Topological Defect‐Regulated Porous Carbon Nanoribbon for High‐Performance Potassium‐Ion Batteries DOI
Yongsheng Zhou,

Yingchun Zhu,

You Liu

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Abstract Potassium‐ion batteries (PIBs) using carbonaceous anode materials have attracted a great deal of research interest. However, the large atomic size potassium ions inevitably leads to huge volume expansion and collapse anodes during intercalation, which greatly hinders rate performance cycling life. In this work, carbon nanotube‐derived porous N‐doped nanoribbon (CNR) bundles are designed as an for PIBs. These CNR in rich defects provide fast channels charge transport abundant active sites ion storage. The exhibit maximum capacity 441.4 mA h g −1 at current density 0.2 A after 200 cycles well highly reversible 263.6 5.0 even 1000 cycles. This work provides guidance structure design high‐performance

Language: Английский

Structural Design and Interface Modification with Selective H+ Binding of 3D Zinc Anode for Aqueous Zinc‐Ion Batteries DOI
Ming Lu,

Bo‐Hao Xiao,

Yu Wei Lu

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 2, 2025

Abstract The reversible cycling lifespan of zinc‐ion batteries is fundamentally compromised by the hydrogen evolution reaction (HER) and growth Zn dendrites induced tips on 2D zinc metal anodes. Herein, a 3D alloy anode to effectively mitigate dendrite HER through dual regulation interface presented. Experimental results confirm that second component with strong H + adsorption can efficiently inhibit ads desorption diffusion, thereby suppressing HER. Moreover, robust interaction between in‐situ derived solid electrolyte interphase (SEI) layer 2+ also enhances diffusion kinetics, reduces nucleation energy barriers, achieving dendrite‐free deposition . as‐prepared Zn‐W anodes achieve up 2400 h coulombic efficiency 99.23% achieved in symmetrical cells exceed 200 when operated at depth discharge as high 91.46%. This work provides simple effective approach toward enhancing safety while significantly improving utilization efficiency.

Language: Английский

Citations

0

High-performance AA-stacked χ3 borophene anode material for sodium and zinc-ion batteries DOI
Qingying Jia, Zhao Liu, Ying Liu

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 113, P. 115588 - 115588

Published: Feb. 7, 2025

Language: Английский

Citations

0

Engineering the local micro-environment of active materials in rechargeable alkali metal based batteries DOI
Rongnan Guo, Zixu Sun,

Jinhai He

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 533, P. 216525 - 216525

Published: Feb. 21, 2025

Language: Английский

Citations

0

Enhanced Stability of Sodium‐Ion Batteries by Controlling the Synthesis Process of Binary Metal Sulfides DOI Creative Commons

Wenbo Qiu,

Zidong Wang,

Zhao Hua-ping

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 27, 2025

Abstract Binary metal sulfides hold significant promise as anode materials for advanced sodium‐ion batteries (SIBs), but their application is often limited by rapid capacity degradation and slow reaction kinetics. While carbon composites are frequently used to address these issues, the influence of sequence carbonization sulfidation on performance has been largely overlooked. To bridge this gap, Co‐Sn synthesized through various processes examine impact synthesis methods material properties. Among these, one‐step CSS‐C1 exhibits enhanced kinetics excellent stability. It delivers a 220.4 mAh g −1 at an ultra‐high current density 20 A maintained 389 over 2300 cycles 10 . When assembled into full‐cell devices (CSS‐C1||Na 3 V 2 (PO 4 ) ), it demonstrates stable retention 900 cycles, establishing highly efficient SIBs.

