Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: 493, P. 138264 - 138264
Published: April 16, 2025
Language: Английский
Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: 493, P. 138264 - 138264
Published: April 16, 2025
Language: Английский
Angewandte Chemie, Journal Year: 2025, Volume and Issue: unknown
Published: March 10, 2025
Abstract The general understanding on the reaction path is that electrocatalytic N 2 reduction follows either individual associative alternating or distal pathways, where efficient activation and selective NH 3 production are very challenging. Herein, an unconventional “alternating‐distal” pathway was achieved by shifting “*NHNH →*NH ” to + step boost synthesis with amorphous CeMnO x electrocatalyst. In this process, realized through π back donation Mn site, while Mn/Ce dual active sites could regulate intermediate configurations avoid nitrogen‐containing by‐product formation. Such affirmed in situ spectroscopic analyses theoretical calculations. a neutral media, average ammonia rate of 82.8 µg h −1 mg outstanding Faradaic efficiency 37.3% were attained. This work validated mechanism synthesis, which might be extended other catalytic process multiple possible paths.
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125254 - 125254
Published: March 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161956 - 161956
Published: March 1, 2025
Language: Английский
Citations
0Materials Research Bulletin, Journal Year: 2025, Volume and Issue: unknown, P. 113472 - 113472
Published: April 1, 2025
Language: Английский
Citations
0Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: 493, P. 138264 - 138264
Published: April 16, 2025
Language: Английский
Citations
0