Dyes and Pigments, Journal Year: 2025, Volume and Issue: unknown, P. 112645 - 112645
Published: Jan. 1, 2025
Language: Английский
Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)
Published: Nov. 2, 2023
Abstract Power-conversion-efficiencies (PCEs) of organic solar cells (OSCs) in laboratory, normally processed by spin-coating technology with toxic halogenated solvents, have reached over 19%. However, there is usually a marked PCE drop when the blade-coating and/or green-solvents toward large-scale printing are used instead, which hampers practical development OSCs. Here, new series N -alkyl-tailored small molecule acceptors named YR-SeNF same molecular main backbone developed combining selenium-fused central-core and naphthalene-fused end-group. Thanks to -alkyl engineering, NIR-absorbing show different crystallinity, packing patterns, miscibility polymeric donor. The studies exhibit that packing, vertical distribution active layer morphologies well optimized introducing newly designed guest acceptor associated tailored chains, providing improved charge transfer dynamics stability for PM6:L8-BO:YR-SeNF-based As result, record-high approaching 19% achieved OSCs fabricated from green-solvent o -xylene high-boiling point. Notably, ternary offer robust operating under maximum-power-point tracking well-keep > 80% initial PCEs even 400 h. Our alkyl-tailored strategy provides unique approach develop high-efficiency stable OSCs, paves way industrial development.
Language: Английский
Citations
56
Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 16(1)
Published: Nov. 23, 2023
Abstract With plenty of popular and effective ternary organic solar cells (OSCs) construction strategies proposed applied, its power conversion efficiencies (PCEs) have come to a new level over 19% in single-junction devices. However, previous studies are heavily based chloroform (CF) leaving behind substantial knowledge deficiencies understanding the influence solvent choice when introducing third component. Herein, we present case where newly designed asymmetric small molecular acceptor using fluoro-methoxylated end-group modification strategy, named BTP-BO-3FO with enlarged bandgap, brings different morphological evolution performance improvement effect on host system PM6:BTP-eC9, processed by CF ortho-xylene ( o -XY). detailed analyses supported series experiments, best PCE 19.24% for green solvent-processed OSCs is found be fruit finely tuned crystalline ordering general aggregation motif, which furthermore nourishes favorable charge generation recombination behavior. Likewise, can achieved replacing spin-coating blade coating active layer deposition. This work focuses commonly met yet frequently ignored issues building blends demonstrate cutting-edge device performance, hence, will instructive other OSC works future.
Language: Английский
Citations
56
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(19)
Published: Jan. 14, 2024
Abstract As simple and versatile tools, additives have been widely used to refine active layer morphology played a crucial role in boosting the power conversion efficiency (PCE) of organic solar cells (OSCs). Herein, three novel solvent named Th‐FSi, Th‐ClSi, Th‐BrSi with same backbone 2,5‐bis(trimethylsilyl)thiophene are designed synthesized by substituting different halogens fluorine, chlorine, bromine, respectively. Notably, Th‐ClSi exhibits more significant dipole moment engages non‐covalent interactions small‐molecule acceptor (SMA) L8‐BO, which slight adjustments intermolecular interaction, crystallinity, molecular packing PM6:L8‐BO layer. Consequently, OSCs incorporating outperform their Th‐FSi counterparts photo‐capturing, reduced energy loss, superior exciton dissociation, charge transfer properties, out‐coming yields an enhanced PCE 18.29%. Moreover, integrating near‐infrared absorbing SMA (BTP‐eC9) guest into matrix, absorption spectrum span 880–930 nm, resultant ternary achieve commendable 19.17%, ranking among highest efficiencies reported date is expanded. These findings underscore promise halogenated thiophene‐based as potent avenue for morphological fine‐tuning consequent enhancement OSCs.
Language: Английский
Citations
37
Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(12), P. 4216 - 4227
Published: Jan. 1, 2024
Pincer-shaped non-covalent bond interactions are introduced between a small-molecule additive and polymer acceptor, effectively improving the photovoltaic performance mechanical stability of all-polymer solar cells.
