Mechanical Regulation of Polymer Gels DOI
Chenggong Xu,

Yi Chen,

Siyang Zhao

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(18), P. 10435 - 10508

Published: Sept. 16, 2024

The mechanical properties of polymer gels devote to emerging devices and machines in fields such as biomedical engineering, flexible bioelectronics, biomimetic actuators, energy harvesters. Coupling network architectures interactions has been explored regulate supportive characteristics gels; however, systematic reviews correlating mechanics interaction forces at the molecular structural levels remain absent field. This review highlights engineering gel a comprehensive mechanistic understanding regulation. Molecular alters architecture manipulates functional groups/moieties level, introducing various permanent or reversible dynamic bonds dissipative energy. usually uses monomers, cross-linkers, chains, other additives. Structural utilizes casting methods, solvent phase regulation, mechanochemistry, macromolecule chemical reactions, biomanufacturing technology construct tailor topological structures, heterogeneous modulus compositions. We envision that perfect combination may provide fresh view extend exciting new perspectives this burgeoning also summarizes recent representative applications with excellent properties. Conclusions are provided from five aspects concise summary, mechanism, biofabrication upgraded applications, synergistic methodology.

Language: Английский

Tough double network hydrogels with rapid self-reinforcement and low hysteresis based on highly entangled networks DOI Creative Commons

Zhu Ruixin,

Dandan Zhu, Zhen Zheng

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Feb. 13, 2024

Abstract Most tough hydrogels are reinforced by introducing energy dissipation mechanisms, but simultaneously realizing a high toughness and low hysteresis is challenging because the structure cannot recover rapidly. In this work, mechanical performance highly entangled double network without fabricated, in which physical entanglements act as primary effective crosslinking first network. This sliding entanglement allows hydrogel to form uniform oriented during stretching, resulting tensile strength of ~3 MPa, fracture 8340 J m −2 strain-stiffening capability 47.5 90% water content. Moreover, almost 100% reversibility obtained via storage based on entropy loss. The not only overcomes typical trade-off between hydrogels, more importantly, it provides an insight into application structures high-performance hydrogels.

Language: Английский

Citations

100
A Biomimetic “Salting Out—Alignment—Locking” Tactic to Design Strong and Tough Hydrogel DOI Creative Commons
Xia Sun, Yimin Mao, Zhengyang Yu

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(25)

Published: March 22, 2024

Abstract Recently, hydrogel‐based soft materials have demonstrated huge potential in robotics, flexible electronics as well artificial skins. Although various methods are developed to prepare tough and strong hydrogels, it is still challenging simultaneously enhance the strength toughness of especially for protein‐based hydrogels. Herein, a biomimetic “salting out—alignment—locking” tactic (SALT) introduced enhancing mechanical properties through synergy alignment salting out effect. As typical example, tensile modulus initially brittle gelatin hydrogels increase 940 folds 10.12 ± 0.50 MPa 2830 34.26 3.94 MPa, respectively, increases up 1785 14.28 3.13 MJ m −3 . The obtained hold records previously reported gelatin‐based hydrogel close tendons. It further elucidated that effect engenders hydrophobic domains, while prestretching facilitates chain alignment, both synergistically contributing outstanding properties. noteworthy SALT demonstrates remarkable versatility across different salt types polymer systems, thus opening new avenues engineering strong, tough, stiff

Language: Английский

Citations

69
An overview of conductive composite hydrogels for flexible electronic devices DOI
Jiaying Chen,

Fangfei Liu,

Tursun Abdiryim

et al.

Advanced Composites and Hybrid Materials, Journal Year: 2024, Volume and Issue: 7(2)

Published: Feb. 17, 2024

Language: Английский

Citations

66
Multiscale Structural Nanocellulosic Triboelectric Aerogels Induced by Hofmeister Effect DOI
Bin Luo, Chenchen Cai, Tao Liu

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(42)

Published: Aug. 28, 2023

Abstract The advent of self‐powered wearable electronics will revolutionize the fields smart healthcare and sports monitoring. This technological advancement necessitates more stringent design requirements for triboelectric materials. aerogels must enhance their mechanical properties to address issue structural collapse in real‐world applications. study fabricates stiff nanocellulosic with multiscale structures induced by Hofmeister effect. aggregation crystallization polymer molecular chains are enhanced effect, while ice crystal growth imparts a porous structure aerogel at micron scale. Therefore, exhibits exceptional stiffness, boasting Young's modulus up 142.9 MPa specific 340.6 kN m kg –1 , remaining undeformed even after supporting 6600 times its weight. Even withstanding an impact 343 kPa, highly robust sensors fabricated remain operational. Additionally, sensor is capable accurately detecting human movements, particularly abnormal fall postures detection. provides considerable research practical value promoting material broadening application scenarios electronics.

Language: Английский

Citations

60
Spider-silk-inspired strong and tough hydrogel fibers with anti-freezing and water retention properties DOI Creative Commons
Shaoji Wu,

Zhao Liu,

Caihong Gong

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: May 24, 2024

Abstract Ideal hydrogel fibers with high toughness and environmental tolerance are indispensable for their long-term application in flexible electronics as actuating sensing elements. However, current exhibit poor mechanical properties instability due to intrinsically weak molecular (chain) interactions. Inspired by the multilevel adjustment of spider silk network structure ions, bionic elaborated ionic crosslinking crystalline domains constructed. Bionic show a 162.25 ± 21.99 megajoules per cubic meter, comparable that silks. The demonstrated structural engineering strategy can be generalized other polymers inorganic salts fabricating broadly tunable properties. In addition, introduction salt/glycerol/water ternary solvent during constructing structures endows anti-freezing, water retention, self-regeneration This work provides ideas fabricate stability electronics.

