Basics and Advances of Manganese‐Based Cathode Materials for Aqueous Zinc‐Ion Batteries DOI Open Access
Ahmed Hashem Abdelmohsen, Sherif A. El‐Khodary, N. Ismail

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

It is greatly crucial to develop low-cost energy storage candidates with high safety and stability replace alkali metal systems for a sustainable future. Recently, aqueous zinc-ion batteries (ZIBs) have received tremendous interest owing their low cost, safety, wide oxidation states, sophisticated fabrication process. Nanostructured manganese (Mn)-based oxides in different polymorphs are the potential cathode materials widespread application of ZIBs. However, Mn-based oxide suffer from several drawbacks, such as electronic/ionic conductivity poor cycling performance. To overcome these issues, various structural modification strategies been adopted enhance electrochemical activity, including phase/defect engineering, doping foreign atoms (e. g., and/or nonmetal atoms), coupling carbon or conducting polymers. Herein, this review targets summarize advantages disadvantages above-mentioned improve performance cathodic part The challenges suggestions development ZIBs put forward.

Language: Английский

Roadmap for electrochromic smart devices: From materials engineering and architectures design to multifunctional application DOI

Jinhui Wang,

Xiaodan Guo,

Chenchen Bian

et al.

Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101461 - 101461

Published: Feb. 1, 2025

Language: Английский

Citations

2
Coupling of Donor–Acceptor of Hydrogen Bonds Manipulated Electrolyte Structure Enables Hydrogen Evolution‐Free and Durable Zn Metal Batteries DOI Open Access
Dan Xie,

Fang‐Yu Tao,

Li‐Han Zhu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 7, 2025

Abstract The undesirable hydrogen evolution reaction (HER) primarily contributes to the instability of Zn anode, which exacerbates corrosion and dendrite growth impedes application metal battery in large‐scale energy storage. Although engineering functional aqueous electrolyte prominently controls HER, it hardly eradicates occurrence HER from source. Herein, this research utilizes coupling donor–acceptor bonds (H‐bonds) manipulate structure design a novel methanol (MeOH)‐based anhydrous organic with propylene carbonate (PC) as co‐solvent, fundamentally eliminating accompanied by suppressed growth. PC molecules acceptor strengthen H‐bonds networks between MeOH donor weaken interaction cations anions, enhancing stability reducing anion‐involved by‐products formation. Meanwhile, preferential adsorbed on anode surface form favorable component‐dominated solid interface layer, inducing uniform deposition along (002) orientation. Consequently, exhibits excellent cycling high reversibility. assembled cells also harvest satisfactory low‐temperature tolerance. More importantly, corresponding Zn||PANI full cell pouch behave an impressive capacity retention 92.4% 91.1% after 3200 1400 cycles, respectively.

Language: Английский

Citations

0
Zinc‐Seeded PEDOT:PSS Aerogel Host as Highly Reversible Dendrite‐Free Zinc Metal Anode DOI

Zhanrui Zhang,

Yao Wang, Jie Sun

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 26, 2025

Abstract The parasitic reactions and rampant dendrite growth on the Zn anode side pose significant obstacles to future applications of aqueous zinc ion batteries. Herein, a lightweight host is reported by introducing nanosized metallic into poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) (P‐S) aerogel (Zn/P‐S). ‒SO 3 H groups interact with 2+ guild their migrations along PSS chains, while offer additional nucleation sites homogenize electrical concentration. Owing these synergistic effects, uniform dense deposition (002) plane aligned parallel P‐S substrate achieved, even at high plating capacity 20 mAh cm −2 . Moreover, deposited over Zn/P‐S (Zn@Zn/P‐S) exhibits highly reversible plating/stripping behavior Coulombic efficiency maintained 99% 700 cycles. Consequently, Zn@Zn/P‐S‐based symmetric Zn||Zn cell can work stably 500 h 0.5 ‒2 100 4 depth discharge 40%. A Zn@Zn/P‐S||NaV O 8 full battery presents rate capability 82.2% retention after 1000 cycles 2 g ‒1 This strategy provides novel approach for designing polymer‐based anodes corrosion‐resistant dendrite‐free striping/plating behaviors.

Language: Английский

Citations

0
Recent Advances in Polymer Interlayers for Zinc Metal Anode Protection‐A Mini‐Review DOI Creative Commons

Yamei Luo,

Lanya Zhao,

Dandan Yin

et al.

ChemElectroChem, Journal Year: 2025, Volume and Issue: unknown

Published: April 29, 2025

Abstract Zn metal anode faces numerous challenges that severely limit its practical application. Polymer interlayer is one of the mostly used strategies to enhance performance. The chemical structure, physical properties, as well morphology these polymer interlayers significantly influenced on effectiveness zinc protection. Considering complexity and their composite materials in this field, it highly needed summarize current progresses anodes. This paper reviews recent advances design stabilize from different perspectives, including hydrogel interlayer, porous conductive interlayers. Finally, review outlines possible future developments field towards commercialization anode.

Language: Английский

Citations

0
Chain Effect-controlled Solvation Chemistry and Interfacial Microstructure Enables Highly Reversible Zn Metal Anode DOI
Dan Xie,

Fang-Yu Tao,

Lihan Zhu

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104039 - 104039

Published: Jan. 1, 2025

Language: Английский

Citations

0
Interfacial micro-electric field induced by phosphorus-doped g-C3N4 for highly reversible dendrite-free zinc metal anode DOI
Ya Xiao, Tongming Su, Tian Wang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162391 - 162391

Published: April 1, 2025

Language: Английский

Citations

0
Synergizing lattice matching and transient N–Li bonds to boost sulfur redox kinetics and regulate uniform lithium deposition in practical Li–S batteries DOI
Yantao Wang, Huiqin Chen, Wenjuan Wu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163405 - 163405

Published: May 1, 2025

Language: Английский

Citations

0
Basics and Advances of Manganese‐Based Cathode Materials for Aqueous Zinc‐Ion Batteries DOI Open Access
Ahmed Hashem Abdelmohsen, Sherif A. El‐Khodary, N. Ismail

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

It is greatly crucial to develop low-cost energy storage candidates with high safety and stability replace alkali metal systems for a sustainable future. Recently, aqueous zinc-ion batteries (ZIBs) have received tremendous interest owing their low cost, safety, wide oxidation states, sophisticated fabrication process. Nanostructured manganese (Mn)-based oxides in different polymorphs are the potential cathode materials widespread application of ZIBs. However, Mn-based oxide suffer from several drawbacks, such as electronic/ionic conductivity poor cycling performance. To overcome these issues, various structural modification strategies been adopted enhance electrochemical activity, including phase/defect engineering, doping foreign atoms (e. g., and/or nonmetal atoms), coupling carbon or conducting polymers. Herein, this review targets summarize advantages disadvantages above-mentioned improve performance cathodic part The challenges suggestions development ZIBs put forward.

Language: Английский

Citations

2