Chemical Science, Journal Year: 2024, Volume and Issue: 15(27), P. 10625 - 10637
Published: Jan. 1, 2024
Insulating polymer is harnessed as an unexpected electron tunneling mediator to boost interfacial charge migration and separation over transition metal chalcogenides for significantly enhanced solar-to-syngas conversion.
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 340, P. 123238 - 123238
Published: Aug. 28, 2023
Language: Английский
Citations
84
EcoEnergy, Journal Year: 2023, Volume and Issue: 1(2), P. 248 - 295
Published: Dec. 1, 2023
Abstract In the advancing world of graphene, highly anisotropic 2D semiconductor nanosheets, notable for their nanometer‐scale thickness, have emerged as a leading innovation, displaying immense potential in exploration renewable and clean energy production. These garnered significant attention from researchers. The nanosheets are marked by extraordinary electronic, optical, chemical attributes, positioning them attractive foundational components heterogeneous photocatalysts. This review diligently summarizes both seminal work ongoing developments pertaining to application solar within context photocatalysis. We begin detailing distinctive properties concentrating on pivotal roles augmenting photocatalytic efficiency, explaining intrinsic mechanisms that govern migration rate photogenerated carriers material's surface. Subsequently, we delineate methods employed synthesize typical nanosheets. alignment with overarching objective expanding light absorption capacity accelerating charge transfer, also examine current research hybridization techniques involving materials varied dimensions, well deployment diverse applications. conclude identifying promising avenues challenges await further this burgeoning field.
Language: Английский
Citations
67
Advanced Science, Journal Year: 2023, Volume and Issue: 10(24)
Published: June 21, 2023
Structure self-modification of graphitic carbon nitride (g-C
Language: Английский
Citations
47
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 505, P. 215691 - 215691
Published: Jan. 31, 2024
Language: Английский
Citations
47
Carbon Energy, Journal Year: 2024, Volume and Issue: 6(1)
Published: Jan. 1, 2024
Abstract Efficient photocatalytic reduction of CO 2 to high‐calorific‐value CH 4 , an ideal target product, is a blueprint for C 1 industry relevance and carbon neutrality, but it also faces great challenges. Herein, we demonstrate unprecedented hybrid SiC photocatalysts modified by Fe‐based cocatalyst, which are prepared via facile impregnation‐reduction method, featuring optimized local electronic structure. It exhibits superior carbon‐based products yield 30.0 µmol g −1 h achieves record selectivity up 94.3%, highlights the effectiveness electron‐rich Fe cocatalyst boosting performance selectivity. Specifically, synergistic effects directional migration photogenerated electrons strong π‐back bonding on low‐valence effectively strengthen adsorption activation reactants intermediates in → pathway. This study inspires effective strategy enhancing multielectron capacity semiconductor with low‐cost instead noble metals as cocatalysts.
Language: Английский
Citations
28
ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(7), P. 5275 - 5285
Published: March 25, 2024
Selective photocatalytic CO2 methanation provides an attractive avenue to address energy and environmental issues. However, impediments such as the sluggish adsorption activation of H2O molecules, along with unexpected intermediate desorption, greatly restrict activity selectivity methanation. To these issues, we devised a dual-active site catalyst comprising Cu single atoms (SAs) nanoclusters (NCs) supported on defective TiO2 (Cu1+NCs/BT). As result, remarkable CH4 98% yield 19.63 μmol gcat.–1 h–1 can be obtained over as-prepared Cu1+NCs/BT in pure water. Mechanistic studies reveal enhanced performance could ascribed synergistic effect sites, where SAs adsorb activate CO2, while NCs boost dissociation for *H coverage. Additionally, adjacent jointly stabilize *CO reduce barrier protonation, promoting multielectron transfer process.
Language: Английский
Citations
28
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151216 - 151216
Published: April 11, 2024
Language: Английский
Citations
28
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(14)
Published: Feb. 5, 2024
Abstract Photocatalytic CO 2 reduction to hydrocarbon fuels through solar energy provides a feasible channel for reducing emission and resource depletion. Nevertheless, severe charge recombination high barrier limit the efficiency. Herein, surface amine‐functionalized SnO with oxygen vacancies (A‐Vo‐SnO ) is fabricated achieve visible‐light‐driven photocatalytic reduction. Specifically, amino groups modified onto of catalyst can provide more active sites promote adsorption . Meanwhile, synchronously induced defect level reduces band‐gap expands light‐absorption region from UV light visible light. The modulate electronic structure work as separation centers spatial charges, thus promoting interfacial transfer efficiency providing catalytic sites, evidenced by experimental observation theoretical calculation. As expected, this A‐Vo‐SnO exhibits CH 4 evolution rate 17.27 µmol g −1 h without adding sacrificial agent co‐catalyst, much higher than 5.98 pure This significant inspiration design engineering based on photocatalysts towards conversion.
Language: Английский
Citations
25
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(33)
Published: May 29, 2024
Selective photocatalytic reduction of CO
Language: Английский
Citations
23
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154584 - 154584
Published: Aug. 5, 2024
Language: Английский
Citations
23