Language: Английский

Citations

57
Silk fibroin hydrogel adhesive enables sealed-tight reconstruction of meniscus tears DOI Creative Commons

Xihao Pan,

Rui Li, Wenyue Li

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: March 26, 2024

Abstract Despite orientationally variant tears of the meniscus, suture repair is current clinical gold treatment. However, inaccessible in company with re-tears susceptibility remain unresolved. To extend meniscal tools from perspective adhesion and regeneration, we design a dual functional biologic-released bioadhesive (S-PIL10) comprised methacrylated silk fibroin crosslinked phenylboronic acid-ionic liquid loading growth factor TGF-β1, which integrates chemo-mechanical restoration inner regeneration. Supramolecular interactions β-sheets hydrogen bonds richened by (PIL) result enhanced wet adhesion, swelling resistance, anti-fatigue capabilities, compared to neat gel. Besides, elimination reactive oxygen species (ROS) S-PIL10 further fortifies localized meniscus tear affecting inflammatory microenvironment dynamic borate ester bonds, continuously releases TGF-β1 for cell recruitment bridging defect edge. In vivo rabbit models functionally evidence seamless dense reconstruction torn verifying that concept adhesive feasible providing promising revolutionary strategy preclinical research tears.

Language: Английский

Citations

51
Bioinspired Ultra‐Robust Ionogels Constructed with Soft‐Rigid Confinement Space for Multimodal Monitoring Electronics DOI
Jingwen Wang,

Yapeng Zheng,

Tianyang Cui

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(6)

Published: Oct. 22, 2023

Abstract Ionogels are compelling materials for flexible hybrid electronics owing to their attractive physical properties and infinite adjustability of chemical structures. However, ionogels must be sufficiently strong ensure durability, stability, a wide range strains in various applications make electronic systems mechanically compliant. Inspired by the hierarchical structure multiphase substances skin, it is fabricated several transparent (>90%) ultra‐robust (tensile strength >17 MPa, toughness >40 MJ m −3 , elongation ≈300%) via situ polymerization polymers with different binding abilities ionic liquid forming soft rigid confinement space. This strategy can also applied other liquids polymers. Furthermore, designed ionogel sensors used develop wearable intelligent health monitoring system capable health‐related physiological signals, such as temperature, body tremors, wrist pulse, breathing, gestures, predicting responding emergencies, which will pave way security technology.

Language: Английский

Citations

49
Research progress of Zn-air batteries suitable for extreme temperatures DOI

Ya Fang Han,

Yunyu Zhao, Yingjian Yu

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 69, P. 103429 - 103429

Published: April 23, 2024

Language: Английский

Citations

25
Tough Supramolecular Hydrogels Crafted via Lignin‐Induced Self‐Assembly DOI Creative Commons
Xiaofeng Pan,

Jiawei Pan,

Li Xiang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 10, 2024

Abstract Supramolecular hydrogels are typically assembled through weak non‐covalent interactions, posing a significant challenge in achieving ultra strength. Developing higher strength based on molecular/nanoscale engineering concepts is potential improvement strategy. Herein, super‐tough supramolecular hydrogel by gradually diffusing lignosulfonate sodium (LS) into polyvinyl alcohol (PVA) solution. Both simulations and analytical results indicate that the assembly subsequent enhancement of crosslinked network primarily attributed to LS‐induced formation gradual densification strong crystalline domains within hydrogel. The optimized exhibits impressive mechanical properties with tensile ≈20 MPa, Young's modulus ≈14 toughness ≈50 MJ m⁻ 3 , making it strongest lignin‐PVA/polymer known so far. Moreover, LS provides excellent low‐temperature stability (<‐60 °C), antibacterial, UV‐blocking capability (≈100%). Interestingly, diffusion ability demonstrated for self‐restructuring damaged hydrogel, 3D patterning surfaces, enhancing local freeze‐thaw PVA goal foster versatile platform combining eco‐friendly biocompatible PVA, paving way innovation interdisciplinarity biomedicine, materials, forestry science.

Language: Английский

Citations

24
Time-Salt Type Superposition and Salt Processing of Poly(methacrylamide) Hydrogel based on Hofmeister Series DOI
Yijie Jin, Shan Lu, Xinran Chen

et al.

Macromolecules, Journal Year: 2024, Volume and Issue: 57(6), P. 2746 - 2755

Published: Feb. 22, 2024

Breakthrough to the extreme properties of polymer networks relies on new insights into their molecular dynamics. Time-salt concentration superposition has been discovered in polyelectrolyte coacervate systems, proving instrumental tuning mechanical performance hydrogels. However, time-salt type never mentioned existing literature. Herein, we reported that poly(methacrylamide) (PMAm) hydrogel can be systematically regulated a vast range by treating with different salts, for example, Young's modulus tuned from 10–2 103 MPa. The unusual behavior salt-stiffening arises salt-enhanced phase separation network and subsequent glassy transition polymer-rich phase. Rheological results demonstrate dynamic hydrogels superposed onto "time-salt type" master curves salt types aligning along Hofmeister series. shift factor exhibits correlation mobility water molecules as revealed low-field nuclear magnetic resonance spectroscopy. A polymer–water–salt ternary interaction mechanism was proposed elucidate equivalent behavior. Guided principle, processing strategy brought up expand property limits PMAm hydrogel. With simply switching employed, could either stiff wear-resistant material akin plastics or soft flowable gel utilizable recycling.

Language: Английский

Citations

23