Commercially Applicable One-Step Method to Construct Homogeneous Anode/Electrolyte Interface and Cathode/Electrolyte Interface Layers in All-Solid-State Lithium–Sulfur Batteries DOI
Jianhui Du,

Wanli Sha,

Chong Luo

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(51), P. 71019 - 71029

Published: Dec. 11, 2024

Using a solid electrolyte is considered to be the most effective strategy solve shuttle effect in lithium–sulfur batteries. However, practical application of solid-state batteries (SLSBs) still far from being realized. This because SLSBs, like all other battery systems, also face dilemma interface degradation (including both anode and cathode interfaces), addition terrible kinetics due nonliquid electrolytes infiltrating nonconductive sulfur particles inside cathode. It necessary consider factors associated with cathode, anode, electrolyte, interfaces an integrated manner problems existing SLSBs. Similar anode/electrolyte formation liquid this work simultaneously synthesized situ cathode/electrolyte by one-step electrochemically inducing polymerization thiophene monomers poly(ethylene oxide) electrolyte. By screening adjustment process, dual ion-electron conductive layer on sides as well inner surface was synthesized. As result these improvements, ionic conductivity 1.1 × 10–4 S cm–1 achieved composited at 40 °C while maintaining specific capacity 1166.6 mAh g–1 after 50 cycles SLSBs assembled. study regulated emphasized important role homogeneity might extended production applications its competitiveness technology economy.

Language: Английский

Interfacial Lithium-Ion Transportation in Solid-State Batteries: Challenges and Prospects DOI Creative Commons
Ming Liu, Ailing Song, Xinyi Zhang

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: 136, P. 110749 - 110749

Published: Feb. 7, 2025

Language: Английский

Citations

3
Building a Better All-Solid-State Lithium-Ion Battery with Halide Solid-State Electrolyte DOI
Chao Li, Yaping Du

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 21, 2025

Since the electrochemical potential of lithium metal was systematically elaborated and measured in early 19th century, lithium-ion batteries with liquid organic electrolyte have been a key energy storage device successfully commercialized at end 20th century. Although battery technology has progressed enormously recent years, it still suffers from two core issues, intrinsic safety hazard low density. Within approaches to address challenges, development all-solid-state (ASSLBs) based on halide solid-state electrolytes (SSEs) displayed for application stationary devices may eventually become an essential component future smart grid. In this Review, we categorize summarize current research status SSEs different halogen anions perspective chemistry, upon which synthetic routes possessing high room-temperature ionic conductivity, compare detail performance terms activation energy, electronic interfacial contact stability, window corresponding optimization strategies each above-mentioned indicators. Finally, provide outlook unresolved challenges opportunities ASSLBs.

Language: Английский

Citations

1
Highly Safe All‐Solid‐State Lithium Metal Battery Enabled by Interface Thermal Runaway Regulation Between Lithium Metal and Solid‐State Electrolyte DOI
Zijie Lin, Qiushi Yao,

Shi‐Jie Yang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 23, 2025

Abstract All‐solid‐state (ASS) Li‐metal batteries are regarded as promising energy‐storage devices due to their high energy density and improved safety. Recently, the interface thermal runaway issues between reactive solid‐state electrolytes (SSEs) have attracted increasing attention, but it has been less studied. Here, using in situ high‐resolution imaging, a significant stress‐release period before catches fire burns Li metal 1.5 Al 0.5 Ge (PO 4 ) 3 (LAGP) SSE is found that can provide opportunities for early warning batteries. Further, highly safe ASS battery without external pressure package reported by constructing stable heterogeneous layer (HIL) consisting of ALD‐coated aluminum oxide PECVD‐deposited amorphous silicon (a‐Si), which significantly reduces exothermic reaction suppresses both theoretically experimentally. The symmetric shows long cycling stability at RT temperature over 150 °C being least 8‐times higher than one HIL. assembled Li‐CO 2 capable 100 cycles with <3.2 V low charge potential 500 mAg −1 °C. This work paves way development next‐generation high‐energy lithium

Language: Английский

Citations

1
Strategies to Boost the Safety and Ionic Conductivity of Lithium‐Ion Batteries Using Solid State Electrolytes: A Review DOI Open Access

Savitha Hosamane,

Nagaraju Kottam,

A. Suresh

et al.

