Supramolecular polynuclear clusters sustained cubic hydrogen bonded frameworks with octahedral cages for reversible photochromism DOI Creative Commons
Xiaojun Ding, Jing Chen, Gang Ye

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: March 30, 2024

Abstract Developing supramolecular porous crystalline frameworks with tailor-made architectures from advanced secondary building units (SBUs) remains a pivotal challenge in reticular chemistry. Particularly for hydrogen-bonded organic (HOFs), construction of geometrical cavities through has been rarely achieved. Herein, body-centered cubic HOF (TCA_NH 4 ) octahedral cages was constructed by C 3 -symmetric block and NH + node-assembled cluster (NH (COOH) 8 (H 2 O) that served as (SSBUs), akin to the polynuclear SBUs Specifically, could encapsulate four homogenous haloforms including CHCl , CHBr CHI truncated octahedron configuration. Crystallographic evidence revealed spatially-confined nanoreactors, enabling fast, broadband photochromic effect associated reversible photo/thermal transformation between encapsulated I . Overall, this work provides strategy shaping SSBUs expand framework topology HOFs prototype nanoreactors accommodate reactions.

Language: Английский

Organic Frameworks Memristor: An Emerging Candidate for Data Storage, Artificial Synapse, and Neuromorphic Device DOI
Zheng Xu, Yixiang Li, Xia Yang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(16)

Published: Jan. 4, 2024

Abstract Memristors have recently become powerful competitors toward artificial synapses and neuromorphic computation, arising from their structural electrical similarity to biological neurons. From the diversity of materials, numerous organic inorganic materials proven exhibit great potential in application memristors. Herein, this work focuses on a class memristors based frameworks (OFs) pay attention most advanced experimental demonstrations. First, typical device structures memristive switching mechanisms are introduced. Second, latest progress OFs‐based is comprehensively summarized, including metal‐organic (MOFs), covalent (COFs), hydrogen‐bonded (HOFs), as well applications data storage, synapses, devices. Finally, future challenges prospects deeply discussed.

Language: Английский

Citations

32
Orthogonal Postsynthetic Copolymerization of Hydrogen‐Bonded Organic Frameworks into a PolyHOF Membrane DOI
Xiao Liu,

Yingxiang Ye,

Xu He

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(12)

Published: Feb. 1, 2024

Abstract Hydrogen‐bonded organic frameworks (HOFs) have shown promise in various fields; however, the construction of HOF/polymer hybrid membranes that can maintain both structural and functional integrity remains challenging. In this study, we here fabricated a new HOF ( HOF‐50 ) with reserved polymerizable allyl group via charge‐assisted H‐bonds between carboxylate anion amidinium, subsequently copolymerized monomers to construct covalently bonded (polyHOF) membrane. The resulting polyHOF membrane not only exhibits customizable mechanical properties extreme stability, but also shows an exceptional ratiometric luminescent temperature‐sensing function very high sensitivity visibility even when lanthanide content is two orders magnitude lower than reported mixed‐lanthanide metal–organic (MOFs) lanthanide‐doped covalent (COFs). This orthogonal postsynthesis copolymerization strategy may provide general approach for preparing connected diverse applications.

Language: Английский

Citations

11
Multistate structures in a hydrogen-bonded polycatenation non-covalent organic framework with diverse resistive switching behaviors DOI Creative Commons
Shimin Chen,

Yan Ju,

Yisi Yang

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Jan. 5, 2024

Abstract The inherent structural flexibility and reversibility of non-covalent organic frameworks have enabled them to exhibit switchable multistate structures under external stimuli, providing great potential in the field resistive switching (RS), but not well explored yet. Herein, we report 0D+1D hydrogen-bonded polycatenation framework (HOF-FJU-52), exhibiting diverse reversible RS behaviors with high performance. Triggered by stimulus electrical E at room temperature, HOF-FJU-52 has excellent random-access memory (RRAM) behaviors, comparable state-of-the-art materials. When cooling down below 200 K, it was transferred write-once-read-many-times (WORM) behaviors. two on a single crystal device through temperature changes. mechanism this been deciphered atomic level detailed single-crystal X-ray diffraction analyses, demonstrating that dual-flexibility both asymmetric hydrogen bonded dimers within 0D loops infinite π–π stacking column between chains contribute structure transformations multi-states thus its dual

Language: Английский

Citations

10
Optically Mediated Nonvolatile Resistive Memory Device Based on Metal–Organic Frameworks DOI
Xue Yang, Jian Huang, Jingjun Li

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)

Published: July 6, 2024

Metal-organic frameworks (MOFs), characterized by tunable porosity, high surface area, and diverse chemical compositions, offer unique prospects for applications in optoelectronic devices. However, the prevailing research on thin-film devices utilizing MOFs has predominantly focused aspects such as information storage photosensitivity, often neglecting integration of advantages inherent both photonics electronics to enhance optical memory. This work demonstrates a light-mediated resistive memory device based highly oriented porphyrin-based film, which resistance state memristor is modulated light, realizing perception information. The shows excellent performance with wide light range 405-785 nm persistent photoconductivity phenomenon up 8.3 × 10

Language: Английский

Citations

8
Hydrogen‐Bonded Organic Framework Films Integrated with Wavy Structured Design for Wearable Bioelectronics DOI Open Access
Xue Yang, Tao Huang, Chang Gao

