Znln2S4 photocatalyst composite with phosphorus-modified MOF-derived cobalt/carbon nanoparticles for efficient visible-light-driven water splitting H2 production DOI

Ao-Sheng She,

Yanxin Chen, Wen Chen

et al.

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 139, P. 806 - 817

Published: May 29, 2025

Language: Английский

Hierarchically porous three-dimensional-ordered macro-microporous metal-organic frameworks: Design, precise synthesis, and applications DOI

Shilong Wen,

Qiuju Fu,

Liting Yan

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 517, P. 215996 - 215996

Published: June 19, 2024

Language: Английский

Citations

18

Enigma of Sustainable CO2 Conversion to Renewable Fuels and Chemicals Through Photocatalysis, Electrocatalysis, and Photoelectrocatalysis: Design Strategies and Atomic Level Insights DOI Open Access

Diksha Suri,

Srimanta Das,

Shivani Choudhary

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Growing global population, escalating energy consumption, and climate change threaten future security. Fossil fuel combustion, primarily coal, oil, natural gas, exacerbates the greenhouse effect driving warming through CO

Language: Английский

Citations

6

Mesoporous single-crystal metal–organic frameworks DOI
Yingji Zhao, Yusuke Yamauchi

Nature Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 22, 2025

Language: Английский

Citations

3

Recent strategies to improve the electroactivity of metal–organic frameworks for advanced electrocatalysis DOI Creative Commons

Runzhi Wei,

Xiao Li, Aziz B. Ibragimov

et al.

Deleted Journal, Journal Year: 2024, Volume and Issue: 1(2), P. 181 - 206

Published: Aug. 4, 2024

Abstract Metal–organic frameworks (MOFs) have emerged as promising materials in the realm of electrocatalysis due to their high surface area, tunable porosity, and versatile chemical functionality. However, practical application has been hampered by inherent limitations such low electrical conductivity a limited number active metal sites. Researchers addressed these challenges through various strategies, including enhancing incorporating conductive nanoparticles, modifying structure composition MOFs replacing nodes functionalizing linkers, preparing catalysts thermal processes decarburization conversion into oxides, phosphides (MPs), sulfides (MSs). This review provided comprehensive summary strategies that were employed enhance electroactivity for improved electrocatalytic performance recent years. It also explored future directions potential innovations design synthesis MOF‐based electrocatalysts, offering valuable insights advancing sustainable energy technologies.

Language: Английский

Citations

11

Spatially Immobilized PtPdFeCoNi as an Excellent Bifunctional Oxygen Electrocatalyst for Zinc–Air Battery DOI Open Access

Mingkuan Xie,

Yu Lu, Xinke Xiao

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 20, 2024

Abstract Developing efficient oxygen electrocatalysts with low cost, high catalytic activity, and robust stability remains a formidable challenge for rechargeable zinc–air batteries (ZABs). Herein, highly dispersed ultrasmall PtPdFeCoNi high‐entropy alloy nanoparticles size of ≈ 2 nm randomly distributed multimetallic single atoms spatially immobilized on the 3D hierarchically ordered porous nitrogen‐doped carbon skeleton (denoted as PtPdFeCoNi/HOPNC) are successfully synthesized via ultra‐rapid Joule heating process. The spatial immobilization HOPNC is key to dispersion multi‐active sites electrocatalysts, formed hierarchical pore structure conducive successful construction rapid mass transfer channel. As result, as‐prepared PtPdFeCoNi/HOPNC exhibits positive half‐wave potential 0.866 V versus RHE reduction reaction (ORR), overpotential 310 mV at 10 mA cm −2 evolution (OER), Tafel slopes both ORR OER. Furthermore, ZAB using bifunctional catalysts excellent rate performances superior cycling stability, surpassing that commercial Pt/C‐RuO mixture. strategy provides new idea design synthesis various applications.

Language: Английский

Citations

11

Nanocatalytic Medicine Enabled Next-Generation Therapeutics for Bacterial Infections DOI Creative Commons
Min Ge, Feng Jiang, Han Lin

et al.

Materials Today Bio, Journal Year: 2024, Volume and Issue: 29, P. 101255 - 101255

Published: Sept. 17, 2024

Language: Английский

Citations

5

Photocatalytic Semi‐Hydrogenation of Acetylene to Polymer‐Grade Ethylene with Molecular and Metal–Organic Framework Cobaloximes DOI Creative Commons

A. Stone,

Anna Fortunato, Xijun Wang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Abstract The semi‐hydrogenation of acetylene in ethylene‐rich gas streams is a high‐priority industrial chemical reaction for producing polymer‐grade ethylene. Traditional thermocatalytic routes reduction to ethylene, despite progress, still require high temperatures and H 2 consumption, possess relatively low selectivity, use noble metal catalyst. Light‐powered strategies are starting emerge, given that they have the potential directly abundant sustainable solar irradiation, but ineffective. Here an efficient, >99.9% selective, visible‐light powered, catalytic conversion ethylene reported. catalyst homogeneous molecular cobaloxime operates tandem with photosensitizer at room temperature bypasses non‐environmentally friendly flammable feed. proceeds through cobalt‐hydride intermediate ≈100% under competitive (ethylene co‐feed) conditions after only 50 min, no evolution or over‐hydrogenation ethane. further incorporated as linker metal–organic framework; result heterogeneous can be recycled up six times remains catalytically active 48 h, before significant loss performance observed.

Language: Английский

Citations

5

Hierarchically ordered meso-/macroporous MOF-based materials for catalysis and energy applications DOI

Anqian Hu,

Qiongyi Xie,

Liyu Chen

et al.

EnergyChem, Journal Year: 2024, Volume and Issue: 6(6), P. 100137 - 100137

Published: Oct. 30, 2024

Language: Английский

Citations

4

High-effective, convenient and environmental-friendly MOFs-chitosan-glyoxal composite film for ceftizoxime adsorption: Behavior and mechanisms DOI

Menghan Qin,

Detian Dou,

Yinghua Zhu

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: unknown, P. 137077 - 137077

Published: Oct. 1, 2024

Language: Английский

Citations

3

Research Progress of Cobalt-Based Metal Organic Frameworks and Their Derivatives in Energy Storage and Conversion DOI Creative Commons
Jiqing Zhang,

Enze Zhu,

Ruotong Li

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(47), P. 46643 - 46663

Published: Nov. 13, 2024

With the rapid development of modern society, efficient and utilization new energy have become more important. The high-performance storage conversion devices has a decisive impact on sustainable use energy. In foreseeable future, exploration high-quality functional materials for will continue to be main goal pursued by scientific application fields. Metal organic frameworks (MOFs) merits adjustable porosity stable structure. Moreover, metal elements in MOFs could play role as active sites during electrochemical process. Thus, various kinds their derivatives been prepared used conversion. this work, applications potentials cobalt-based (Co-MOFs) supercapacitors, advanced batteries, catalysts reviewed summarized. properties, mechanisms, effects performance were described depth. A large number Co-MOFs with unique structures, well numerous Co-MOF composites, developed, excellent achieved, which already some most advantageous field. addition, current research status, difficulties, prospects Co-based comprehensively summarized at end study.

Language: Английский

Citations

3