Aggregated CoO for Selective CO2 Electroreduction to CH3OH DOI
Jianzhi Huang, Han Fu, Mingjing Li

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(17)

Published: May 1, 2025

Abstract In this work, an aggregated CoO with a unique structure was prepared, which showed the ability of high‐activity electrochemical reduction CO 2 to produce methanol. 0.1 M KHCO 3 aqueous solution at −0.85 V, highest yield methanol generation 37.6 mmol g −1 h , and Faraday efficiency (FE) 68%, overpotential as low 230 mV. The continuous test results show that catalyst has certain stability. Meanwhile, we found compared non‐aggregated structure, nanoparticles conducive infiltration, enrichment, adsorption, reaction in catalyst, thus enhancing electroreduction reactivity.

Language: Английский

Insights into Operating Conditions on Electrocatalytic CO2 Reduction DOI Open Access
Zhaozhao Zhu, Wu Tang, Junjie Wang

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Abstract Electrocatalytic CO 2 reduction (CO RR) is rapidly emerging as a promising sustainable strategy for transforming into valuable fuels and chemical feedstocks, crucial step toward carbon‐neutral society. The efficiency, selectivity, stability of RR are heavily influenced by the chosen catalyst operating conditions used. Despite substantial advances in development catalysts, there scarcity comprehensive reviews focusing on influence different environments performance. This review offers detailed examination internal external environmental control strategies designed to enhance efficiency. fundamental reaction mechanisms through situ operational techniques, paired with theoretical analyses, discussed while also identifying key challenges future research directions technology. By delivering overview current state field, this highlights critical role control, mechanistic insights, practical considerations needed successful commercialization

Language: Английский

Citations

2
Understanding and Tuning the Effects of H2O on Catalytic CO and CO2 Hydrogenation DOI
Mingrui Wang, Guanghui Zhang, Hao Wang

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(21), P. 12006 - 12085

Published: Oct. 31, 2024

Catalytic COx (CO and CO2) hydrogenation to valued chemicals is one of the promising approaches address challenges in energy, environment, climate change. H2O an inevitable side product these reactions, where its existence effect are often ignored. In fact, significantly influences catalytic active centers, reaction mechanism, performance, preventing us from a definitive deep understanding on structure-performance relationship authentic catalysts. It necessary, although challenging, clarify provide practical strategies tune concentration distribution optimize influence. this review, we focus how induces structural evolution catalysts assists processes, as well efforts understand underlying mechanism. We summarize discuss some representative tuning for realizing rapid removal or local enrichment around catalysts, along with brief techno-economic analysis life cycle assessment. These fundamental understandings further extended reactions CO CO2 reduction under external field (light, electricity, plasma). also present suggestions prospects deciphering controlling applications.

Language: Английский

Citations

12
Harnessing Interfacial Cl− Ions for Concurrent Formate Production at Industrial Level via CO2 Reduction and Methanol Oxidation DOI Creative Commons
Yiqun Chen, Yan Zhang, Zhen Li

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Abstract The efficient electrocatalytic conversion of CO 2 to formate is often impeded by the high energy requirements oxygen evolution reaction (OER) and limited activity selectivity reduction (CO RR). Herein, a novel strategy enhance production substituting OER with methanol oxidation (MOR) optimizing cathodic microenvironment interfacial Cl − ions presented. Through theoretical analysis, binder‐free Bi NiOOH electrodes that achieve remarkable Faradaic efficiencies (FE ) exceeding 90% at current densities 50–250 mA·cm −2 for RR MOR, respectively, are identified. These combined experimental investigations demonstrate enrichment on electrode modulates local electronic structure, fostering conducive RR. Bi–NiOOH full cell maintains FE above industry‐level (100–300 ), enabling concurrent electrosynthesis both electrodes. This work highlights critical role anion environments in electrocatalysis provides strategic framework synergistic engineering electrochemical systems.

Language: Английский

Citations

0
Aggregated CoO for Selective CO2 Electroreduction to CH3OH DOI
Jianzhi Huang, Han Fu, Mingjing Li

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(17)

Published: May 1, 2025

Abstract In this work, an aggregated CoO with a unique structure was prepared, which showed the ability of high‐activity electrochemical reduction CO 2 to produce methanol. 0.1 M KHCO 3 aqueous solution at −0.85 V, highest yield methanol generation 37.6 mmol g −1 h , and Faraday efficiency (FE) 68%, overpotential as low 230 mV. The continuous test results show that catalyst has certain stability. Meanwhile, we found compared non‐aggregated structure, nanoparticles conducive infiltration, enrichment, adsorption, reaction in catalyst, thus enhancing electroreduction reactivity.

Language: Английский

Citations

0