Industrial & Engineering Chemistry Research,
Journal Year:
2024,
Volume and Issue:
63(45), P. 19568 - 19577
Published: Oct. 29, 2024
Flexible
conductive
elastomers
play
a
pivotal
role
in
biosensing,
electronic
skin,
and
wearable
devices.
However,
fabricating
self-healing
with
superior
mechanical
properties
remains
formidable
challenge.
Here,
we
introduce
simple
strategy
for
the
preparation
of
flexible
elastomer
that
integrates
stretchability,
conductivity,
capabilities.
Initially,
lipoic
acid
(LA)
deep
eutectic
solvents
(DES)
are
thermally
initiated
ring-opening
copolymerized,
yielding
linear
copolymer
P(LA-DES).
This
polymer
is
then
integrated
polyurethane
by
intermolecular
hydrogen
bonds,
followed
incorporation
Fe3+
ions
to
form
dynamic
cross-linked
network
containing
disulfide
metal
coordination.
supramolecular
not
only
exhibits
remarkable
but
also
demonstrates
stable
reliable
signal
response
capabilities
when
used
as
strain
sensor.
The
possesses
tensile
strength
4.63
MPa
an
elongation
at
break
893%,
electrical
conductivity
up
2.67
×
10–4
S·m–1.
Moreover,
it
achieves
healing
efficiency
exceeding
90%
subjected
80
°C
24
h.
Additionally,
elastomer-based
sensor
capable
sensitively
detecting
human
joint
motion,
underscoring
its
potential
applications
realm
devices
health
monitoring.
Giant,
Journal Year:
2024,
Volume and Issue:
19, P. 100321 - 100321
Published: July 11, 2024
Biomimetic
damping
materials
have
emerged
as
promising
candidates
for
various
applications
due
to
their
ability
mimic
the
exceptional
properties
observed
in
biological
systems.
This
review
provides
a
comprehensive
overview
of
recent
advances
field
biomimetic
gel
materials.
The
conceptual
framework
is
discussed,
synthesis
methods
inspired
by
principles
are
elucidated,
and
key
considerations
material
selection
highlighted.
latest
research
findings
on
mechanical
properties,
biocompatibility
practical
these
synthesized
insights
into
future
directions
offered.
Industrial & Engineering Chemistry Research,
Journal Year:
2024,
Volume and Issue:
63(45), P. 19568 - 19577
Published: Oct. 29, 2024
Flexible
conductive
elastomers
play
a
pivotal
role
in
biosensing,
electronic
skin,
and
wearable
devices.
However,
fabricating
self-healing
with
superior
mechanical
properties
remains
formidable
challenge.
Here,
we
introduce
simple
strategy
for
the
preparation
of
flexible
elastomer
that
integrates
stretchability,
conductivity,
capabilities.
Initially,
lipoic
acid
(LA)
deep
eutectic
solvents
(DES)
are
thermally
initiated
ring-opening
copolymerized,
yielding
linear
copolymer
P(LA-DES).
This
polymer
is
then
integrated
polyurethane
by
intermolecular
hydrogen
bonds,
followed
incorporation
Fe3+
ions
to
form
dynamic
cross-linked
network
containing
disulfide
metal
coordination.
supramolecular
not
only
exhibits
remarkable
but
also
demonstrates
stable
reliable
signal
response
capabilities
when
used
as
strain
sensor.
The
possesses
tensile
strength
4.63
MPa
an
elongation
at
break
893%,
electrical
conductivity
up
2.67
×
10–4
S·m–1.
Moreover,
it
achieves
healing
efficiency
exceeding
90%
subjected
80
°C
24
h.
Additionally,
elastomer-based
sensor
capable
sensitively
detecting
human
joint
motion,
underscoring
its
potential
applications
realm
devices
health
monitoring.