ACS Applied Materials & Interfaces,
Journal Year:
2023,
Volume and Issue:
15(3), P. 4549 - 4558
Published: Jan. 16, 2023
3D
printed
silicones
have
demonstrated
great
potential
in
diverse
areas
by
combining
the
advantageous
physiochemical
properties
of
with
unparalleled
design
freedom
additive
manufacturing.
However,
their
low-temperature
performance,
which
is
particular
importance
for
polar
and
space
applications,
has
not
been
addressed.
Herein,
a
silicone
foam
unprecedented
elasticity
presented,
featured
extraordinary
fatigue
resistance,
excellent
shape
recovery,
energy-absorbing
capability
down
to
low
temperature
−60
°C
after
extreme
compression
(an
intensive
load
over
66000
times
its
own
weight).
The
achieved
direct
writing
phenyl
silicone-based
pseudoplastic
ink
embedded
sodium
chloride
as
sacrificial
template.
During
water
immersion
process
create
pores
filaments,
unique
osmotic
pressure-driven
morphing
strategy
also
reported,
offers
an
attractive
alternative
traditional
4D
hydrogels
virtue
favorable
mechanical
robustness
material.
underlying
mechanisms
are
discussed
detail.
Advanced Materials,
Journal Year:
2022,
Volume and Issue:
34(28)
Published: March 5, 2022
Additive
manufacturing
(AM)
has
gained
significant
attention
due
to
its
ability
drive
technological
development
as
a
sustainable,
flexible,
and
customizable
scheme.
Among
the
various
AM
techniques,
direct
ink
writing
(DIW)
emerged
most
versatile
3D
printing
technique
for
broadest
range
of
materials.
DIW
allows
practically
any
material,
long
precursor
can
be
engineered
demonstrate
appropriate
rheological
behavior.
This
acts
unique
pathway
introduce
design
freedom,
multifunctionality,
stability
simultaneously
into
printed
structures.
Here,
comprehensive
review
complex
structures
from
materials,
including
polymers,
ceramics,
glass,
cement,
graphene,
metals,
their
combinations
through
multimaterial
is
presented.
The
begins
with
an
overview
fundamentals
rheology,
followed
by
in-depth
discussion
methods
tailor
different
classes
Then,
diverse
applications
ranging
electronics
food
biomedical
industries
are
discussed.
Finally,
current
challenges
limitations
this
highlighted,
prospects
guideline
toward
possible
futuristic
innovations.
Reactive and Functional Polymers,
Journal Year:
2022,
Volume and Issue:
179, P. 105374 - 105374
Published: Aug. 10, 2022
4D
bioprinting
is
the
next-generation
additive
manufacturing-based
fabrication
platform
employed
to
construct
intricate,
adaptive,
and
dynamic
soft
hard
tissue
structures
as
well
biomedical
devices.
It
achieved
by
using
stimuli-responsive
materials,
especially
shape
memory
polymers
(SMPs)
hydrogels,
which
possess
desirable
biomechanical
characteristics.
In
last
few
years,
numerous
efforts
have
been
made
printing
community
develop
novel
polymeric
materials
considering
their
perspective.
This
review
presents
an
up-to-date
overview
of
technology
incorporating
functionalities
biomaterials
focused
approach
towards
different
engineering
regenerative
medicine
(TERM)
applications.
includes
bone,
cardiac,
neural,
cartilage,
drug
delivery
systems,
other
high-value
also
addresses
current
limitations
challenges
in
provide
a
basis
for
foreseeable
advancements
TERM
applications
that
could
be
helpful
successful
utilization
clinical
settings.
Chemical Reviews,
Journal Year:
2023,
Volume and Issue:
123(18), P. 11137 - 11189
Published: Sept. 7, 2023
Architected
flexible
electronic
devices
with
rationally
designed
3D
geometries
have
found
essential
applications
in
biology,
medicine,
therapeutics,
sensing/imaging,
energy,
robotics,
and
daily
healthcare.