Language: Английский

Citations

0

Advanced Aqueous Electrolytes for Aluminum-Ion Batteries: Challenges and Opportunities DOI
Michael Ruby Raj, Karim Zaghib, Gibaek Lee

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104211 - 104211

Published: March 1, 2025

Language: Английский

Citations

0

Tin Disulfide Nanosheet as Cathode Materials for Rechargeable Aluminum Ion Batteries: Synthesis, Electrochemical Performance, and Mechanism DOI Creative Commons
Ruiyuan Zhuang,

Xinming Tan,

Yuxin Wang

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(8), P. 1649 - 1649

Published: April 8, 2025

Aluminum ion batteries (AIBs) exhibit a promising development prospect due to their advantages such as high theoretical specific capacity, safety, low cost, and sufficient raw material sources. In this work, nanosheet tin disulfide (SnS2) was successfully prepared using the hydrothermal method then used cathode for AIBs. The synthesized nano-flake SnS2 has large size thin thickness, with of about 900 nm thickness 150 nm. This electrode effectively enhances contact interface electrolyte shortens depth travel distance deintercalation. As an electrode, battery obtained residual discharge capacity 55 mAh g-1 coulombic efficiency 83% after 600 cycles. Furthermore, first-principles calculation results show that energy storage mechanism is deintercalation behavior Al3+. Based on model analysis results, it can be seen compared position between two sulfur atoms, Al3+ more inclined deintercalated directly above atom. study provides fundamental data large-scale preparation AIBs application research

Language: Английский

Citations

0

Co-solvent strategy for rechargeable post-lithium metal batteries DOI
Xu Liu, Xu Dong, Henry Adenusi

et al.

Nature Reviews Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 28, 2025

Language: Английский

Citations

0

Research on the sodium-ion storage behavior of bituminous coal-derived anodes DOI
Junli Kong,

Chen Quan-bin,

Zhijiang Su

et al.

Powder Technology, Journal Year: 2025, Volume and Issue: unknown, P. 121094 - 121094

Published: May 1, 2025

Language: Английский

Citations

0

Rigid‐Flexible Coupling Realized by Synergistic Engineering of the Graphitic‐Amorphous Architecture for Durable and Fast Potassium Storage DOI Creative Commons

Mingchi Jiang,

Ning Sun, Bin Cao

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 22, 2024

Abstract Graphite anodes hold great potential for potassium‐ion batteries (PIBs), yet their practical application is hindered by poor cycle performance caused substantial interlayer expansion. Herein, a partial graphitic carbon (PGC) elaborately engineered via the catalytic effect of ferric citrate using pitch as precursor. Systematically varying catalyst content enables an optimal PGC design integrating highly graphitized phase providing abundant active sites K‐ion intercalation, balanced with amorphous region that accommodates volume expansion and facilitates ion diffusion. The optimized PGC12 electrode exhibits high reversible capacity 281.9 mAh g −1 , characterized prolonged low‐potential plateau region, excellent stability retention 94.8% after 300 cycles. It also realizes impressive rate capability retained 222.2 at 1 C. Moreover, assembled full‐cell delivers exceptional energy density 148.2 Wh kg . In‐situ XRD DFT simulations further verify distinct transition mechanisms reaction dynamics across different configurations. This work elucidates impact configurations on K‐storage proposes structural model efficient storage, which instrumental in rational advancement PIBs.

Language: Английский

Citations

1

Topological Defect‐Regulated Porous Carbon Nanoribbon for High‐Performance Potassium‐Ion Batteries DOI
Yongsheng Zhou,

Yingchun Zhu,

You Liu

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Abstract Potassium‐ion batteries (PIBs) using carbonaceous anode materials have attracted a great deal of research interest. However, the large atomic size potassium ions inevitably leads to huge volume expansion and collapse anodes during intercalation, which greatly hinders rate performance cycling life. In this work, carbon nanotube‐derived porous N‐doped nanoribbon (CNR) bundles are designed as an for PIBs. These CNR in rich defects provide fast channels charge transport abundant active sites ion storage. The exhibit maximum capacity 441.4 mA h g −1 at current density 0.2 A after 200 cycles well highly reversible 263.6 5.0 even 1000 cycles. This work provides guidance structure design high‐performance

Language: Английский

Citations

1