Cited by Efficient Host Materials for Lithium‐Sulfur Batteries: Ultrafine CoP Nanoparticles in Black Phosphorus‐Carbon Composite

Engineering Strategies for Suppressing the Shuttle Effect in Lithium–Sulfur Batteries DOI

Jiayi Li,

Li Gao,

Fengying Pan

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 16(1)

Published: Nov. 10, 2023

Lithium-sulfur (Li-S) batteries are supposed to be one of the most potential next-generation owing their high theoretical capacity and low cost. Nevertheless, shuttle effect firm multi-step two-electron reaction between sulfur lithium in liquid electrolyte makes much smaller than value. Many methods were proposed for inhibiting polysulfide, improving corresponding redox kinetics enhancing integral performance Li-S batteries. Here, we will comprehensively systematically summarize strategies from all components First, electrochemical principles/mechanism origin described detail. Moreover, efficient strategies, including boosting conversion rate sulfur, confining or polysulfides (LPS) within cathode host, LPS shield layer, preventing contacting anode, discussed suppress effect. Then, recent advances inhibition cathode, electrolyte, separator, anode with aforementioned have been summarized direct further design materials Finally, present prospects development directions

Language: Английский

Citations

Interface engineering toward stable lithium–sulfur batteries DOI

Yi Guo,

Qian Niu, Fei Pei

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(4), P. 1330 - 1367

Published: Jan. 1, 2024

The interfaces, interfacial issues, and their impact on lithium–sulfur electrochemistry are overviewed for both coin cells practical batteries.

Language: Английский

Citations

Recent Advances in Multifunctional Binders for High Sulfur Loading Lithium‐Sulfur Batteries DOI

Rongnan Guo,

Yi Yang,

Xiang Huang

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(1)

Published: Sept. 24, 2023

Abstract Lithium‐sulfur batteries (LSBs) are regarded as a highly promising next‐generation energy storage technology due to their exceptional theoretical capacity and density. However, the practical application of these is hindered by several challenges, including significant volume change active materials, severe shuttle effect lithium polysulfides, inadequate electronic ionic conductivity, safety concerns. These issues particularly pronounced in cathodes with high sulfur loading, which essential for effective implementation LSBs. Binders an constituent cathodes, they perform crucial function enhancing efficacy LSBs, when subjected loading. A considerable amount research has been conducted investigate potential multifunctional binders tackle aforementioned challenges associated This article provides comprehensive overview various roles that advanced play but not limited preserving electrode integrity, capturing regulating Li 2 S deposition, accelerating reaction kinetics, promoting cathode safety, safeguarding environment. Additionally, paper outlines prospects future endeavors aimed at creating innovative improving overall performance

Language: Английский

Citations

Integrated Gradient Cu Current Collector Enables Bottom‐Up Li Growth for Li Metal Anodes: Role of Interfacial Structure DOI

Yuhang Liu, Yifan Li, Zhuzhu Du

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 10(23)

Published: June 13, 2023

3D Cu current collectors have been demonstrated to improve the cycling stability of Li metal anodes, however, role their interfacial structure for deposition pattern has not investigated thoroughly. Herein, a series integrated gradient Cu-based are fabricated by electrochemical growth CuO nanowire arrays on foil (CuO@Cu), where structures can be readily controlled modulating dispersities arrays. It is found that constructed sparse and dense dispersion both disadvantageous nucleation metal, consequently fast dendrite growth. In contrast, uniform appropriate dispersity enables stable bottom associated with smooth lateral deposition, affording ideal bottom-up pattern. The optimized CuO@Cu-Li electrodes exhibit highly reversible including coulombic efficiency up ≈99% after 150 cycles long-term lifespan over 1200 h. When coupling LiFePO4 cathode, coin pouch full-cells deliver outstanding rate capability. This work provides new insight design toward high-performance anodes.

Language: Английский

Citations

Recent advances and strategies of metal phosphides for accelerating polysulfide redox and regulating Li plating DOI

Yi Yang,

Bowen Sun, Zhiqiang Sun

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 510, P. 215836 - 215836

Published: April 12, 2024

Language: Английский

Citations

Customizing the water-scarce, zinc ion-rich Helmholtz plane of a zinc anode for Ah-scale Zn metal batteries DOI

Guowei Gao, Xiaomei Huo, Boxin Li

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(20), P. 7850 - 7859

Published: Jan. 1, 2024

By constructing a hydrogel film doped with an ionic liquid on Zn anode, water-scarce inner Helmholtz plane and ion-enriched outer is developed, which effectively enables stable zinc anode for Ah-scale metal batteries.

