Catenation Control in Stable Zr‐MOFs for Fine‐Tuning LNG‐ANG‐Related Methane Storage DOI
Si Ma, Le Shi,

Yuanlong Zhong

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 22, 2024

Abstract The liquefied natural gas and adsorbed (LNG‐ANG) coupling systems are emerging as an attractive solution to solve boil‐off gases generated by LNG tanks. Metal‐organic frameworks (MOFs) promising candidates for methane storage delivery owing their high porosity, large specific surface area, tunable pore structures. However, systematically tuning LNG‐ANG‐related adsorption performance of MOFs has yet be explored. In this context, interpenetrated zirconium‐based (3,8)‐connected the ‐MOF, Zr‐TTB‐1, with limited porosity is synthesized. further delicate modulation reaction conditions allows assembly a non‐interpenetrated counterpart, Zr‐TTB‐2, significantly improved porosity. Such molecular‐level catenation control results in substantial increase low‐temperature related LNG‐ANG. volumetric working capacity Zr‐TTB‐2 up 255 cm 3 (standard temperature pressure, STP) −3 under LNG‐ANG condition (159 K, 6 bar, 298 5 bar), outperforms more than twice that counterpart—Zr‐TTB‐1 (115 (STP) ). To end, investigation provides efficacious example regulating through structural designed porous frameworks.

Language: Английский

Pore Space Partition Enabled by Lithium(I) Chelation of a Metal–Organic Framework for Benchmark C2H2/CO2 Separation DOI
You‐Zeng Hao, Kai Shao, Xu Zhang

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: March 20, 2025

Adsorptive separation of acetylene (C2H2) from carbon dioxide (CO2) offers a promising approach to purify C2H2 with low-energy footprints. However, the development ideal adsorbents simultaneous high adsorption and selectivity remains great challenge due their very small molecular sizes physical properties. Herein, we report lithium(I)-chelation strategy for pore space partition (PSP) in microporous MOF (Li+@NOTT-101-(COOH)2) achieve uptake selectivity. The chelation model Li+ ions within framework was visually identified by single-crystal X-ray diffraction studies. immobilized were found have two functions: (1) partitioning large cages into smaller ones while maintaining surface area (2) providing specific binding sites selectively take up over CO2. resulting Li+@NOTT-101-(COOH)2 exhibits rare combination capture capacity (205 cm3 g-1) C2H2/CO2 (13) at ambient conditions, far surpassing that NOTT-101-(COOH)2 (148 g-1 3.8, respectively) most top-tier materials reported. Theoretical calculations gas-loaded SCXRD studies reveal chelated combined segmented can bind amount through unique π-complexation, accounting improved Breakthrough experiments validated its excellent actual mixtures, one highest productivities 118.9 L kg-1 (>99.5% purity) single adsorption-desorption cycle.

Language: Английский

Citations

3
Metal–organic frameworks for one-step ethylene purification from multi-component hydrocarbon mixtures DOI

Yan Han,

Linyao Wang,

Yuanbin Zhang

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216291 - 216291

Published: Oct. 29, 2024

Language: Английский

Citations

11
Lanthanide-bimetallic organic frameworks: from mechanism and sensors design to ratiometric fluorescent applications DOI
Jialing Zhou, Xiao Hu, Chen Liu

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 534, P. 216574 - 216574

Published: March 4, 2025

Language: Английский

Citations

1
Removal of Trace Benzene from Cyclohexane Using a MOF Molecular Sieve DOI

Rui-Chao Zhao,

Lin‐Hua Xie, Xiaomin Liu

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

Cyclohexane (Cy), commonly produced by the catalytic hydrogenation of benzene (Bz), is used in large quantities as a solvent or feedstock for nylon polymers. Removing trace unreacted Bz from Cy product technically difficult due to their similar molecular structures and physical properties. Herein, we report that metal-organic framework (MOF) adsorbent shows sieving effect with record-high Bz/Cy adsorption selectivities (216, 723, 1027) liquid mixtures (v/v = 1:1, 1:10, 1:20), traps molecules effectively even at low partial pressure vapor phase (e.g., 2.49 mmol/g 8.2 Pa) content liquid-phase 128 mg/g 20 ppm). Over 99% removal (1000 ppm) could be achieved one simple stripping step room temperature using this sorbent, producing >99.999% purity. Single-crystal structure analyses guest-free Bz-loaded phases MOF disclosed narrow slit-like pore aperture strong uniting multiple weak host-guest guest-guest interactions are co-origin its distinct property Cy.

