochemical water splitting for H 2 production is limited by the sluggish anode oxygen evolution reaction (OER), thus using hydrazine oxidation (HzOR) to replace OER has received great attention. Here we report hierarchical porous nanosheet arrays with abundant Ni 3 N‐Co N heterointerfaces on foam superior hydrogen (HER) and HzOR activity, realizing working potentials of −43 −88 mV 10 mA cm −2 , respectively, achieving an industry‐level 1000 at 200 HzOR. The two‐electrode overall (OHzS) electrolyzer requires cell voltages 0.071 0.76 V 400 respectively. powered a direct fuel (DHzFC) commercial solar are investigated inspire future practical applications. DFT calculations decipher that simultaneously optimize adsorption free energy (Δ G H* ) promote dehydrogenation kinetics. This work provides rationale advanced bifunctional electrocatalysts, propels energy‐saving generation techniques.

Language: Английский

Citations

329

Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production DOI Creative Commons
Tongzhou Wang, Xuejie Cao, Lifang Jiao

et al.

eScience, Journal Year: 2021, Volume and Issue: 1(1), P. 69 - 74

Published: Sept. 21, 2021

Electrochemical water splitting is a sustainable and feasible strategy for hydrogen production but hampered by the sluggish anodic oxygen evolution reaction (OER). Herein, an effective approach introduced to significantly decrease cell voltage replacing OER with urea oxidation (UOR). A Ni2P/NiMoP nanosheet catalyst hierarchical architecture uniformly grown on nickel foam (NF) substrate through simple hydrothermal phosphorization method. The achieves impressive HER activity, low overpotential of only 22 mV at 10 mA cm–2 Tafel slope 34.5 dec–1. In addition, reduced from 1.49 V 1.33 after introduction 0.33 M urea. Notably, two-electrode electrolyzer employing as bifunctional exhibits current density 1.35 excellent long-term durability 80 h.

Language: Английский

Citations

324

Atomic heterointerface engineering overcomes the activity limitation of electrocatalysts and promises highly-efficient alkaline water splitting DOI
Qiucheng Xu, Jiahao Zhang, Haoxuan Zhang

et al.

Energy & Environmental Science, Journal Year: 2021, Volume and Issue: 14(10), P. 5228 - 5259

Published: Jan. 1, 2021

This review summarizes the recent progress of atomic heterointerface engineering to overcome activity limitation electrocatalysts for water splitting and elaborates its electron effect ensemble effect, etc.

Language: Английский

Citations

323