Stretchable Thermochromic Fluorescent Fibers Based on Self-Crystallinity Phase Change for Smart Wearable Displays DOI Open Access

Yongmei Guo,

Zixi Hu,

Luyao Zhan

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(24), P. 3575 - 3575

Published: Dec. 21, 2024

Smart fibers with tunable luminescence properties, as a new form of visual output, present the potential to revolutionize personal living habits in future and are receiving more attention. However, huge challenge smart wearable materials is their stretching capability for seamless integration human body. Herein, stretchable thermochromic fluorescent prepared based on self-crystallinity phase change, using elastic polyurethane (PU) fiber matrix, meet dynamic requirements The switching fluorescence-emitting characteristic derived from reversible conversion dispersion/aggregation state fluorophore coumarin 6 (C6) quencher methylene blue (MB) phase-change material hexadecanoic acid (HcA) during heating/cooling processes. Considering important role materials, dye encapsuled solid via piercing–solidifying method avoid dissolution HcA by organic solvent PU spinning solution maintain excellent behavior fibers. obtained wet exhibit good emission contrast reversibility, well high elasticity 800% elongation. This work presents strategy constructing human–machine interaction communications.

Language: Английский

Compatibility Enhancement of the Polylactic Acid/Polystyrene Immiscible Blend Using Reactive Graphene DOI Creative Commons
Marcos Fernando Pérez-Pucheta, Stephen C. Boothroyd,

Selene Munoz-Vargas

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: March 17, 2025

Graphene can be utilized as an additive to produce composites with outstanding properties by improving the stabilization of morphology bicontinuous blends. The structure used create novel porous materials and reduce percolation threshold when graphene is selectively localized at interface or preferentially in a single phase. This study explores effect reactive on immiscible polystyrene/polylactic acid (PS/PLA) system. Transmission electron microscopy scanning observations showed that PS/PLA system, stopping coarsening during static annealing stabilizing morphology. Dynamic rheological measurements addition had significant elastic blend. Moreover, it was shown form percolated conductive network, which also recovery upon destroying initial microstructure.

Language: Английский

Citations

0

Smart Polymer Fibers: Promising Advances in Microstructures, Stimuli-Responsive Properties and Applications DOI
Yiling Yu, Fenghua Zhang, Yanju Liu

et al.

Advanced Fiber Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 11, 2025

Language: Английский

Citations

0

Surface Tension-Driven Self-Planarization of MXene Liquid Crystalline Fiber for High-Performance Energy Storage DOI

Jin Goo Kim,

Taeyeong Yun, Go Bong Choi

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: April 18, 2025

2D MXene-based liquid crystalline (LC) systems have emerged as promising precursors for constructing highly ordered functional materials, such fibers, films, and aerogels via solution-based processing. In this study, we demonstrate surface tension-mediated self-planarization of MXene LC fibers by adjusting the solvent composition during wet-spinning, targeting improved electrochemical performance. Ethanol, a poor MXene, induced spontaneous parallel alignment platelets facilitated densification into ribbon-like geometry coagulation. The resulting featured pore volume 0.11 cm3 g-1 an average diameter 34 nm, enabling volumetric capacitance 1721.7 F cm-3 electrical conductivity 9211.66 S cm-1. mechanism underlying was investigated using range solvents with varying physicochemical properties to identify key processing parameters. were successfully implemented LED-powered supercapacitor prototypes, demonstrating potential applicability wearable energy applications.

Language: Английский

Citations

0

Recent Trends and Perspectives in Palladium Nanocatalysis: From Nanoparticles to Frameworks, Atomically Precise Nanoclusters and Single-Atom Catalysts DOI

Jun Zhou,

Didier Astruc

Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2024, Volume and Issue: 34(7), P. 2903 - 2925

Published: April 16, 2024

Language: Английский

Citations

3

Evolution of high spin state single-atom catalyst active centers in Na–O2 batteries DOI
Jing Li,

A. Y. Mao,

Jiahui Li

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(36), P. 24285 - 24295

Published: Jan. 1, 2024

Compared to O 2 @MN 4 , 3 with high spin state favors side-on mode, which enhances the coupling between 3d xy orbital of metal and hence causes evolution active center from MN (OMO)N increases performance Na–O batteries.