Language: Английский

Citations

4
Synergistic Binding Sites in a Robust and Scalable Metal–Organic Framework for Record CH4 Capture DOI Open Access
Miao Chang,

Yongsong Li,

Minman Tong

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 12, 2025

Abstract Effectual CH 4 reclamation from /N 2 blends by existing physisorbents in industrialization confronts the adversity of frustrated separation performance, weak structural strength, and restricted scale‐up preparation. To solve aforesaid bottlenecks, herein, a strategy is presented to fabricate synergistic strong recognition binding sites robust scalable optimum Cu(pma) with ultramicroporous feature regarding superb versus N . By virtue contribution multiple affinities accompanied enormous potential field overlap pore restriction, it imparts toward molecules. Equilibrium adsorption bears record KH, (88.2 cm 3 (STP) g −1 bar ), uptake (48.5 stacking density (303.9 L (1.52 mol ) coexisting one highest selectivity (11.5) Q0 st, (29.8 kJ hitherto, authorizing novel benchmark. Thermodynamically driven mechanisms within ‐established synergy forces are deciphered situ PXRD FT‐IR combined theoretical studies. The breakthrough effect dynamic (28.8 cooperation exceptional recyclability easy synthesis scalability under ambient conditions strengthened attractiveness

Language: Английский

Citations

0
Discovery of metal-organic frameworks for efficient NF3/N2 separation by integrating high-throughput computational screening, machine learning, and experimental validation DOI
Yanjing He, Zhi Fang, Weijiang Xue

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132481 - 132481

Published: March 1, 2025

Language: Английский

Citations

0
Coordination‐Dissociation Induced T1‐Weighted Magnetic Resonance Imaging Responses in a spn‐Type MOF for Potential Drug Release Monitoring DOI Open Access
Dan Luo, Tianze Wu, Tianze Qiu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Developing novel nanoplatforms capable of monitoring drug release by identifiable magnetic resonance imaging (MRI) responses is a great promising yet challenging task. Here, isoreticular chemistry strategy introduced to enable spn ‐type metal–organic framework (MOF) with T 1 ‐weighted MRI turned‐on response the via coordination‐dissociation process. Post‐synthetic functionalization endows structure high longitudinal relaxivity r 12.63 m −1 s as well abundant accessible coordination sites catch carboxylate probes and drugs. Mechanism studies reveal size‐dependent decrease in coordinated increase size, bulk benzoic acid showing largest reduction at 71%. In vitro model further validate signals respectively coordinating four drugs aromatic groups. Finally, vivo experiments confirm feasibility using this coordination‐dissociation‐induced monitor release. This proof‐of‐principle study demonstrates practical pathway for designing MOF‐based responsive MRI, paving way enhanced non‐invasive techniques.

Language: Английский

Citations

0
The adsorption and light hydrocarbon separation performance for the scalable synthesis of microporous Cu-MOF DOI
Yuting Du, Yunfei Xu, Ziyou Zhang

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142090 - 142090

Published: March 1, 2025

Language: Английский

Citations

0
Fast diffusion and High C2H2 Capture in a 2D MOF with Oxygen-riched Wide Channels for Efficient C2H2/CO2 Separation DOI
Wenpeng Xie,

Qiuju Fu,

Guoliang Chen

et al.

Composites Part B Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 112414 - 112414

Published: March 1, 2025

Language: Английский

Citations

0
Innovative horizons of MOF-based electrode materials for next-generation energy storage and conversion: Bridging progress and challenges DOI
Usama Zahid, Fasiha Kashif

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 45, P. 102705 - 102705

Published: April 1, 2025

Language: Английский

Citations

0