Wiley Interdisciplinary Reviews Energy and Environment, Journal Year: 2025, Volume and Issue: 14(1)

Published: Jan. 2, 2025

ABSTRACT The enormous potential of lithium‐ion batteries (LIBs) to provide environmentally sustainable practices and efficient energy storage has led a rising interest in LIBs. Thermal runaway behaviors LIBs, including high temperature, ejection, combustion, explosion, the release toxic gases, as well thermal failure propagation battery pack, are both possible. Here, briefly mentioned about solid‐state electrolytes (SSE), which may use make LIBs safer by reducing these risks. However, SSE's ionic conductivity is subpar when compared that other liquid electrolytes, demanding modification. authors have also focused on several SSE types this review, inorganic SSE, solid polymer (SPEs), composite electrolytes. Additionally, it was described how enhance SSEs at ambient temperature.

Language: Английский

Citations

0
Self-purification and surface-coordination dual-polymer/Li6.4La3Zr1.4Ta0.6O12 interphase achieves Li+-transport-enhanced composite solid-state electrolyte DOI

Yaqin Ji,

Haoran Du, Kang Wang

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 646, P. 237289 - 237289

Published: May 10, 2025

Language: Английский

Citations

0
Proton conduction induced weak negative permittivity and low frequency dispersion in activated carbon felt-polyaniline metacomposites DOI
Jingyu Bi, Benli Du, Zihao Guo

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 163470 - 163470

Published: May 1, 2025

Language: Английский

Citations

0
Recent Advances in Poly(ethylene oxide)-Based Solid-State Electrolytes for Lithium-Ion Batteries DOI
Jiajia Tan,

Lingxiao Guo,

Jinming Hu

et al.

The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: 128(41), P. 17197 - 17218

Published: Oct. 8, 2024

Poly(ethylene oxide) (PEO)-based solid polymer electrolytes are pivotal in advancing high-energy-density solid-state battery technology, particularly for lithium-ion and other rechargeable batteries. PEO-based regarded as promising due to their high conductivity stability. However, conventional linear PEO exhibits limited ionic conductivity, attributed the crystallinity of ethylene oxide (EO) chains. This impedes ion migration, at low temperatures. Various strategies have been employed reduce enhance electrolytes. Moreover, electrochemical window compatibility with both electrodes critical. Scientists investigated diverse approaches interfacial performance better Review summarizes latest research advancements batteries, emphasizing enhancements transport properties, mechanical performance, stability, structural design optimization, exploration new electrolyte systems. Finally, challenges future prospects these materials discussed.

Language: Английский

Citations

2
Electrolyte additives for bulk-type all-oxide solid-state lithium-ion batteries DOI
Otmane Zoubir, Abdelfettah Lallaoui, Zineb Edfouf

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 104, P. 114592 - 114592

Published: Nov. 20, 2024

Language: Английский

Citations

1
Silica gel combing with zinc nanoparticles as high-rate and long-cycle anodes for lithium-ion batteries DOI
Yijie Wu, Mingzhu Li,

Baoyang Liu

et al.

Journal of Physics and Chemistry of Solids, Journal Year: 2024, Volume and Issue: unknown, P. 112538 - 112538

Published: Dec. 1, 2024

Language: Английский

Citations

1
Commercially Applicable One-Step Method to Construct Homogeneous Anode/Electrolyte Interface and Cathode/Electrolyte Interface Layers in All-Solid-State Lithium–Sulfur Batteries DOI
Jianhui Du,

Wanli Sha,

Chong Luo

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(51), P. 71019 - 71029

Published: Dec. 11, 2024

Using a solid electrolyte is considered to be the most effective strategy solve shuttle effect in lithium–sulfur batteries. However, practical application of solid-state batteries (SLSBs) still far from being realized. This because SLSBs, like all other battery systems, also face dilemma interface degradation (including both anode and cathode interfaces), addition terrible kinetics due nonliquid electrolytes infiltrating nonconductive sulfur particles inside cathode. It necessary consider factors associated with cathode, anode, electrolyte, interfaces an integrated manner problems existing SLSBs. Similar anode/electrolyte formation liquid this work simultaneously synthesized situ cathode/electrolyte by one-step electrochemically inducing polymerization thiophene monomers poly(ethylene oxide) electrolyte. By screening adjustment process, dual ion-electron conductive layer on sides as well inner surface was synthesized. As result these improvements, ionic conductivity 1.1 × 10–4 S cm–1 achieved composited at 40 °C while maintaining specific capacity 1166.6 mAh g–1 after 50 cycles SLSBs assembled. study regulated emphasized important role homogeneity might extended production applications its competitiveness technology economy.

Language: Английский

Citations

0