Language: Английский

Citations

2

Surface Optimization of Noble‐Metal‐Free Conductive [Mn1/4Co1/2Ni1/4]O2 Nanosheets for Boosting Their Efficacy as Hybridization Matrices DOI Creative Commons
Nam Hee Kwon,

Se‐Jun Kim,

Tae‐Ha Gu

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 4, 2024

Abstract Conductive 2D nanosheets have evoked tremendous scientific efforts because of their high efficiency as hybridization matrices for improving diverse functionalities nanostructured materials. To address the problems posed by previously reported conductive like poorly‐interacting graphene and cost‐ineffective RuO 2 nanosheets, economically feasible noble‐metal‐free [Mn x Co 1−2x Ni ]O oxide are synthesized with outstanding interfacial interaction capability. The surface‐optimized 1/4 1/2 outperformed /graphene in exploring high‐performance visible‐light‐active (λ >420 nm) photocatalysts. most efficient g‐C 3 N 4 –[Mn nanohybrid exhibited unusually photocatalytic activity (NH + formation rate: 1.2 mmol g −1 h ), i.e., one highest reduction efficiencies. effect defective is attributed to optimization surface bonding character electronic structure, allowing improved coordination at defect sites. Results from spectroscopic measurements theoretical calculations reveal that helps optimize bandgap energy, improves charge separation, adsorptivity, reactivity. universality nanosheet versatile corroborated improvement electrocatalytic hybridized Co−Fe‐LDH well hydrogen production ability CdS.

Language: Английский

Citations

0

Chemical Surface Metallization for Elastomers with Biphasic Liquid Metals DOI

Yang Gu,

Zixun Chen,

Yan Peng

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: 6(22), P. 13681 - 13689

Published: Nov. 7, 2024

Growing interest has been received in lightweight, cost-effective, and easily processable conductive materials with the rapid development of wearable electronics, smart robotics, bioengineering. Flexible polymer metallization is most prevalent method to inherit merits both metals elastomers. This work explores optimizes process successfully fabricates a three-layer flexible material through electroless copper plating gallium electroplating on surface The obtained this exhibits strong adhesion between coating layer soft (peel strength: 1.52 N/mm), considerable stretchability (elongation at break: 507%), high electrical conductivity (3.11 × 104 S/m), outstanding electromechanical stability (2000 cycles). Interestingly, integration photolithography enabled selective specific regions elastomer substrate, providing applications intelligent devices. contributes advancement treatment technologies based combination elastomers, which beneficial for diverse advanced including E-skin, microelectronics, nanotechnology.

Language: Английский

Citations

0

Two-dimensional materials van der Waals assembly enabling scalable smart textiles DOI

Mengyu Du,

Ziqi Li, Lifeng Bian

et al.

Materials Science and Engineering R Reports, Journal Year: 2024, Volume and Issue: 163, P. 100915 - 100915

Published: Dec. 8, 2024

Language: Английский

Citations

0

Stretchable Thermochromic Fluorescent Fibers Based on Self-Crystallinity Phase Change for Smart Wearable Displays DOI Open Access

Yongmei Guo,

Zixi Hu,

Luyao Zhan

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(24), P. 3575 - 3575

Published: Dec. 21, 2024

Smart fibers with tunable luminescence properties, as a new form of visual output, present the potential to revolutionize personal living habits in future and are receiving more attention. However, huge challenge smart wearable materials is their stretching capability for seamless integration human body. Herein, stretchable thermochromic fluorescent prepared based on self-crystallinity phase change, using elastic polyurethane (PU) fiber matrix, meet dynamic requirements The switching fluorescence-emitting characteristic derived from reversible conversion dispersion/aggregation state fluorophore coumarin 6 (C6) quencher methylene blue (MB) phase-change material hexadecanoic acid (HcA) during heating/cooling processes. Considering important role materials, dye encapsuled solid via piercing–solidifying method avoid dissolution HcA by organic solvent PU spinning solution maintain excellent behavior fibers. obtained wet exhibit good emission contrast reversibility, well high elasticity 800% elongation. This work presents strategy constructing human–machine interaction communications.

Language: Английский

Citations

0