Advanced Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 10, 2025
1T-MoS2
is
considered
an
attractive
energy
storage
material
due
to
its
large
layer
spacing
and
excellent
electrical
conductivity.
Unfortunately,
difficult
synthesize
directly
the
substability,
which
limits
development
application.
Electron-filling
engineering
of
Mo
4d
orbitals
core
idea
induce
efficient
conversion
2H
1T
phase.
Based
on
this
theory,
a
homogeneous
CuS@MoS2
heterogeneous
nanosheet
successfully
constructed
based
electron-rich
CuS
as
electron
donor.
Both
density
functional
theory
(DFT)
X-ray
absorption
fine
structure
analysis
(XAFS)
illustrate
that
part
electrons
from
Cu
at
interface
are
transferred
Mo,
triggers
reorganization
formation
strong
built-in
electric
field
interface,
induces
irreversible
phase
transition
in
MoS2.
structural
features,
nanosheets
have
high
first
discharge
capacity
725
mAh
g-1
0.1
A
g-1,
rate
performance
(466.73
10
g-1),
long
cycle
stability
(506.03
after
3200
cycles
5
g-1).
This
work
provides
new
perspectives
for
high-performance
sodium
anode
materials
1T-rich
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 21, 2024
Abstract
Transition
metal
selenides
(TMSes)
are
considered
promising
candidates
for
the
anodes
of
sodium‐ion
batteries
(SIBs)
due
to
their
substantial
theoretical
capacity.
However,
TMSes
still
face
with
inferior
cycling
lifespan
caused
by
sluggish
Na
+
diffusion
kinetics
and
vigorous
volume
variations
during
dis/charge
processes.
Engineering
heterostructure
is
an
attractive
solution
rapid
transfer,
introducing
carbonaceous
materials
also
facilitates
enhanced
conductivity
structural
stability.
Herein,
CoSe/MoSe
2
combined
homogeneous
carbon
composites
rational
designed.
The
kinetic
analysis
calculations
verified
that
heterointerface
engineering
induced
build‐in
electric
field
effect
can
amplifies
kinetics,
while
contributes
electrical
Expectedly,
‐C
exhibits
high
capacity
extremely
ultra‐long
(320.9
mAh
g
−1
at
2.0
A
over
10,000
cycles
average
decay
only
0.01781
per
cycle).
Furthermore,
in
situ
X‐ray
diffraction
(XRD),
ex
photoelectorn
(XPS),
high‐resolution
electron
microscopy
(HRTEM)
exploited
explore
storage
mechanism.
In
addition,
3
V
(PO
4
)
@rGO//CoSe/MoSe
(NVP@rGO//CoSe/MoSe
‐C)
pouch‐type
full‐cells
successfully
assembled
delivered
satisfactory
performance.
This
research
presents
a
viable
strategy
targeted
aimed
enhancing
efficiency
SIBs.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 6, 2024
Abstract
Transition
metal
sulfides
as
anode
materials
for
sodium‐ion
batteries
(SIBs)
have
the
advantage
of
high
capacity.
However,
their
cycle‐life
and
rate
performance
at
ultra‐high
current
density
is
still
a
thorny
issue
that
limit
applicability
these
materials.
In
this
paper,
carbon‐embedded
heterojunction
with
sulfur‐vacancies
regulated
by
ultrafine
bimetallic
(vacancy‐CoS
2
/FeS
@C)
robust
interfacial
C‐S‐Co/Fe
chemical
bonds
successfully
synthesized
explored
an
material
battery.
By
changing
ratio
two
cations,
concentration
anion
sulfur
vacancies
can
be
in‐situ
adjusted
without
additional
post‐treatment.
The
as‐prepared
vacancy‐CoS
@C
offers
ultrahigh
(285.1
mAh
g
−1
200
A
),
excellent
long‐cycle
stability
(389.2
40
after
10000
cycles),
outperforming
all
reported
transition
sulfides‐based
SIBs.
Both
ex‐situ
characterizations
provide
strong
evidence
evolution
mechanism
phases
stable
solid‐electrolyte
interface
(SEI)
on
surface.
functional
theory
calculations
show
constructing
reasonable
significantly
increase
electronic
conductivity.
