Single-atom catalysts in the catalytic production of H2O2 DOI Creative Commons
Zhiqi Li, Zhihan Yu,

Chen Guan

et al.

Journal of Materiomics, Journal Year: 2024, Volume and Issue: unknown, P. 100982 - 100982

Published: Dec. 1, 2024

Language: Английский

Cd Single Atom as an Electron Mediator in an S‐Scheme Heterojunction for Artificial Photosynthesis of H2O2 DOI Creative Commons
Xiaowen Ruan,

Minghua Xu,

Chunsheng Ding

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 13, 2025

Abstract Developing conductor‐mediated S‐scheme heterojunction photocatalysts imitating natural photosynthetic systems emerges as a promising approach to hydrogen peroxide (H 2 O ) production. However, achieving precise coupling between two semiconductors with charge shuttle and modulating the interfacial interactions still remain significant bottleneck. Herein, we propose catalyst architecture Cd single atom mediated formed by interfacing CdS TiO nanoparticles. This exhibits an H production rate high 60.33 µmol g −1 min under UV–vis light irradiation, which is attributed efficient transport at interface of thanks S‐scheme. In‐situ X‐ray photoelectron spectroscopy (XPS) electron spin resonance (ESR) spin‐trapping tests confirm transfer route. Femtosecond transient absorption (fs‐TA) other ex‐situ characterizations further corroborate across interface. work offers new perspective on constructing atoms heterojunctions enhance photocatalytic performance.

Language: Английский

Citations

1
Trap Engineering in Violet Antimony Phosphorus: Modulating Photoelectron Transfer Pathways for Enhanced Photocatalytic Hydrogen Evolution DOI

Xuewen Zhao,

Xiaolu Bai,

Rui Zhai

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125166 - 125166

Published: Feb. 1, 2025

Language: Английский

Citations

1
Synthesis of borocarbonitride nanosheets from biomass for enhanced charge separation and hydrogen production DOI Creative Commons
Zhishan Luo, Jinhao Chen,

Yuanmeng Fang

et al.

Scientific Reports, Journal Year: 2024, Volume and Issue: 14(1)

Published: June 23, 2024

Abstract Borocarbonitride (BCN) materials have shown significant potential as photocatalysts for hydrogen production. However, traditional bulk BCN exhibits only moderate photocatalytic activity. In this study, we introduce an environmentally conscious and sustainable strategy utilizing biomass-derived carbon sources to synthesize nanosheets. The evolution efficiency of BCN-A nanosheets (110 μmol h −1 g ) exceeds that (12 by 9.1 times, mainly due the increased surface area (205 m 2 presence numerous active sites with enhanced charge separation capabilities. Notably, offer key advantages such sustainability, cost-effectiveness, reduced footprint during These findings highlight biomass-based nanomaterials facilitate a greener more efficient route energy, contributing global transition towards renewable energy solutions.

Language: Английский

Citations

4
Metal-nitrogen coordinated single atomic photocatalysts for solar energy conversion DOI
Yiqiao Wang,

Liling Liao,

Gangqiang Zhu

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216254 - 216254

Published: Oct. 15, 2024

Language: Английский

Citations

4
Internal Nanocavity Regulation of Embedded Rare Earth Up‐Conversion Nanoparticles for H2O2 Production Operable at Up to 780 nm DOI Open Access
Ben Chong, Honghui Ou, Baorong Xu

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 24, 2025

Abstract Semiconductor photocatalysts embedded with rare earth upconversion nanoparticles (REUPs) are a promising strategy to improve their photoresponse range, but photocatalytic performance within the near‐infrared (NIR) region is far from satisfactory. Here, method reported activity by adjusting nanocavity of inside semiconductor. Two types CdS NaYF 4 :Yb,Er core‐shell structure (no cavity) (NYE/CdS) and yolk‐shell (empty (NYE@CdS) synthesized different methods. Experimental theoretical analysis indicates that NYE@CdS can enhance local fluorescence‐induced electric field hollow cavity, realize more effective energy transfer REUPs CdS. Notably, H 2 O production reaches 0.33 mmol g −1 h under NIR light irradiation ( λ > 780 nm), exceeding most photocatalysts. This research will provide new ideas for design high‐efficiency production.

Language: Английский

Citations

0
Electro-Fenton process for wastewater treatment: From selective H2O2 generation to efficient •OH conversion DOI

Jialong Yin,

Heng Zhang, Meng-Fan Luo

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160709 - 160709

Published: Feb. 1, 2025

Language: Английский

Citations

0
Synergistic Mechanism of Hydroxyl Regulation and a Polyvinylpyrrolidone Surfactant in Enhancing the Catalytic Oxidation Abilities of BiOBr DOI Creative Commons
Yiran Zhang,

Bin Xuan,

Jiekai Wang

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(6), P. 1286 - 1286

Published: March 13, 2025

The rational design of BiOBr photocatalysts with optimized surface properties and enhanced photooxidative capacities is crucial. This study proposes a synergistic strategy combining hydroxyl-rich solvents polyvinylpyrrolidone (PVP) surfactants to modulate the structural electronic through solvothermal approach. resulting self-assembled microspheres demonstrated exceptional efficiency in degrading ciprofloxacin (CIP), methyl orange (MO), rhodamine B (RhB). Among synthesized variants, BiOBr-EG-PVP (fabricated ethylene glycol PVP) exhibited highest photocatalytic activity, achieving near-complete removal 20 mg/L CIP RhB within 10 min under visible light irradiation, degradation rates 60.12–101.73 times higher than pristine BiOBr. characterization revealed that (EG) not only induced formation but also introduced abundant hydroxyl groups, which simultaneously hole-mediated oxidation capabilities. incorporation PVP further promoted development hierarchical honeycomb-like synergistically both group density potential interfacial engineering. Density functional theory (DFT) calculations confirmed performance originated from an increased oxygen content. work elucidates effects surfactant modification fabrication advanced BiOBr-based photocatalysts, providing new insights for high-performance photocatalysis environmental remediation.

Language: Английский

Citations

0
Nb2C MXene quantum dots modulate built-in electric field within heterostructures for efficient solar-to-H2O2 conversion from seawater DOI

Yamei Huang,

Xinglin Wang, Huihui Zhang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125262 - 125262

Published: March 1, 2025

Language: Английский

Citations

0
Inducing Exciton Dissociation in Covalent Organic Framework by Local Gradient Ionic Polarization for Enhanced Hydrogen Peroxide Photosynthesis DOI

Ruijuan Bian,

Yang Deng, Li Yang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125292 - 125292

Published: March 1, 2025

Language: Английский

Citations

0
Metal-free two-dimensional nanomaterials supported single atom catalysts for energy conversion DOI
Yong Wan, Mingming Zhang, Cui Lai

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180261 - 180261

Published: April 1, 2025

Language: Английский

Citations

0