High Conductivity in PEDOT:PSS Thin‐Films by Secondary Doping with Superacid Vapor: Mechanisms and Application to Thermoelectrics DOI Creative Commons
Juhyung Park, Jeong Han Song,

Jae Gyu Jang

et al.

Advanced Physics Research, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

Abstract Poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), a conductive polymer, have attracted attention as promising materials for future electronic applications, owing to its tunable doping level high electrical conductivity ( σ ) through simple post‐treatments. A novel post‐treatment method conventionally doped PEDOT:PSS thin‐films (immersed in methanol) is presented further enhance via with the superacid, trifluoromethanesulfonic acid (TFSA). The origin of improved treated this dual approach investigated. study reveals that superacid vapor treatment uniquely enhances lamellar stacking PEDOT chains and induces vertical phase separation between PSS, leading carrier mobility by factor three. This behavior differs from conventional post‐treatments, making combined methanol immersion TFSA an effective strategy achieving ≈2053 S cm −1 , these films ideal candidates various polymer‐based electronics. Furthermore, findings demonstrate thermoelectric power subjected secondary exhibits threefold enhancement (104.2 µW m K −2 compared samples solely (29.7 ). resulting insights will advance understanding mechanisms charge transport polymers.

Language: Английский

Rational design of amorphous vanadium pentoxide and hollow porous carbon spheres hybrid for superior zinc-ion battery DOI

Lina Li,

Sai Dong,

Wenchao Peng

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 677, P. 608 - 616

Published: Aug. 13, 2024

Language: Английский

Citations

8

Unraveling the correlation between reduced thickness and enhanced electrical conductivity in HNO3-treated PEDOT:PSS ultrathin nanofilms DOI
Minghua Kong, Qinglin Jiang, Wenkai Zhong

et al.

Materials Today Nano, Journal Year: 2025, Volume and Issue: 29, P. 100574 - 100574

Published: Jan. 6, 2025

Language: Английский

Citations

0

The Multifaceted Role of 3D Printed Conducting Polymers in Next-Generation Energy Devices: A Critical Perspective DOI Creative Commons
Nipun Jain, Yusuf Olatunji Waidi

JACS Au, Journal Year: 2025, Volume and Issue: 5(2), P. 411 - 425

Published: Jan. 22, 2025

The increasing human population is leading to growing consumption of energy sources which requires development in devices. modern iterations these devices fail offer sustainable and environmentally friendly answers since they require costly equipment produce a lot waste. Three-dimensional (3D) printing has spurred incredible innovation over the years variety fields clearly an attractive option because technology can create unique geometric items quickly, cheaply, with little Conducting polymers (CPs) are significant family functional materials that have garnered interest research community their high conductivity, outstanding sustainability, economic significance. They extensive number applications involving supercapacitors, power sources, electrochromic gadgets, electrostatic components, conducting pastes, sensors, biological thanks special physical electrical attributes, ease synthesis, appropriate frameworks for attachment. use three-dimensional become popular as exact way enhance prepared networks. Rapid technological advancements reproducing patterns building structures enable automated deposition intricate structures. Different composites been created using oxides metals carbon improve efficiency CPs. Such actively investigated exceptional producers low-power electronic techniques, by range applications, verified surface area, remarkable electrochemical behavior. hybridization such produced equipment, gathering energy, protective storage facilities. A few possible uses CPs sensors discussed this perspective. We also provide overview key strategies scientific industrial eye on potential improvements future.

Language: Английский

Citations

0

Electrospray and Assembly of PEDOT:PSS on Silver Nanowires for Multifunctional Stretchable Electronic Membranes DOI
Ming Li, Wei Peng,

Chunfa Ye

et al.

ACS Applied Electronic Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 10, 2025

Language: Английский

Citations

0

A Biocompatible Infrared Rewritable Technique Based on Flexible Conjugated Polymer PEDOT:DSS DOI Open Access

Ganghui Wei,

Qiong Li, Lan Ni

et al.

Advanced Materials Technologies, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 18, 2025

Abstract With the rapid advancement of information technology, security has become a major challenge in contemporary society. Optical cryptography gained attention as key research area due to its unique multi‐dimensional storage and large‐capacity features. In this study, novel infrared rewritable PEDOT:DSS film (IRR‐PDF) is introduced, that demonstrates excellent biocompatibility flexibility. Furthermore, it can efficiently regulate thermal emission through simple redox treatment be written erased reversibly. Additionally, operational principles IRR‐PDF modulating imaging are explored. This investigation reveals core mechanisms behind phenomenon involve modulation polar transport properties PEDOT molecules by agents regulation changes crystal conformation during process. The discovery opens up new possibilities for practical applications direct writing cryptographic encryption. PEDOT:DSS, which distinguishes from other conductive polymers such poly(3,4‐ethylenedioxythiophene):(styrenesulfonate) (PEDOT:PSS), allows widely used smart wearables field. It also establishes crucial technological link with high‐capacity features optical cryptography, provides insights material foundations future advancements security.