Mechanically-guided
assembly
methods,
exploiting
mechanics
principles
of
materials
structures
to
transform
planar
fabricated
using
mature
semiconductor
techniques
into
architected
ones,
are
promising
routes
such
devices.
Here,
we
comprehensively
review
mechanically-guided
methods
for
electronics.
Mainstream
classified
discussed
on
the
basis
their
fundamental
deformation
modes
(i.e.,
rolling,
folding,
curving,
buckling).
Diverse
interconnects
device
forms
then
summarized,
which
correspond
two
key
components
an
device.
Afterward,
structure-induced
functionalities
highlighted
provide
guidelines
function-driven
structural
designs
electronics,
followed
by
a
collective
summary
resulting
applications.
Finally,
conclusions
outlooks
given,
covering
achieve
extreme
deformations
dimensions,
inverse
design
encapsulation
strategies
as
well
perspectives
future
Science Advances,
Journal Year:
2024,
Volume and Issue:
10(5)
Published: Feb. 2, 2024
3D
soft
bioscaffolds
have
great
promise
in
tissue
engineering,
biohybrid
robotics,
and
organ-on-a-chip
engineering
applications.
Though
emerging
three-dimensional
(3D)
printing
techniques
offer
versatility
for
assembling
biomaterials,
challenges
persist
overcoming
the
deformation
or
collapse
of
delicate
structures
during
fabrication,
especially
overhanging
thin
features.
This
study
introduces
a
magnet-assisted
fabrication
strategy
that
uses
magnetic
field
to
trigger
shape
morphing
provide
remote
temporary
support,
enabling
straightforward
creation
with
overhangs
thin-walled
3D.
We
demonstrate
effectiveness
our
through
replicate
complex
topology
branching
vascular
systems.
Furthermore,
we
engineered
hydrogel-based
support
actuators
capable
walking
motion
triggered
by
cardiomyocytes.
approach
opens
new
possibilities
shaping
hydrogel
materials
into
morphologies,
which
will
further
empower
broad
range
biomedical
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(26)
Published: Feb. 25, 2024
Choreographing
the
adaptive
shapes
of
patterned
surfaces
to
exhibit
designable
mechanical
interactions
with
their
environment
remains
an
intricate
challenge.
Here,
a
novel
category
strain-engineered
dynamic-shape
materials,
empowering
diverse
multi-dimensional
shape
modulations
that
are
combined
form
fine-grained
microarchitectures
is
introduced.
Using
micro-origami
tessellation
technology,
heterogeneous
materials
provided
strategic
creases
featuring
stimuli-responsive
micro-hinges
morph
precisely
upon
chemical
and
electrical
cues.
Freestanding
multifaceted
foldable
packages,
auxetic
mesosurfaces,
morphable
cages
three
forms
demonstrated
herein
these
complex
4-dimensional
(4D)
metamaterials.
These
systems
integrated
in
dual
proof-of-concept
bioelectronic
demonstrations:
soft
supercapacitor
enhancing
its
power
density
(≈108
mW
cm
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
33(15)
Published: Dec. 7, 2022
Abstract
Additive
manufacturing
is
a
promising
technology
that
can
directly
fabricate
structures
with
complex
internal
geometries,
which
barely
achieved
by
traditional
manufacturing.
However,
the
mechanical
properties
of
fused
deposition
modeling
(FDM)‐printed
objects
are
inferior
to
those
conventionally
manufactured
products.
To
improve
printed
products,
series
novel
thermoplastic
polyurethanes
self‐healing
properties,
intrinsic
photothermal
effects,
and
excellent
printability
designed
synthesized
introducing
dynamic
oxime–carbamate
bonds
hydrogen
into
polymer
chains.
On‐demand
introduction
near‐infrared
(NIR)
irradiation,
direct
heating,
sunlight
irradiation
enhances
interfacial
bonding
strength
thus
product.
