Amphibious Multifunctional Hydrogel Flexible Haptic Sensor with Self-Compensation Mechanism DOI Creative Commons
Zhenhao Sun,

Yunjiang Yin,

Baoguo Liu

et al.

Sensors, Journal Year: 2024, Volume and Issue: 24(10), P. 3232 - 3232

Published: May 19, 2024

In recent years, hydrogel-based wearable flexible electronic devices have attracted much attention. However, sensors are affected by structural fatigue, material aging, and water absorption swelling, making stability accuracy a major challenge. this study, we present DN-SPEZ dual-network hydrogel prepared using polyvinyl alcohol (PVA), sodium alginate (SA), ethylene glycol (EG), ZnSO4 propose self-calibration compensation strategy. The strategy utilizes metal salt solution to adjust the carrier concentration of mitigate resistance drift phenomenon improve in amphibious scenarios, such as land water. ExpGrow model was used characterize trend ∆R/R0 dynamic response curves hydrogels stress tests, average deviation fitted ϵ¯ calculated quantify differences different groups. results showed that uncompensated group lower than compensated utilizing LiCl, NaCl, KCl, MgCl2, AlCl3 solutions (ϵ¯ air 276.158, 1.888, 2.971, 30.586, 13.561 times higher AlCl3, respectively; seawater 10.287 times, 1.008 1.161 4.986 1.281 respectively, MgCl2 AlCl3). addition, for ranking effect solutions, ionic radius charge cation were found be important factors determining effect. Detection events environments swallowing, robotic arm grasping, Morse code, finger–wrist bending also performed study. This work provides viable method enhancement with strain pressure sensing capabilities offers sensor applications both airborne underwater environments.

Language: Английский

Polycation-regulated hydrogel electrolytes with nanoscale hydrophobic confinement inducing Zn(002) deposition for highly reversible zinc anodes DOI
Xilin Wang, Bin Wang,

Pengyang Lei

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(18), P. 6640 - 6655

Published: Jan. 1, 2024

A polycation-regulated hydrogel electrolyte with nanoscale hydrophobic confinement addresses dendrites, corrosion, and lifespan issues in AZIBs by regulating the electric field, enhancing Zn 2+ migration, guiding Zn(002) plane growth.

Language: Английский

Citations

17
Polymer gels for aqueous metal batteries DOI
Tianfu Zhang, Keliang Wang,

Hengwei Wang

et al.

Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101426 - 101426

Published: Jan. 1, 2025

Citations

2
Weakening the Space Charge Layer Effect Through Tethered Anion Electrolyte and Piezoelectric Effect Toward Ultra‐Stable Zinc Anode DOI
Zhipeng Wen,

Zuyang Hu,

Xiangwen Wang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 12, 2024

The space charge layer (SCL) dilemma, caused by mobile anion concentration gradient and the rapid consumption of cations, is fundamental reason for generation zinc dendrites, especially under high-rate discharge conditions. To address issue, a physical (PbTiO

Language: Английский

Citations

13
An Ultrahigh‐Modulus Hydrogel Electrolyte for Dendrite‐Free Zinc Ion Batteries DOI Open Access
Zong‐Ju Chen, Tianyu Shen, Xiong Xiao

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 14, 2024

Abstract Quasi‐solid‐state aqueous zinc ion batteries suffer from anodic dendrite growth during plating/stripping processes, impeding their commercial application. The inhibition of dendrites by high‐modulus electrolytes has been proven to be effective. However, hydrogel are difficult achieve high modulus owing inherent water contents. This work reports a electrolyte with ultrahigh that can overcome the stress through mechanical suppression effect. By combining wet‐annealing, solvent‐exchange, and salting‐out processes tuning hydrophobic crystalline domains, is obtained substantial content (≈70%), (198.5 MPa), toughness (274.3 MJ m −3 ), zinc‐ion conductivity (28.9 mS cm −1 which significantly outperforms previously reported poly(vinyl alcohol)‐based hydrogels. As result, exhibits excellent dendrite‐suppression effect achieves stable performance in Zn||Zn symmetric (1800 h cycle life at 1 mA −2 ). Moreover, Zn||V 2 O 5 pouch display cycling operate stably even under extreme conditions, such as large bending angle (180°) automotive crushing. provides promising approach for designing mechanically reliable advanced batteries.