Language: Английский

Citations

Three Birds with One Stone: Multifunctional TiN‐MXene‐Co@CNTs Network as Sulfur/Lithium Host for High‐Areal‐Capacity Lithium‐Sulfur Batteries DOI

Xintao Zuo,

Lufei Wang, Mengmeng Zhen

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(35)

Published: June 13, 2024

Abstract The inevitable shuttling and slow redox kinetics of lithium polysulfides (LiPSs) as well the uncontrolled growth Li dendrites have strongly limited practical applications lithium‐sulfur batteries (LSBs). To address these issues, we innovatively constructed carbon nanotubes (CNTs) encapsulated Co nanoparticles in situ grown on TiN‐MXene nanosheets, denoted TiN‐MXene‐Co@CNTs, which could serve simultaneously both sulfur/Li host to kill “three birds with one stone” (1) efficiently capture soluble LiPSs expedite their conversion, (2) accelerate nucleation/decomposition solid 2 S, (3) induce homogeneous deposition. Benefiting from synergistic effects, TiN‐MXene‐Co@CNTs/S cathode a sulfur loading 2.5 mg cm −2 show high reversible specific capacity 1129.1 mAh g −1 after 100 cycles at 0.1 C, ultralong cycle life over 1000 1.0 C. More importantly, it even achieves areal 6.3 50 under 8.9 low E/S ratio 5.0 μL . Besides, TiN‐MXene‐Co@CNTs deliver stable plating/striping behavior h.

Language: Английский

Citations

Conformal 3D Li/Li₁₃Sn₅ Scaffolds Anodes for High‐Areal Energy Density Flexible Lithium Metal Batteries DOI

Xiaomei Huo, Xin Gong, Yuhang Liu

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(14)

Published: Feb. 7, 2024

Abstract Achieving a high depth of discharge (DOD) in lithium metal anodes (LMAs) is crucial for developing areal energy density batteries suitable wearable electronics. Yet, the persistent growth dendrites compromises battery performance, and significant consumption during pre‐lithiation obstructs their broad application. Herein, A flexible 3D Li 13 Sn 5 scaffold designed by allowing molten to infiltrate carbon cloth adorned with SnO 2 nanocrystals. This design markedly curbs troublesome dendrite growth, thanks uniform electric field distribution swift + diffusion dynamics. Additionally, minimal nanocrystals loading (2 wt.%), only 0.6 wt.% consumed pre‐lithiation. Insights from situ optical microscope observations COMSOL simulations reveal that remains securely anchored within scaffold, result rapid mass/charge transfer distribution. Consequently, this electrode achieves remarkable DOD 87.1% at 10 mA cm −2 40 mAh . Notably, when coupled polysulfide cathode, constructed Li/Li @CC||Li S 6 /SnO @CC pouch cell delivers high‐areal capacity 5.04 an impressive areal‐energy 10.6 mWh The findings pave way toward development high‐performance LMAs, ideal long‐lasting

Language: Английский

Citations

Defect engineering enables an advanced separator modification for high-performance lithium-sulfur batteries DOI

Jian Zhou, Siwei Sun,

Xinchi Zhou

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 487, P. 150574 - 150574

Published: March 23, 2024

Language: Английский

Citations

Challenges and Solutions for Lithium–Sulfur Batteries with Lean Electrolyte DOI

Huifa Shi,

Weiyi Sun,

Jiakai Cao

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(42)

Published: Aug. 27, 2023

Abstract Lithium–sulfur (Li–S) batteries have high theoretical energy density and are regarded as next‐generation batteries. However, their practical is much lower than the value. In previous studies, increase of areal capacity cathode decrease negative/positive ratio can be well achieved, yet shows no corresponding increase. The main reason difficulty in decreasing electrolyte dosage because lean inevitably causes deterioration reaction kinetics sulfur utilization. Thus, electrolyte/active material reported works usually higher 10 µL mg −1 , that Li‐ion (usually ≈0.3 for cathode). Although many focused on this topic, a systematic discussion still rare. This review systematically discusses key challenges solutions assembling high‐performance lean‐electrolyte Li–S First, arising from conditions discussed detail. Then, approaches recent progress to reduce usage, including optimization electrode porosity ion conduction, introduction electrocatalysis, exploration new active materials, regulation, Li metal protection reviewed. Finally, future research directions proposed.

Language: Английский

Citations