Nano-Micro Letters,
Journal Year:
2023,
Volume and Issue:
15(1)
Published: April 10, 2023
Abstract
Rechargeable
proton
batteries
have
been
regarded
as
a
promising
technology
for
next-generation
energy
storage
devices,
due
to
the
smallest
size,
lightest
weight,
ultrafast
diffusion
kinetics
and
negligible
cost
of
charge
carriers.
Nevertheless,
battery
possessing
both
high
power
density
is
yet
achieved.
In
addition,
poor
cycling
stability
another
major
challenge
making
lifespan
unsatisfactory.
These
issues
motivated
extensive
research
into
electrode
materials.
Nonetheless,
design
electrode–electrolyte
interphase
electrolytes
underdeveloped
solving
challenges.
this
review,
we
summarize
development
elaborate
on
their
importance
in
enhancing
density,
lifespan.
The
fundamental
understanding
reviewed
with
respect
desolvation
process,
interfacial
reaction
kinetics,
solvent-electrode
interactions,
analysis
techniques.
We
categorize
currently
used
according
physicochemical
properties
analyze
electrochemical
potential
window,
solvent
(e.g.,
water)
activities,
ionic
conductivity,
thermal
stability,
safety.
Finally,
offer
our
views
challenges
opportunities
toward
future
achieving
high-performance
storage.
Energy & Environmental Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Zn(CF
3
COO)
2
promotes
the
dual
reduction
of
anions
to
fluoride
and
sulfide,
forming
an
amorphous
hybrid
solid
electrolyte
interface
(SEI).
This
SEI
significantly
benefits
plating/stripping
Zn
anode
thereby
improves
battery
performance.
Nature Communications,
Journal Year:
2025,
Volume and Issue:
16(1)
Published: Jan. 2, 2025
Aqueous
zinc
ion
batteries
exhibit
great
prospects
due
to
their
low
cost
and
high
safety,
while
lifespan
is
limited
by
severe
dendritic
growth
problems.
Herein,
we
develop
an
anti-dendrite
hot-pressing
separator
interlayer
through
a
mass-producible
strategy,
spreading
metal-organic
framework
(MOF)
precursor
on
nonwoven
matrix
followed
simple
process.
The
in
situ
modification
of
MOF
crystals
fiber
surface
processes
abundant
nitrogenous
functional
groups
specific
area
(190.8
m2
g−1)
with
strong
attraction
Zn2+.
These
features
contribute
staged
deposition
behavior
promote
uniform
nucleation
at
concentrations
two-dimensional
grain
concentrations.
Consequently,
Zn
|
|Zn
symmetrical
cells
demonstrate
cycle
lives
3000
hours
2
mA
cm−2,
mAh
cm−2.
Moreover,
|I2
pouch
realizes
840
cycles
capacity
retention
90.9%
final
discharge
110.6
25
°C.
Zinc
aqueous
zinc-ion
influenced
separators.
Here,
authors
introduce
MOF-modified
regulate
Zn2+
concentration
two
stages
via
groups,
reducing
crystal
nucleus
radius
ensuring
deposition.
Nano-Micro Letters,
Journal Year:
2023,
Volume and Issue:
15(1)
Published: April 10, 2023
Abstract
Rechargeable
proton
batteries
have
been
regarded
as
a
promising
technology
for
next-generation
energy
storage
devices,
due
to
the
smallest
size,
lightest
weight,
ultrafast
diffusion
kinetics
and
negligible
cost
of
charge
carriers.
Nevertheless,
battery
possessing
both
high
power
density
is
yet
achieved.
In
addition,
poor
cycling
stability
another
major
challenge
making
lifespan
unsatisfactory.
These
issues
motivated
extensive
research
into
electrode
materials.
Nonetheless,
design
electrode–electrolyte
interphase
electrolytes
underdeveloped
solving
challenges.
this
review,
we
summarize
development
elaborate
on
their
importance
in
enhancing
density,
lifespan.
The
fundamental
understanding
reviewed
with
respect
desolvation
process,
interfacial
reaction
kinetics,
solvent-electrode
interactions,
analysis
techniques.
We
categorize
currently
used
according
physicochemical
properties
analyze
electrochemical
potential
window,
solvent
(e.g.,
water)
activities,
ionic
conductivity,
thermal
stability,
safety.
Finally,
offer
our
views
challenges
opportunities
toward
future
achieving
high-performance
storage.