Additionally,
anisotropy
products
be
sophistically
manipulated
regulating
conditions.
Support‐free
printing
healing
damaged
also
owing
material.
Moreover,
as‐prepared
materials
exhibit
shape‐memory
NIR
or
heating
effectively
triggers
recovery
demonstrates
their
potential
in
4D
man‐like
robot.
This
study
not
only
provides
facile
strategy
for
obtaining
high‐performance
but
broadens
applications
FDM
intelligent
devices.
Biomedical Materials,
Journal Year:
2022,
Volume and Issue:
17(6), P. 062001 - 062001
Published: Aug. 31, 2022
Abstract
Nature’s
materials
have
evolved
over
time
to
be
able
respond
environmental
stimuli
by
generating
complex
structures
that
can
change
their
functions
in
response
distance,
time,
and
direction
of
stimuli.
A
number
technical
efforts
are
currently
being
made
improve
printing
resolution,
shape
fidelity,
speed
mimic
the
structural
design
natural
with
three-dimensional
printing.
Unfortunately,
this
technology
is
limited
fact
printed
objects
static
cannot
reshaped
dynamically
In
recent
years,
several
smart
been
developed
undergo
dynamic
morphing
a
stimulus,
thus
resolving
issue.
Four-dimensional
(4D)
refers
manufacturing
process
involving
additive
manufacturing,
materials,
specific
geometries.
It
has
become
an
essential
for
biomedical
engineering
potential
create
wide
range
useful
products.
This
paper
will
discuss
concept
4D
bioprinting
developments
which
actuated
different
exploited
develop
biomimetic
structures,
significant
implications
pharmaceutics
research,
as
well
prospects
future.
Pharmaceuticals,
Journal Year:
2022,
Volume and Issue:
15(10), P. 1282 - 1282
Published: Oct. 19, 2022
Advancements
in
the
material
design
of
smart
hydrogels
have
transformed
way
therapeutic
agents
are
encapsulated
and
released
biological
environments.
On
other
hand,
expeditious
development
3D
printing
technologies
has
revolutionized
fabrication
hydrogel
systems
for
biomedical
applications.
By
combining
these
two
aspects,
4D
(i.e.,
hydrogels)
emerged
as
a
new
promising
platform
novel
controlled
drug
delivery
that
can
adapt
mimic
natural
physio-mechanical
changes
over
time.
This
allows
printed
objects
to
transform
from
static
dynamic
response
various
physiological
chemical
interactions,
meeting
needs
healthcare
industry.
In
this
review,
we
provide
an
overview
innovation
systems,
current
technical
approaches
toward
printing,
emerging
structures
Finally,
discuss
existing
challenges
their
prospects.
International Journal of Extreme Manufacturing,
Journal Year:
2023,
Volume and Issue:
5(3), P. 032011 - 032011
Published: June 22, 2023
Highlights
The
key
technological
roadmap
for
implementation
of
4D
printing
is
comprehensively
summarized.
Material-structure-functionality
integrated
aspects
in
are
emphasized.
links
between
smart
materials,
3D
techniques,
structures,
stimulus,
and
new
functionalities
multidisciplinary
applications
established.
General
approaches
to
designing
programmable
structures
introduced.
Advanced Materials Technologies,
Journal Year:
2023,
Volume and Issue:
8(5)
Published: Feb. 5, 2023
Microinjection
protocols
are
ubiquitous
throughout
biomedical
fields,
with
hollow
microneedle
arrays
(MNAs)
offering
distinctive
benefits
in
both
research
and
clinical
settings.
Unfortunately,
manufacturing-associated
barriers
remain
a
critical
impediment
to
emerging
applications
that
demand
high-density
of
hollow,
high-aspect-ratio
microneedles.
To
address
such
challenges,
here,
hybrid
additive
manufacturing
approach
combines
digital
light
processing
(DLP)
3D
printing
"ex
situ
direct
laser
writing
(