Language: Английский

Citations

13
Recent advances and perspectives of 1D/2D carbon materials for high-performance flexible zinc ion batteries DOI

Qingqing Zheng,

Zewei Hu, Liyang Liu

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(33), P. 21531 - 21552

Published: Jan. 1, 2024

This review provides a summary of recent advancements in 1D/2D carbon materials (carbon nanotubes, graphene, MXenes, and fibers) for FZIBs. It mainly introduces the functions enhancing performance

Language: Английский

Citations

10
Ultra-Thin Amphiphilic Hydrogel Electrolyte for Flexible Zinc-ion Paper Batteries DOI
Huan Xia, Wei Zhang, Chunyang Miao

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(18), P. 6507 - 6520

Published: Jan. 1, 2024

The paper-like ZIBs can be folded and unfolded using the Miura folding technique, enhancing areal energy density by a factor of 18.

Language: Английский

Citations

10
Hydrogel Electrolyte with Electron/Ion Dual Regulation Mechanism for Highly Reversible Flexible Zinc Batteries DOI

Fusheng Luo,

Yang Song, Qing Yang Steve Wu

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The unique electron/ion dual regulation mechanism is established in the well-designed hydrogel electrolyte by integrating polyacrylamide network and carboxylated multi-walled carbon nanotubes for high performance flexible ZIBs.

Language: Английский

Citations

9
Water-Restrained Hydrogel Electrolytes with Repulsion-Driven Cationic Express Pathways for Durable Zinc-Ion Batteries DOI Creative Commons
Dewu Lin,

Yushuang Lin,

R. Pan

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: March 19, 2025

Abstract The development of flexible zinc-ion batteries (ZIBs) faces a three-way trade-off among the ionic conductivity, Zn 2+ mobility, and electrochemical stability hydrogel electrolytes. To address this challenge, we designed cationic named PAPTMA to holistically improve reversibility ZIBs. long branch chains in polymeric matrix construct express pathways for rapid transport through an repulsion mechanism, achieving simultaneously high transference number (0.79) conductivity (28.7 mS cm −1 ). Additionally, reactivity water hydrogels is significantly inhibited, thus possessing strong resistance parasitic reactions. Mechanical characterization further reveals superior tensile adhesion strength PAPTMA. Leveraging these properties, symmetric employing deliver exceeding 6000 h reversible cycling at 1 mA −2 maintain stable operation 1000 with discharge depth 71%. When applied 4 × 2 pouch cells MnO as cathode material, device demonstrates remarkable operational mechanical robustness 150 cycles. This work presents eclectic strategy designing advanced that combine enhanced reactions, paving way long-lasting

Language: Английский

Citations

1
Biopolymer‐Based Gel Electrolytes for Advanced Zinc Ion Batteries: Progress and Perspectives DOI

Renjie Jia,

Chuanliang Wei, Benhua Ma

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

Abstract In recent years, aqueous zinc ion batteries (ZIBs) with ultra‐high safety and environmental friendliness have emerged as a promising candidates for energy storage conversion devices. However, the severe side reactions dendrites issues discourage practical application of ZIBs. Recently, biopolymer‐based gel electrolytes disclosed large potential in tackling these challenges ZIBs, numerous advancements reported. Their advantages lie suppressing including hydrogen evolution Zn metal anode corrosion, well inhibiting growth dendrites. This review comprehensively examines classification, structures properties electrolytes, focus on hydrogel derived from various natural macromolecular biopolymers, along brief discussion non‐hydrogel using ionic liquids or organic solutions solvents. Subsequently, preparation physical chemical methods are summarized. Furthermore, applications ZIBs diverse cathodes materials introduced. Finally, it highlights benefits excellent electrochemical performance outlining their prospects next generation proposing future perspectives.

Language: Английский

Citations

7
Superelastic hydrogel electrolyte incorporating helical protein molecules as zinc ion transport pathways to enhance cycling stability of zinc metal batteries DOI

Xiaoyun Xu,

Songmei Sun, Shubin Yang

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A superelastic, high ionic conductivity and environment-friendly hydrogel electrolyte is developed based on the unique advantages of α-helical proteins.

Language: Английский

Citations

6