Language: Английский

Citations

0

A microneedle sensor for in-vivo sodium ion detection in plants DOI

Cheng-Xiao Fan,

Zhuo Wang, Zhi-Hao Wang

et al.

Analytica Chimica Acta, Journal Year: 2025, Volume and Issue: 1352, P. 343892 - 343892

Published: March 7, 2025

Language: Английский

Citations

0

Electrically Conductive Functional Polymers and Application Progress in Lithium Batteries DOI Open Access
Zhe Huang,

Mengting Lyu,

Nan Meng

et al.

Polymers, Journal Year: 2025, Volume and Issue: 17(6), P. 778 - 778

Published: March 14, 2025

Electrically conductive functional polymers (ECFPs) have attracted much attention not only for their electron conductivity but also versatile properties, including redox activity, flexibility, and designability. These attributes are expected to enhance the energy density mechanical compatibility of lithium batteries while mitigating safety risks associated with such batteries. Furthermore, ECFPs key candidates as active materials, current collectors, coatings, binders, additives in storage conversion systems, especially development flexible batteries, dry electrodes, solid-state However, low conductivity, poor environmental stability, instability dopants, high costs limit usage production large-scale applications. In this review, two major electrically polymer species conjugated radical structures focused on reveal mechanisms. Moreover, strategies improving performance these summarized, which include molecular design optimize enhanced addition hydrophobic groups or protective coatings improve resistance, a side-chain that is self-doping introduce high-stability multifunctional systems through compositing two-dimensional carbon-based materials. Additionally, green processes renewable resource applications introduced aim creating cost-effective sustainable preparation technologies. The advancement structural engineering optimization will facilitate potentially expansive devices.

Language: Английский

Citations

0

Preventing Benzoquinone‐Based Catalyst Aggregation Enables the One‐Step Synthesis of Highly Conductive Poly(benzodifurandione) without Post‐Reaction Purification DOI Creative Commons
Jun‐Da Huang, Qifan Li, Qingqing Wang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

Abstract Conductive polymers have become crucial in advancing various electronic applications. While p‐type materials like poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) are widely used and produced at scale, the development of high‐performance n‐type has lagged due to challenges synthesis scalability. In this work, a novel method is introduced synthesize highly conductive polymer poly(benzodifurandione) (PBFDO) using α‐tocopherylquinone (α‐TQ) as catalyst. This approach eliminates need for post‐reaction dialysis, major obstacle large‐scale PBFDO production. By preventing catalyst aggregation, high electrical conductivity (>1320 S cm −1 ) achieved, which remains stable air over 180 d, significantly simplifying process. The α‐TQ‐synthesized also exhibits excellent thermoelectric properties, with power factor exceeding 100 µW m K −2 , placing it among highest‐performing polymers. Additionally, residual α‐TQ acts plasticizer, reducing elastic modulus by tenfold while maintaining conductivity, making material suitable mechanically compliant electronics. Similarly, lowers thermal more than an order magnitude. process scalable, demonstrated producing high‐conductivity ink 20 L reactor. work presents efficient sustainable

Language: Английский

Citations

0

Laser Beam Machining of Janus Porous Electrodes for Long‐term Electrophysiological Sensing DOI Open Access
Yu Zhou,

Zaifu Huang,

Yan Chen

et al.

Advanced Materials Technologies, Journal Year: 2025, Volume and Issue: unknown

Published: March 23, 2025

Abstract Flexible epidermal electrodes have attracted significant attention for their ability to conform irregular surfaces, with comfortable and non‐invasive sensing performance. However, challenges remain regarding conformality, breathability, contact interfacial impedance. This work introduces an ultrathin, trim‐paste, inexpensive Janus porous electrode by laser beam machining. The micron‐pore‐sized exhibit exceptional breathability sweat permeability in less than 1s. In addition, the ultrathin profiles, a thickness of only 23 µm, ultralight weight 0.12 g. Porous can be trimmed pasted onto human skin or objects variety shapes sizes as required. particular, kirigami demonstrate stretchability, elongation at break up 350%. used detect electromyography electrocardiogram signals, showing superior performance compared commercial gel electrodes, especially sweat‐rich environment.

Language: Английский

Citations

0

Transparent conductive PEDOT–graphene films from large-flake graphite DOI
Sean T. McDermott, Brenden Ferland, J.R. Liu

et al.

Synthetic Metals, Journal Year: 2025, Volume and Issue: unknown, P. 117866 - 117866

Published: March 1, 2025

Language: Английский

Citations

0