Progress and prospect of CO2 photocatalytic reduction to methanol DOI

Tongxin Qu,

Shuzhou Wei,

Zhuo Xiong

et al.

Fuel Processing Technology, Journal Year: 2023, Volume and Issue: 251, P. 107933 - 107933

Published: Aug. 21, 2023

Language: Английский

Cooperatively tailored surface frustrated Lewis pairs and N-doping on CeO2 for photocatalytic CO2 reduction to high-value hydrocarbon products DOI

Xinying Yan,

Bo Gao, Xiaoli Zheng

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 343, P. 123484 - 123484

Published: Nov. 7, 2023

Language: Английский

Citations

33

Atomically Dispersed Unsaturated Cu‐N3 Sites on High‐Curvature Hierarchically Porous Carbon Nanotube for Synergetic Enhanced Nitrate Electroreduction to Ammonia DOI
Yan Wang, Wenchang Zhang,

Weidong Wen

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(46)

Published: July 20, 2023

Abstract Cu‐based single‐atom catalysts (SACs) are regarded as promising candidates for electrocatalytic reduction of nitrate to ammonia (NO 3 RR) owing the appropriate intrinsic activity and merits SACs. However, most reported Cu SACs based on 4N saturated coordination supported planer carbon substrate, their performances unsatisfactory. Herein, low‐coordinated Cu‐N designed constructed high‐curvature hierarchically porous N‐doped nanotube (NCNT) via a stepwise polymerization–surface modification–electrostatic adsorption–carbonization strategy. The SACs/NCNT exhibits outstanding NO RR performance with maximal Faradaic efficiency 89.64% NH yield rate up 30.09 mg cat −1 h (70.8 mol g ), superior catalysts. results integrated from potassium thiocyanide poisoning experiments, online differential electrochemical mass spectrometry, in situ Fourier transform infrared spectroscopy, density functional theory calculations demonstrate: 1) unsaturated is active site; 2) possesses NO*‐HNO*‐H 2 NO*‐H NOH* pathway; 3) sites support synergetic promote reaction dynamics reduce rate‐determining step barrier. This study inspires enhancement catalysis strategy creating environment regulating structure.

Language: Английский

Citations

32

Accelerating solar driven CO2 reduction via sulfur-doping boosted water dissociation and proton transfer DOI

Ke Yan,

Liang Chen, Yangguang Hu

et al.

Nano Research, Journal Year: 2023, Volume and Issue: 17(3), P. 1056 - 1065

Published: July 26, 2023

Language: Английский

Citations

30

Photocatalytic CO2 reduction reaction: Influencing factors, reaction pathways and dominant catalysts DOI
Jiyue Zhang,

Jiaying Jiang,

Yaru Lei

et al.

Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 328, P. 125056 - 125056

Published: Sept. 9, 2023

Language: Английский

Citations

29

Progress and prospect of CO2 photocatalytic reduction to methanol DOI

Tongxin Qu,

Shuzhou Wei,

Zhuo Xiong

et al.

Fuel Processing Technology, Journal Year: 2023, Volume and Issue: 251, P. 107933 - 107933

Published: Aug. 21, 2023

Language: Английский

Citations

26