New Journal of Chemistry, Journal Year: 2025, Volume and Issue: 49(6), P. 2014 - 2033
Published: Jan. 1, 2025
Zinc-ion batteries (ZIBs) offer safe, low-cost, high-capacity energy storage, but dendrite growth, hydrogen evolution, and corrosion limit their use. This paper reviews stability strategies research directions.
Language: Английский
Energy storage materials, Journal Year: 2024, Volume and Issue: 68, P. 103364 - 103364
Published: March 24, 2024
Language: Английский
Citations
39
Energy storage materials, Journal Year: 2024, Volume and Issue: 71, P. 103616 - 103616
Published: July 1, 2024
Language: Английский
Citations
34
Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(10), P. 3409 - 3418
Published: Jan. 1, 2024
A zinc hydroxide sulfate layer inheriting the ordered structure and porous channels of MOF was developed for high-performance Zn anodes.
Language: Английский
Citations
25
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(18)
Published: March 12, 2024
Abstract Metallic zinc is a promising anode material for rechargeable aqueous multivalent metal‐ion batteries due to its high capacity and low cost. However, the practical use always beset by severe dendrite growth parasitic side reactions occurring at anode/electrolyte interface. Here we demonstrate dynamic molecular interphases caused trace dual electrolyte additives of D‐mannose sodium lignosulfonate ultralong‐lifespan dendrite‐free anode. Triggered plating stripping electric fields, species are alternately reversibly (de‐)adsorbed on Zn metal, respectively, accelerate 2+ transportation uniform nucleation deposition inhibit Coulombic efficiency. As result, in such dual‐additive exhibits highly reversible stripping/plating behaviors >6400 hours 1 mA cm −2 , which enables long‐term cycling stability Zn||Zn x MnO 2 full cell more than 2000 cycles.
Language: Английский
Citations
23
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(25)
Published: Jan. 20, 2024
Abstract The development of aqueous rechargeable Zn metal batteries, as one the most promising large‐scale energy storage technology, is hindered largely by dendrite growth and surface passivation anode, which are deleterious to battery life Coulombic efficiency (CE). This report demonstrates that ethylenediamine tetramethylenephosphonic acid can in situ coordinate with (EDTMP‐Zn) along exposing (002) planes for highly reversible stable plating/stripping. zincophilic EDTMP‐Zn layer may serve ion sieves homogenize flux at anode consequently induce uniform deposition Zn. hydrophobic groups such functional thought circumvent from corrosion hydrogen evolution reaction. EDTMP15‐Zn modified (EDTMP15‐Zn@Zn) delivers a lifespan exceeding 1400 h 5 mA cm −2 , 1 mAh Zn||Zn symmetric cell improved CE 99.7% over 1000 cycles Zn||Cu cell. full coupled NH 4 V O 10 cathode rate performance cycle stability.
Language: Английский
Citations
22
ACS Nano, Journal Year: 2024, Volume and Issue: 18(11), P. 8452 - 8462
Published: March 1, 2024
Rampant dendrite formation and serious adverse parasitic reactions induced by migration of dissolved V/Mn cathode ions on Zn anode have hampered the high performance aqueous zinc-ion batteries (AZIBs). Inspired coordination chemistry between functional groups polymer electrolyte ions, a freestanding layer consisting dopamine-functionalized polypyrrole (DA-PPy) nanowires served as selective ion transport at anode–electrolyte interface to address these two issues, which could simultaneously avoid polarization caused introduction an additional interface. On one hand, DA-PPy displays excellent zinc charge transfer ability, well provides chemical homochanneling for interface, endow with properties guider physical barrier inhibition. other can trap excess transition metal fleeing from cathodes, thus serving barrier, preventing Vx+/Mnx+-passivation surface anode. Consequently, AZIBs based V2O5 MnO2 cathodes involving show great improvement in capacity retention.
Language: Английский
Citations
21
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(33)
Published: June 20, 2024
Developing hydrophobic interface has proven effective in addressing dendrite growth and side reactions during zinc (Zn) plating aqueous Zn batteries. However, this solution inadvertently impedes the solvation of
Language: Английский
Citations
20
iScience, Journal Year: 2025, Volume and Issue: 28(2), P. 111751 - 111751
Published: Jan. 9, 2025
Rechargeable zinc metal batteries (ZMBs) represent a promising solution for large-scale energy storage due to their safety, cost-effectiveness, and high theoretical capacity. However, the development of anodes is hindered by challenges such as dendrite formation, hydrogen evolution reaction (HER), low Coulombic efficiency stemming from undesirable interfacial processes in aqueous electrolytes. This review explores various strategies enhance anode performance, focusing on artificial SEI, morphology adjustments, electrolyte regulation, flowing electrolyte. These approaches aim suppress growth, mitigate side reactions, optimize electric double layer (EDL) Zn2+ solvation structures. By addressing these challenges, insights presented here pave way designing high-performance ZMBs, offering directions future research into scalable sustainable battery technologies.
Language: Английский
Citations
3
Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101453 - 101453
Published: Feb. 1, 2025
Language: Английский
Citations
2
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown
Published: June 5, 2024
Abstract Achieving reversible plating/stripping of zinc (Zn) anodes is crucial in aqueous Zn‐ion batteries (AZIBs). However, undesired dendrite growth and parasitic side reactions severely deteriorate battery lifespan. The construction stable protective coating an effective strategy to enhance anode stability. In this study, a multifunctional nanodiamond (ND) inorganic layer designed constructed on both Zn Cu electrodes that can effectively inhibit suppress corrosion. Experimental results theoretical calculations demonstrate artificial layer, with ultra‐high surface energy, enables the controlled creation abundant nucleation sites (in order 10 12 cm −2 ) for homogenization ion flux electric field anode. It found ions preferentially adhere diamond surfaces lower diffusion barriers, leading uniform deposition. A symmetric cell ND‐protected (Zn‐ND) exhibits behavior impressive duration over 3600 h at 1 mA . Furthermore, MnO 2 ||Zn full retains 90% its initial capacity after 3500 cycles g −1 , assembled hybrid capacitor operates smoothly 65 000 These underscore potential as promising solution achieving highly batteries.
Language: Английский
Citations
13