Harnessing Interfacial Cl− Ions for Concurrent Formate Production at Industrial Level via CO2 Reduction and Methanol Oxidation DOI Creative Commons
Yiqun Chen, Yan Zhang, Zhen Li

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Abstract The efficient electrocatalytic conversion of CO 2 to formate is often impeded by the high energy requirements oxygen evolution reaction (OER) and limited activity selectivity reduction (CO RR). Herein, a novel strategy enhance production substituting OER with methanol oxidation (MOR) optimizing cathodic microenvironment interfacial Cl − ions presented. Through theoretical analysis, binder‐free Bi NiOOH electrodes that achieve remarkable Faradaic efficiencies (FE ) exceeding 90% at current densities 50–250 mA·cm −2 for RR MOR, respectively, are identified. These combined experimental investigations demonstrate enrichment on electrode modulates local electronic structure, fostering conducive RR. Bi–NiOOH full cell maintains FE above industry‐level (100–300 ), enabling concurrent electrosynthesis both electrodes. This work highlights critical role anion environments in electrocatalysis provides strategic framework synergistic engineering electrochemical systems.

Language: Английский

Direct Electroreduction of Low-Concentration CO2: Progress and Perspective DOI
Jingjing Li, Qin Xiang Xia, Xiaoran Wang

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: March 13, 2025

The conversion of CO2 into carbon-based fuels and chemicals via the electrocatalytic reduction reaction (CO2RR) offers an attractive route to reducing emission for carbon neutrality. Currently, high-purity gas has been widely used as feedstock most CO2RR studies, while sources with a typically low concentration impose extra cost capture purification steps. direct utilization low-concentration is promising approach substantially address this problem. In Perspective, we first highlight prominent advantages electroreduction CO2. Then focus on summary several important design strategies in diluted impurities-containing atmosphere. Finally, propose personal outlooks future challenges some opportunities fascinating research field.

Language: Английский

Citations

0
Single-atom catalysts confined in shell layer achieved by a modified top-down strategy for efficient CO2 reduction DOI
Wei Dong, Aihao Xu, Xiangyu Chen

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137566 - 137566

Published: April 1, 2025

Language: Английский

Citations

0
Harnessing Interfacial Cl− Ions for Concurrent Formate Production at Industrial Level via CO2 Reduction and Methanol Oxidation DOI Creative Commons
Yiqun Chen, Yan Zhang, Zhen Li

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Abstract The efficient electrocatalytic conversion of CO 2 to formate is often impeded by the high energy requirements oxygen evolution reaction (OER) and limited activity selectivity reduction (CO RR). Herein, a novel strategy enhance production substituting OER with methanol oxidation (MOR) optimizing cathodic microenvironment interfacial Cl − ions presented. Through theoretical analysis, binder‐free Bi NiOOH electrodes that achieve remarkable Faradaic efficiencies (FE ) exceeding 90% at current densities 50–250 mA·cm −2 for RR MOR, respectively, are identified. These combined experimental investigations demonstrate enrichment on electrode modulates local electronic structure, fostering conducive RR. Bi–NiOOH full cell maintains FE above industry‐level (100–300 ), enabling concurrent electrosynthesis both electrodes. This work highlights critical role anion environments in electrocatalysis provides strategic framework synergistic engineering electrochemical systems.

Language: Английский

Citations

0