Physical review. E,
Journal Year:
2024,
Volume and Issue:
109(3)
Published: March 29, 2024
Physical
networks
formed
by
ionizable
polymers
with
ionic
clusters
as
crosslinks
are
controlled
coupled
dynamics
that
transcend
from
through
chain
motion
to
macroscopic
response.
Here,
the
dynamics,
across
length
scales,
in
toluene
swollen
polystyrene
sulfonate
networks,
were
directly
correlated,
electrostatic
environment
of
physical
was
altered.
The
multiscale
insight
is
attained
coupling
neutron
spin
echo
measurements
molecular
simulations,
carried
out
times
typical
relaxation
solutions.
experimental
dynamic
structure
factor
outstanding
agreement
one
calculated
computer
perturbed
elevating
temperature
and
changing
environment.
In
toluene,
long-lived
remain
stable
over
hundreds
ns
a
broad
range,
while
polymer
network
remains
dynamic.
Though
size
changes
dielectric
constant
solvent
modified
addition
ethanol,
they
but
morph,
enhancing
dynamics.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 10, 2025
Abstract
Anion
exchange
membrane
fuel
cells
(AEMFCs)
are
among
the
most
promising
sustainable
electrochemical
technologies
to
help
solve
energy
challenges.
Compared
proton
(PEMFCs),
AEMFCs
offer
a
broader
choice
of
catalyst
materials
and
less
corrosive
operating
environment
for
bipolar
plates
membrane.
This
can
lead
potentially
lower
costs
longer
operational
life
than
PEMFCs.
These
significant
advantages
have
made
highly
competitive
in
future
cell
market,
particularly
after
advancements
developing
non‐platinum‐group‐metal
anode
electrocatalysts,
anion
membranes
ionomers,
understanding
relationships
between
conditions
mass
transport
AEMFCs.
review
aims
compile
recent
literature
provide
comprehensive
three
key
areas:
i)
mechanisms
hydrogen
oxidation
reaction
(HOR)
oxygen
reduction
(ORR)
alkaline
media;
ii)
synthesis
routes
structure‐property
cutting‐edge
HOR
ORR
as
well
ionomers;
iii)
conditions,
including
water
management
impact
CO
2
.
Finally,
based
on
these
aspects,
development
perspectives
proposed.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(29)
Published: June 3, 2024
Abstract
Designing
suitable
anion
exchange
ionomers
is
critical
to
improving
the
performance
and
in
situ
durability
of
membrane
water
electrolyzers
(AEMWEs)
as
one
promising
devices
for
producing
green
hydrogen.
Herein,
highly
gas‐permeable
dimensionally
stable
(QC6xBA
QC6xPA)
are
developed,
which
bulky
cyclohexyl
(C6)
groups
introduced
into
polymer
backbones.
QC6
50
BA‐2.1
containing
mol%
C6
composition
shows
16.6
times
higher
H
2
permeability
22.3
O
than
that
0
without
groups.
Through‐plane
swelling
decreases
12.5%
from
31.1%
(QC6
BA‐2.1)
while
OH
−
conductivity
slightly
(64.9
56.2
mS
cm
−1
BA‐2.1,
respectively,
at
30
°C).
The
electrolysis
cell
using
gas
permeable
ionomer
Ni
0.8
Co
0.2
anode
catalyst
layer
achieves
two
(2.0
A
−2
1.69
V,
IR‐included)
those
previous
in‐house
(QPAF‐4‐2.0)
(1.0
IR‐included).
During
1000
h
operation
1.0
,
exhibits
nearly
constant
voltage
with
a
decay
rate
1.1
µV
after
initial
increase
voltage,
proving
effectiveness
AEMWEs.
Chemical Engineering Journal,
Journal Year:
2024,
Volume and Issue:
494, P. 153111 - 153111
Published: June 14, 2024
This
review
article
comprehensively
explores
the
significant
advancements
in
electrodialysis
(ED)
technology
within
field
of
chemical
engineering,
presenting
a
holistic
overview
that
spans
fundamental
principles,
membrane
materials
and
fabrication
techniques,
operational
parameters,
wide
array
applications.
Unlike
previous
studies
often
narrow
their
focus
to
specific
aspects
ED,
this
work
synthesizes
global
advances,
bridging
gaps
between
diverse
research
themes
offer
coherent
understanding
current
trends
future
directions.
membrane-based
separation
process
driven
by
electric
potential,
is
pivotal
for
its
applications
water
purification,
desalination,
resource
recovery,
beyond.
delves
into
evolution
ion-exchange
membranes,
highlighting
innovations
materials,
alongside
advances
techniques
enhance
selectivity
efficiency.
It
also
scrutinizes
impact
parameters
on
performance
ED
systems,
addressing
challenges
like
ion
leakage,
fouling,
balance
conductivity.
Process
intensification
system
optimization
strategies
are
discussed,
revealing
how
recent
developments
contribute
energy
efficiency,
scalability,
sustainability.
The
further
extends
emerging
sectors
ranging
from
environmental
management
hydrometallurgy
industries,
underscored
case
demonstrate
practical
implementations.
Conclusively,
underlines
multidisciplinary
approach
required
advancement
technologies,
suggesting
avenues
prioritize
impact,
economic
feasibility,
technological
innovation.
Through
perspective,
it
aims
catalyze
exploration
application
some
most
pressing
challenges.