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 26, 2025

Abstract The integration of hydrogen‐bonded organic frameworks (HOFs) with flexible electronic technologies offers a promising strategy for monitoring detailed health information, owing to their inherent porosity, excellent biocompatibility, and tunable catalytic capabilities. However, application in wearable real‐time remains largely unexplored, primarily due the mechanical mismatch between traditionally fragile HOFs particles softness human skin. Herein, this study demonstrates an epidermal biosensor that maintains reliable sensing capability even under extreme deformation complex environmental conditions by integrating films wavy bioelectrodes. This ultrasensitive detection capabilities, limit 49.64 nM, accurately measures nutritional content sweat while conforming curved skin surfaces. sensor's performance is comparable those obtained using high‐performance liquid chromatography (HPLC). More strikingly, scratched can be regenerated through simple solvent rinsing process, enabling reuse fabrication new biosensors offering significant advantage over conventional materials. work has potential inspire development more devices, leveraging structural adaptability diversity personalized healthcare applications monitoring.

Language: Английский

Citations

1
Construction of 0D guanine nanospheres/2D vermiculite nanosheets heterostructures in confined space towards humidity sensing and proton migrations DOI

Lan Zhao,

Qiqi Hong,

Ningning Tan

et al.

Sensors and Actuators B Chemical, Journal Year: 2024, Volume and Issue: 410, P. 135702 - 135702

Published: March 28, 2024

Language: Английский

Citations

7
Orthogonal Postsynthetic Copolymerization of Hydrogen‐Bonded Organic Frameworks into a PolyHOF Membrane DOI
Xiao Liu,

Yingxiang Ye,

Xu He

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(12)

Published: Feb. 1, 2024

Abstract Hydrogen‐bonded organic frameworks (HOFs) have shown promise in various fields; however, the construction of HOF/polymer hybrid membranes that can maintain both structural and functional integrity remains challenging. In this study, we here fabricated a new HOF ( HOF‐50 ) with reserved polymerizable allyl group via charge‐assisted H‐bonds between carboxylate anion amidinium, subsequently copolymerized monomers to construct covalently bonded (polyHOF) membrane. The resulting polyHOF membrane not only exhibits customizable mechanical properties extreme stability, but also shows an exceptional ratiometric luminescent temperature‐sensing function very high sensitivity visibility even when lanthanide content is two orders magnitude lower than reported mixed‐lanthanide metal–organic (MOFs) lanthanide‐doped covalent (COFs). This orthogonal postsynthesis copolymerization strategy may provide general approach for preparing connected diverse applications.

Language: Английский

Citations

6
Recent progress in porous organic frameworks for electrochemical sensing of environmental pollutants DOI

Zesen Zuo,

Hao Zhang,

Sanshuang Gao

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113263 - 113263

Published: June 5, 2024

Language: Английский

Citations

6
Arylsulfonate Ionic Hydrogen-Bonded Organic Frameworks Enable Highly Stable and Superprotonic Conductivity for Enhancing Direct Methanol Fuel Cells DOI

Xiang‐Tian Bai,

Li‐Hui Cao, Zhao Fang

et al.

ACS Materials Letters, Journal Year: 2024, Volume and Issue: unknown, P. 3351 - 3357

Published: June 28, 2024

Developing proton-conducting materials with superior proton conductivity and excellent stability plays an indispensable role in the advancement of direct methanol fuel cells (DMFCs). In this work, we successfully synthesized ionic hydrogen-bonded organic framework (iHOF-13) 3D hydrogen-bonding network structures. The inherent abundance hydrogen bonding networks HOFs enables them to exhibit superprotonic conductivity. Specifically, iHOF-13 demonstrates a 1.3 × 10–1 S cm–1 at 98% relative humidity 100 °C. iHOF is enriched transport sites, its doping into Nafion matrix exhibits extremely high (10–1 cm–1) low permeability. maximum power density 7.5%-iHOF-13/Nafion composite membrane can reach 104.7 mW cm–2 DMFCs, which 2.1 times higher than that recast Nafion. incorporation high-performance facilitates enhancement pathway while effectively inhibiting crossover, thus expanding potential application cells.

Language: Английский

Citations

5
Topological hydrogen-bonded organic frameworks (HOFs) and their electronic applications in sensor, memristor, and neuromorphic computing DOI
Cheng Zhang,

Chenyu Wang,

Chao Li

et al.

Applied Physics Reviews, Journal Year: 2024, Volume and Issue: 11(3)

Published: July 8, 2024

Recently, an emerging class of hydrogen-bonded organic frameworks (HOFs) has become appealing member material family, attributed to their layered self-assembly structures, high-crystalline, and environmentally friendly characteristics, which have rapidly propelled development in the field electronic devices. In this context, we focus on latest category topological HOFs, with particular attention given cutting-edge experimental demonstrations, exceptional electrical performances, promising applications. First, a concise concept fundamental mechanism HOFs are provided, elucidating potential correlation between structural designs properties. Subsequently, comprehensive summary is presented preparation synthesis methods, such as hydrothermal techniques, epitaxial growth, electro-deposition, among others. Notably, advancements HOFs-based electronics thoroughly introduced discussed, along applications sensors, memristors, artificial synapses, neuromorphic computing, human perception systems. Finally, future challenges prospects elaborated upon aim providing valuable guidance for high-performance HOF-based electronics.

Language: Английский

Citations

5