Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
The
time-dependent
phosphorescence
colors
(TDPC)
towards
anti-Kasha
emission
from
the
T
2
energy
level
was
activated
by
coordination
effects
in
multi-component
system
TPy-BA/ZnCl
/PVA.
Advanced Optical Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 18, 2025
Abstract
The
exploration
of
phosphorescence
supramolecular
soft
materials
with
both
sufficient
mechanical
and
photophysical
properties
is
crucial
for
their
practical
optoelectronic
applications.
Herein,
robust
hydrogels
are
conveniently
constructed
by
green
one‐pot
copolymerization
monoalkene‐functionalized
iodoisoquinolinium
derivatives
(G),
exfoliated
Laponite
(LP)
nanosheets,
acrylamide
(AAm)
monomers
in
aqueous
solution.
Compared
the
G
molecule
exhibiting
single
fluorescence
emission
at
454
nm,
electrostatically
driven
co‐assembly
complementary
negatively
charged
LP
not
only
induces
an
emerging
room‐temperature
(RTP)
peak
centered
on
547
nm
but
also
creates
polymerizable
noncovalent
precursor
crosslinkers,
which
can
be
further
covalently
thermopolymerized
AAm
into
polymeric
RTP
hydrogels.
Owing
to
synergistic
dual
covalent
cross‐linkings,
synthetic
possess
high
strength,
rapid
self‐healing
ability,
transparency,
as
well
improved
performance
even
tolerant
temperatures.
Fascinatingly,
efficient
long‐lived
red‐shifted
emissions
up
777
readily
achieved
incorporating
ultralow
content
(≈0.5%)
acceptors
via
a
delayed
sensitization
strategy.
Ultimately,
potential
multi‐channel
imaging
applications
these
realized
living
HeLa
cells,
contributes
effective
strategy
preparing
advanced
phosphorescent
points
new
direction
exploring
biotechnological
Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
The
time-dependent
phosphorescence
colors
(TDPC)
towards
anti-Kasha
emission
from
the
T
2
energy
level
was
activated
by
coordination
effects
in
multi-component
system
TPy-BA/ZnCl
/PVA.