ACS Omega,
Journal Year:
2025,
Volume and Issue:
10(4), P. 3282 - 3303
Published: Jan. 21, 2025
Scientists
worldwide
have
been
inspecting
hydrogen
production
routes
and
showing
the
importance
of
developing
new
functional
materials
in
this
domain.
Numerous
research
articles
published
past
few
years,
which
require
records
analysis
for
a
comprehensive
bibliometric
bibliographic
review
low-carbon
production.
Hence,
data
set
297
publications
was
selected
after
filtering
journal
papers
since
2010.
The
search
keywords
Scopus
Database
were
"green
hydrogen"
"low
carbon
materials".
analyzed
using
R
Bibliometrix
package.
This
made
it
possible
to
determine
total
annual
publication
rate
segregate
by
country,
author,
journal,
institution.
With
general
upward
trend
number
publications,
China
identified
as
leading
country
on
subject,
followed
Germany
Korea.
Keyword
chronological
evolution
several
important
related
topic
showed
focus
water
splitting
H2
Finally,
provides
future
directions
technologies
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 21, 2025
Abstract
Electrochemical
energy
storage
(EES)
demonstrates
significant
potential
for
large‐scale
applications
in
renewable
storage.
Among
these
systems,
vanadium
redox
flow
batteries
(VRFB)
have
garnered
considerable
attention
due
to
their
promising
prospects
widespread
utilization.
The
performance
and
economic
viability
of
VRFB
largely
depend
on
critical
components,
including
membranes,
electrodes,
electrolytes.
However,
as
the
fundamental
materials
ion
conduction,
often
struggle
effectively
balance
proton
transfer
while
preventing
crossover,
enhancing
long‐term
stability,
reducing
manufacturing
costs.
Additionally,
inherent
structural
limitations
surface
property
defects
electrode
significantly
impact
improvement
V
2+
/V
3+
electrochemical
reaction
kinetics
enhancement
power
density.
Furthermore,
composition
concentration
electrolyte
play
a
crucial
role
determining
cost
VRFB,
well
its
density
cycling
performance.
This
review
analyzes
summarizes
each
component,
reviews
evaluates
latest
research
advancements
material
modification,
optimization,
processes
components
over
past
5
years.
Moreover,
comprehensive
assessment
environmental
sustainability,
feasibility,
is
presented,
aiming
provide
strategic
guidance
commercialization
VRFB.
Carbon Neutrality,
Journal Year:
2024,
Volume and Issue:
3(1)
Published: Aug. 26, 2024
Abstract
Anion
exchange
membrane
water
electrolysis
(AEMWE)
has
seen
rapid
advancements
over
the
past
decade
due
to
its
promising
role
in
green
hydrogen
production.
Ensuring
long-term
functionality
is
as
crucial
optimizing
performance
achieve
commercial
viability
and
industrial
integration.
However,
few
studies
have
systematically
discussed
degradation
issues
of
this
technology.
Therefore,
a
thorough
understanding
AEMWE
needed
guide
design,
assembly,
operation,
maintenance
device
lifetime.
To
address
gap,
review
overviewed
heterogeneous
across
different
material
interface
levels,
focusing
on
several
key
components
including
catalysts,
ionomers,
membranes,
gas
diffusion
layers.
The
influences
these
their
interfaces
catalytic
efficiency,
active
site
density,
mass
electron
transfer
capabilities
were
discussed.
Moreover,
impacts
operation
conditions,
temperature,
electrolyte
composition,
clamping
pressure,
stable
assessed.
Accordingly,
current
mitigation
strategies
resolve
phenomena
rigorously
evaluated.
By
offering
insights
into
operations,
designing
materials,
improving
assessment
protocols
for
AEMWE,
work
will
contribute
enhancing
stability
large-scale
EES Catalysis,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
The
fundamentals
of
salt
precipitation
and
water
flooding
in
membrane
electrode
assemblies
for
acidic
electrocatalytic
CO
2
reduction
are
discussed
potential
remedies
via
engineering
electrodes,
electrolytes,
membranes
proposed.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 7, 2024
The
growing
demand
for
renewable
energy
sources
has
accelerated
a
boom
in
research
on
new
battery
chemistries.
Despite
decades
of
development
various
types,
including
lithium-ion
batteries,
their
suitability
grid-scale
storage
applications
remains
imperfect.
In
recent
years,
rechargeable
hydrogen
gas
batteries
(HGBs),
utilizing
catalytic
electrode
as
anode,
have
attracted
extensive
academic
and
industrial
attention.
HGBs,
facilitated
by
appropriate
catalysts,
demonstrate
notable
attributes
such
high
power
density,
capacity,
excellent
low-temperature
performance,
ultralong
cycle
life.
This
review
presents
comprehensive
overview
four
key
aspects
pertaining
to
HGBs:
fundamentals,
principles,
materials,
applications.
First,
detailed
insights
are
provided
into
electrodes,
encompassing
electrochemical
mechanisms,
advancements
structural
considerations
design.
Second,
an
examination
future
prospects
cathode
material
compatibility,
both
current
potential
summarized.
Third,
other
components
engineering
HGBs
elaborated,
cell
stack
design
pressure
vessel
Finally,
techno-economic
analysis
outlook
offers
the
status
indicating
orientation
further
application
advancements.
Soft Matter,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Ion-conducting
polymers
(ICPs)
are
gaining
interest
in
various
scientific
and
technological
fields.
This
review
highlights
advancements
ICP
thin
films
using
chemical
vapor
deposition
(CVD)
addresses
challenges
of
traditional
methods.