Multiple-resonant nitrogen embedded nanographenes with high photoluminescence efficiency and high colour purity DOI Creative Commons
Hao Luo, Jinbei Wei,

Minqiang Mai

et al.

Journal of Materials Chemistry C, Journal Year: 2024, Volume and Issue: 12(39), P. 15888 - 15894

Published: Jan. 1, 2024

Two indolo[3,2,1- jk ]carbazole-based nanographenes (ICz-NGs) were designed and synthesized. Organic light-emitting diodes employing these ICz-NGs as emitters exhibited blue green emissions with small full width at half maxima of 18–23 nm.

Language: Английский

Heteroatom-contained carbon-rich macrocycles and carbon nanobelts: Synthesis, molecular architectures, characteristics and applications DOI
Xin Sun,

Jinku Bai,

Xinyue Wang

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 518, P. 216063 - 216063

Published: July 17, 2024

Language: Английский

Citations

1
Molecular Engineering of Rylene Diimides via Sila‐Annulation Toward High‐Mobility Organic Semiconductors DOI
Ning Xue, Kai Chen, Guogang Liu

et al.

Small, Journal Year: 2023, Volume and Issue: 20(17)

Published: Dec. 10, 2023

Abstract The continuous innovation of captivating new organic semiconducting materials remains pivotal in the development high‐performance electronic devices. Herein, a molecular engineering by combining sila‐annulation with vertical extension rylene diimides (RDIs) toward high‐mobility semiconductors is presented. unilateral and bilateral sila‐annulated quaterrylene (Si‐QDI 2Si‐QDI) are designed synthesized. In particular, symmetrical 2Si‐QDI exhibits compact, 1D slipped π – stacking arrangement through synergistic combination sizable ‐conjugated core intercalating alkyl chains. Combining appreciable elevated HOMO levels reduced energy gaps, single‐crystalline field‐effect transistors (SC‐OFETs) based on demonstrate exceptional ambipolar transport characteristics an impressive hole mobility 3.0 cm 2 V −1 s electron 0.03 , representing best ampibolar SC‐OFETs RDIs. Detailed theoretical calculations rationalize that larger transfer integral along direction responsible for achievement superior charge transport. This study showcases remarkable potential optimizing carrier performances polycyclic aromatic hydrocarbons (PAHs).

Language: Английский

Citations

3
Bowl‐Shaped Kekulene Analogues: Cycloarenes with two Five‐Membered Rings DOI Creative Commons

Hideyuki Murakami,

H Iwabuchi,

Miki Asari

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(45)

Published: May 31, 2024

Kekulene, a cycloarene composed of 12 fused benzene rings in circular arrangement, exhibits highly planar and robust structure. Kekulene has been the subject investigation into its aromaticity electronic structure, particularly relation to cyclic benzenoid. We have successfully synthesized novel bowl-shaped kekulene analogues with five-membered incorporated The results DFT calculations VT-NMR spectra indicate that inversion their concave-convex structures occurs at room temperature. NICS AICD plots predict Clar's type resonance structure is found manner analogous pristine kekulene, albeit interruption π-conjugation on sp

Language: Английский

Citations

0
Multiple-resonant nitrogen embedded nanographenes with high photoluminescence efficiency and high colour purity DOI Creative Commons
Hao Luo, Jinbei Wei,

Minqiang Mai

et al.

Journal of Materials Chemistry C, Journal Year: 2024, Volume and Issue: 12(39), P. 15888 - 15894

Published: Jan. 1, 2024

Two indolo[3,2,1- jk ]carbazole-based nanographenes (ICz-NGs) were designed and synthesized. Organic light-emitting diodes employing these ICz-NGs as emitters exhibited blue green emissions with small full width at half maxima of 18–23 nm.

Language: Английский

Citations

0