Language: Английский
Citations
33
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(21)
Published: Feb. 9, 2024
Abstract Ternary strategyopens a simple avenue to improve the power conversion efficiency (PCE) of organic solar cells (OSCs). The introduction wide bandgap polymer donors (PDs) as third component canbetter utilize sunlight and mechanical thermal stability active layer. However, efficient ternary OSCs (TOSCs) with two PDs are rarely reported due inferior compatibility shortage match acceptors. Herein, PDs‐(PBB‐F PBB‐Cl) adopted in dual‐PDs systems explore underlying mechanisms their photovoltaic performance. findings demonstrate that components exhibit excellent miscibility PM6 embedded host donor form alloy‐like phase. A more profound mechanism for enhancing through dual mechanisms, guest energy transfer charge transport at donor/acceptor interface, has been proposed. Consequently, PM6:PBB‐Cl:BTP‐eC9 TOSCs achieve PCE over 19%. Furthermore, better than binary reduction spatial site resistance resulting from tightly entangled long‐chain structure. This work not only provides an effective approach fabricate high‐performance TOSCs, but also demonstrates importance developing compatible PD materials.
Language: Английский
Citations
27
ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(12), P. 15121 - 15132
Published: March 19, 2024
Acquiring the ideal blend morphology of active layer to optimize charge separation and collection is a constant goal polymer solar cells (PSCs). In this paper, ternary strategy sequential deposition process were combined make sufficient use spectrum, energy-level structure, regulate vertical phase morphology, ultimately enhance power conversion efficiency (PCE) stability PSCs. Specifically, donor acceptor illustrated gradient-blended distribution in deposition-processed films, thus resulting facilitated carrier characteristics devices. Consequently, PSCs based on D18-Cl/Y6:ZY-4Cl have achieved device over 18% with synergetic improvement open-circuit voltage (VOC), short-circuit current density (JSC), fill factor (FF). Therefore, work reveals facile approach fabricating improved performance stability.
Language: Английский
Citations
21
Nature Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 29, 2025
Language: Английский
Citations
13
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 4, 2025
Abstract Ternary organic solar cells (T‐OSCs) based on energy transfer can significantly boost the light absorption efficiency, thereby improving their power conversion efficiency (PCE). However, uncontrolled distribution of third component in bulk heterojunction (BHJ) device often results low ( E FRET ), and also tends to compromise interpenetrating network structure active layer. Herein, a localized deposition strategy is proposed establish with controlled (CDBHJ). Take PM6:Y6:IBC‐F for example, IBC‐F serves as donor PM6 acceptor. Compared BHJ‐based devices, proportion within phase increases from 25.1% 72.7%, enhancing 46.5% 66.8% CDBHJ‐based devices. Furthermore, improves crystallization separation kinetics during film‐forming process. Thus, exhibits superior exciton generation, diffusion, dissociation process, along higher more balanced charge transport. Consequently, achieves PCE 18.29%, which ranks among best PM6:Y6‐based T‐OSCs. This work demonstrates effectiveness controlling component, presenting an innovative pathway development highly efficient
Language: Английский
Citations
4
Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)
Published: Feb. 20, 2025
Abstract Limited by large batch differences and inferior polymerization degree of current polymer acceptors, the potential high efficiency stability advantages all-polymer solar cells (all-PSCs) cannot be fully utilized. Alternatively, largely π-extended structurally definite oligomer acceptors are effective strategies to realize overall performance acceptors. Herein, we report a linear tetramer acceptor namely 4Y-BO with identical molecular skeleton comparable molecular-weight relative control PY-BO. The shows refined film-forming kinetics improved ordering, offering uniform crystallinity donor hence well-defined fibrous heterojunction textures. Encouragingly, PM6:4Y-BO devices achieve an up 19.75% (certified efficiency:19.58%), surpassing that PM6:PY-BO device (15.66%) ranks highest among based on More noticeably, thermal stability, photostability mechanical flexibility collectively enhanced for devices. Our study provides important approach fabricating stable organic photovoltaics.
Language: Английский
Citations
3
Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 63(3)
Published: Dec. 7, 2023
Oligomer acceptors in organic solar cells (OSCs) have garnered substantial attention owing to their impressive power conversion efficiency (PCE) and long-term stability. However, the simple efficient synthesis of oligomer with higher glass transition temperatures (T
Language: Английский
Citations
32