Microenvironment Engineering of Heterogeneous Catalysts for Liquid-Phase Environmental Catalysis DOI

Zhong‐Shuai Zhu,

Shuang Zhong, Cheng Cheng

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(20), P. 11348 - 11434

Published: Oct. 9, 2024

Environmental catalysis has emerged as a scientific frontier in mitigating water pollution and advancing circular chemistry reaction microenvironment significantly influences the catalytic performance efficiency. This review delves into engineering within liquid-phase environmental catalysis, categorizing microenvironments four scales: atom/molecule-level modulation, nano/microscale-confined structures, interface surface regulation, external field effects. Each category is analyzed for its unique characteristics merits, emphasizing potential to enhance efficiency selectivity. Following this overview, we introduced recent advancements advanced material system design promote (e.g., purification, transformation value-added products, green synthesis), leveraging state-of-the-art technologies. These discussions showcase was applied different reactions fine-tune regimes improve from both thermodynamics kinetics perspectives. Lastly, discussed challenges future directions engineering. underscores of intelligent materials drive development more effective sustainable solutions decontamination.

Language: Английский

A Review of Anode Materials for Dual-Ion Batteries DOI Creative Commons

Hongzheng Wu,

Shenghao Luo,

Hubing Wang

et al.

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)

Published: July 24, 2024

Distinct from "rocking-chair" lithium-ion batteries (LIBs), the unique anionic intercalation chemistry on cathode side of dual-ion (DIBs) endows them with intrinsic advantages low cost, high voltage, and eco-friendly, which is attracting widespread attention, expected to achieve next generation large-scale energy storage applications. Although electrochemical reactions anode DIBs are similar that LIBs, in fact, match rapid insertion kinetics anions consider compatibility electrolyte system also serves as an active material, materials play a very important role, there urgent demand for rational structural design performance optimization. A review summarization previous studies will facilitate exploration optimization future. Here, we summarize development process working mechanism exhaustively categorize latest research their applications different battery systems. Moreover, design, reaction briefly discussed. Finally, fundamental challenges, potential strategies perspectives put forward. It hoped this could shed some light researchers explore more superior advanced systems further promote DIBs.

Language: Английский

Citations

19
O defect anchored Ru on BiOBr with nanoconfined structure for catalytic N2 fixation DOI
Yuzhou Xia,

Xinghe Xia,

Lu Chen

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 349, P. 123859 - 123859

Published: April 24, 2024

Language: Английский

Citations

17
The structure-performance relationships in active center size-dependent Fenton-like catalysis: From nanoparticles to single atoms DOI

Bingkun Huang,

Zelin Wu, Hongyu Zhou

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 355, P. 124157 - 124157

Published: May 9, 2024

Language: Английский

Citations

17
MOF-Based Electrocatalysts: An Overview from the Perspective of Structural Design DOI

Nana Sun,

Syed Shoaib Ahmad Shah, Zhongyuan Lin

et al.

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 18, 2025

The electrocatalytic technique, as an efficient energy storage and conversion technology, has attracted significant attention to address exhaustion environmental pollution. Usually, the activity selectivity of reactions are largely dominated by dynamic process occurring on electrocatalysts. Therefore, high-performance electrocatalysts, which can dominate pathway barrier reactions, great significance for advancement technique. Metal-organic frameworks (MOFs), emerging crystalline porous materials, present structural component advantages including well-defined structure, high surface area, large porosity, diverse components, easy tailorability, demonstrating fantastic potential precise fabrication In this Review, strategies in electrocatalysts based MOF-related materials specifically introduced from aspects catalytic site design microenvironment modulation around sites. Furthermore, representative progress achieved various applications employing MOF-based is systematically summarized, with special emphasis MOFs performance optimization. Finally, remaining challenges future perspectives further highlighted.

Language: Английский

Citations

3
Recent advances of ammonia synthesis under ambient conditions over metal-organic framework based electrocatalysts DOI Open Access
Yu Yu, Yuan Li,

Yu Hong Fang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 340, P. 123161 - 123161

Published: Aug. 10, 2023

Language: Английский

Citations

32
Recent Advances in Metal‐Organic Framework‐Based Nanomaterials for Electrocatalytic Nitrogen Reduction DOI
Bo Han, Jiawei Liu, Carmen Lee

et al.

Small Methods, Journal Year: 2023, Volume and Issue: 7(9)

Published: May 18, 2023

Abstract The production of ammonia under moderate conditions is environmental and sustainable importance. electrochemical nitrogen reduction reaction (E‐NRR) method has been intensively investigated in the recent decades. Nowadays, further development E‐NRR largely hindered by lack competent electrocatalysts. Metal‐organic frameworks (MOFs) are considered as next‐generation catalysts for E‐NRR, featuring their tailorable structures, abundant active sites favorable porosity. To present a comprehensive review on both fundamental advanced MOFs catalyst‐based field, this paper first introduces basic principles including mechanism, major apparatus components, performance criteria, detection protocols. Next, synthesis characterization methods derivatives discussed. In addition, mechanism study via density functional theory calculations also presented. After that, advancement MOF‐based field well modification approaches optimization elaborated. Finally, current challenges outlook MOF emphasized.

