Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131234 - 131234
Published: Dec. 1, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131234 - 131234
Published: Dec. 1, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2025, Volume and Issue: 354, P. 128696 - 128696
Published: Feb. 1, 2025
Language: Английский
Citations
8Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131343 - 131343
Published: Dec. 1, 2024
Language: Английский
Citations
4ACS Materials Letters, Journal Year: 2024, Volume and Issue: 6(9), P. 3925 - 3931
Published: July 26, 2024
Pillar-layered structures represent a significant category within MOFs; however, the exploration of their chemical stability and systematic functionalization has been largely neglected. Herein, we fabricated pillar-layered MOF (Zn-LC–C) with fsc topology, utilizing tetradentate carboxylic ligand bipyridine Zn(II) ions via approach. Notably, this topological structure displays markedly superior compared typical MOFs pcu topology. In addition, by introducing unsaturated bonds to modify increase length pillars, three additional (Zn-LN=N, Zn-LC=C, Zn-LC≡C) were obtained. Compared those Zn-LC–C, adsorption capacities for C2H2 other have improved. Strikingly, dynamic uptake Zn-LN=N is as high 53.7 cm3 g–1, separation ratio C2H2/CO2 3.2. These results demonstrate that introduction diazo groups in pillar can enhance C2H2.
Language: Английский
Citations
3Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131860 - 131860
Published: Jan. 1, 2025
Language: Английский
Citations
0Composites Part B Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 112414 - 112414
Published: March 1, 2025
Language: Английский
Citations
0AIChE Journal, Journal Year: 2025, Volume and Issue: unknown
Published: May 19, 2025
Abstract One‐step purification of ethylene (C 2 H 4 ) from complex crude C products containing acetylene ), ethane 6 and carbon dioxide (CO impurities is highly critical desirable. Herein, we customize the pore environments with versatile dense adsorption sites in a novel interpenetrated adsorbent, Zn‐mtz‐ina, to simultaneously remove , CO . As result, Zn‐mtz‐ina exhibits benchmark capacity for (3.01 mmol g −1 IAST selectivity /C (4.7), along low uptake (1.60 among reported similar adsorbents. Dynamic breakthrough experiments confirm direct production polymer‐grade (>99.9%) /CO (1/33/33/33, v/v/v/v gas mixture high productivity 0.36 under ambient conditions. The underlying separation mechanisms guest–host interactions are elucidated through gas‐loaded single crystal analysis, density functional theory calculations, visualized Hirshfeld surface analysis.
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130094 - 130094
Published: Oct. 1, 2024
Language: Английский
Citations
2Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 358, P. 130359 - 130359
Published: Nov. 2, 2024
Language: Английский
Citations
2Adsorption, Journal Year: 2024, Volume and Issue: 31(1)
Published: Nov. 30, 2024
Language: Английский
Citations
2Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131049 - 131049
Published: Dec. 1, 2024
Language: Английский
Citations
2