Notably,
assembled
@C//Na
3
V
(PO
4
)
/C
full‐cell
shows
capacity
226.2
400
cycles
2.0
,
confirming
material's
practicability.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(29), P. 11229 - 11266
Published: Jan. 1, 2024
This
paper
reviews
advancements
in
flexible
carbon-based
and
polymer
gel
materials
for
various
types
of
energy
storage
systems,
providing
guidance
future
development
next-generation
wearable
electronics.
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 1, 2024
Abstract
Anion
doping
engineering
is
recognized
as
a
prospective
strategy
to
adjust
the
electronic
configuration
and
transport
capacity
of
carbon‐based
magnetoelectric
hybrids
optimize
defects
for
modulation
electromagnetic
(EM)
properties.
This
study
effectively
accomplishes
an
overwhelming
enhancement
in
dielectric
coupling
between
conduction
polarization
CuCo
bimetallic/carbon
system
by
employing
situ
(N,
O)/ex
(S,
Se)
defect
strategies.
The
well‐designed
lattice
distortions
are
facilitated
large
atomic
radii
(Se)
intercalated
carbon
skeleton
bimetallic
CuCo,
which
activate
reinforcement
dipole
high‐frequency
region.
Interestingly,
appropriate
number
vacancies
acts
“electron
traps”
accelerate
local
charge
redistribution,
endowing
with
extremely
strong
interactions
interface‐induced
polarization.
It
remarkable
that
ultra‐thin
feature
(1.8
mm)
able
achieve
extraordinary
microwave
attenuation
(‒56.1
dB).
Additionally,
specific
upgrading
anionic
Se
beneficially
hinders
development
phonon
transmission,
conferring
Cu
2
Se/CoSe
/NC‐Se
aerogel
outstanding
infrared
stealth
capabilities
along
inheriting
advantages
traditional
(lightness,
compressive/structural
stability,
hydrophobicity/anti‐corrosive
properties).
research
offers
distinctive
perspectives
on
advanced
design
multifunctional
absorbers
complex
environments.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(29)
Published: June 3, 2024
Abstract
Exploring
efficient
and
low‐toxicity
radiosensitizers
to
break
through
the
bottleneck
of
radiation
tolerance,
immunosuppression
poor
prognosis
remains
one
critical
developmental
challenges
in
radiotherapy.
Nanoheterojunctions,
due
their
unique
physicochemical
properties,
have
demonstrated
excellent
radiosensitization
effects
energy
deposition
lifting
tumor
radiotherapy
inhibition.
Herein,
they
doped
selenium
(Se)
into
prussian
blue
(PB)
construct
a
nano‐heterojunction
(Se@PB),
which
could
promote
increase
Fe
2+
/Fe
3+
ratio
conversion
Se
high
valence
state
with
introduction.
The
‐Se‐Fe
electron
transfer
chain
accelerates
rate
on
surface
nanoparticles,
turn
endows
it
X‐ray
transport
capability,
enhances
physical
sensitivity.
Furthermore,
Se@PB
induces
glutathione
(GSH)
depletion
accumulation
pro‐Fenton
reaction,
thereby
disturbs
redox
balance
cells
biochemical
sensitivity
As
an
radiosensitizer,
effectively
induced
mitochondrial
dysfunction
DNA
damage,
promotes
cell
apoptosis
synergistic
cervical
cancer
This
study
elucidates
mechanism
Se‐doped
nanoheterojunction
from
perspective
biochemistry
provides
low‐toxic
strategy
ACS Applied Energy Materials,
Journal Year:
2024,
Volume and Issue:
7(9), P. 3523 - 3539
Published: April 15, 2024
Energy
storage
devices
have
become
indispensable
for
smart
and
clean
energy
systems.
During
the
past
three
decades,
lithium-ion
battery
technologies
grown
tremendously
been
exploited
best
system
in
portable
electronics
as
well
electric
vehicles.
However,
extensive
use
limited
abundance
of
lithium
made
researchers
explore
sodium-ion
batteries
(SIBs)
an
alternative
to
lithium.
Throughout
few
years,
rapid
progression
has
represented
a
noteworthy
advancement
field
technologies.
This
review
discusses
recent
advancements
SIBs,
focusing
on
methodologies
improve
performance
cathode
anode
materials,
evolution
electrolytes
toward
solvent-free
electrolytes,
fast-charging
low-temperature
SIBs.
work
also
highlights
some
that
empowered
electrochemical
five
years.
It
concludes
emerging
routes
enhance
overall
batteries,
leading
comparable
with
Li-ion
future
research.