Language: Английский

Citations

27
Multifunctional Dysprosium(III)–Organic Framework for Efficiently Catalyzing the Cycloaddition of CO2 and Knoevenagel Condensation under Mild Conditions DOI
Xiutang Zhang, Chong Li,

Tuoping Hu

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(50), P. 17837 - 17848

Published: Dec. 6, 2023

Two-dimensional (2D) materials with higher order in-plane nanoscale pores play a crucial role in innumerable applications, but their precise and reasonable preparation remains huge challenge. Herein, we report the highly robust 2D dysprosium(III)–organic framework {[Dy(H2BDTP)(DMF)2]·2DMF·3H2O}n (NUC-101) (15.2 × 6.4 Å2) (H5BDTP = 2,6-bis(2,4-dicarboxyphenyl)-4-(2H-tetrazol-5-yl)pyridine). After activation, scarcely reported host [Dy2(H2BDTP)2]n is of great interest due to that it not only contains voids 15.2 11.7 Å3 also functionalized by free carboxyl, pyridinyl, tetrazolyl groups upper lower parts. Thanks excellent physicochemical properties including omnidirectional opening pores, ultrahigh porosity, larger specific surface area, plentiful coexisting Lewis acid–base sites open dinuclear Dy3+ ions, groups, cycloaddition CO2 epoxides Knoevenagel condensation malonitrile aldehydes can be efficiently catalyzed NUC-101a under comparatively mild conditions high selectivity turnover frequency. This work provides valuable insight development nanoporous more feasible for achieving goal catalytic applications.

Language: Английский

Citations

27
Recent advances in bimetallic metal-organic frameworks and their derivatives for thermal catalysis DOI
Fengbin Zheng,

Lin Tian,

Kun Wang

et al.

Nano Research, Journal Year: 2023, Volume and Issue: 16(12), P. 12919 - 12935

Published: Aug. 8, 2023

Language: Английский

Citations

26
Metal‐Organic Framework (MOF)‐Based Clean Energy Conversion: Recent Advances in Unlocking its Underlying Mechanisms DOI

Zheng Zhu,

Jingjing Duan, Sheng Chen

et al.

Small, Journal Year: 2023, Volume and Issue: 20(20)

Published: Dec. 21, 2023

Abstract Carbon neutrality is an important goal for humanity . As eco‐friendly technology, electrocatalytic clean energy conversion technology has emerged in the 21st century. Currently, metal‐organic framework (MOF)‐based electrocatalysis, including oxygen reduction reaction (ORR), evolution (OER), hydrogen (HER), oxidation (HOR), carbon dioxide (CO 2 RR), nitrogen (NRR), are mainstream catalytic reactions, which driven by electrocatalysis. In this paper, current advanced characterizations analyses of MOF‐based reactions have been described details, such as density function theory (DFT), machine learning, operando/in situ characterization, provide in‐depth mechanisms related to above reported past years. The practical applications that developed some responses application values, fuel cells, metal‐air batteries, and water splitting also demonstrated. This paper aims maximize potential electrocatalysts field catalysis, shed light on development intense situations.

Language: Английский

Citations

25
Nanoengineering Metal–Organic Frameworks and Derivatives for Electrosynthesis of Ammonia DOI Creative Commons
Daming Feng,

Lixue Zhou,

Timothy J. White

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: Aug. 24, 2023

Abstract Electrocatalytic synthesis under mild conditions has become increasingly important as one of the practical alternatives for industrial applications, especially green ammonia (NH 3 ) industry. A properly engineered electrocatalyst plays a vital role in realization superior catalytic performance. Among various types promising nanomaterials, metal–organic frameworks (MOFs) are competitive candidates developing efficient electrocatalytic NH from simple nitrogen-containing molecules or ions, such N 2 and NO − . In this review, recent advances development electrocatalysts derived MOFs electrosynthesis collected, categorized, discussed, including their application reduction reaction (NRR) (NO RR). Firstly, fundamental principles illustrated, plausible mechanisms generation , apparatus corresponding electrocatalysis, parameters evaluation efficiency, detection methods yielding Then, NRR processes discussed detail, pristine MOFs, MOF-hybrids, MOF-derived N-doped porous carbons, single atomic catalysts pyrolysis other MOF-related materials. Subsequently, RR also listed discussed. Finally, existing challenges prospects rational design fabrication electrochemical presented, evolution investigation with artificial intelligence, innovation synthetic catalysts, advancement characterization techniques, extended reactions. "Image missing"

Language: Английский

Citations

23