Urchin-like γ-MnO2/Carbon Nanotubes as an Efficient Cathode Catalyst for Durable Solid-State Lithium and Sodium-CO2 Batteries DOI
Jilong Liu,

Zhi Li,

Chen Chen

et al.

ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: 7(22), P. 10730 - 10737

Published: Nov. 13, 2024

Metal-CO2 batteries integrate the benefits of carbon dioxide capture and efficient energy storage, representing a prospective innovation in storage systems. In particular, most research attention has been concentrated on Li-CO2 Na-CO2 due to their high density discharge potential. However, excessive accumulation products volatilization liquid electrolyte restrict further advancements these batteries. Herein, we synthesized an urchin-like γ-MnO2 cathode catalyst that enables rapid reversible CO2 reduction reaction (CO2RR) evolution (CO2ER). The assembled solid-state Li/Na-CO2 with Li7La3Zr2O12- Na3Zr2Si2PO12-based composite solid electrolytes facilitate uniform stripping/deposition metallic anodes, thereby ensuring long-term cycling stability exhibit for 240 100 cycles, respectively, at current 200 mA g–1 cutting-off capacity 500 mAh g–1. Even g–1, still possess excellent rate capability. This work provides promising solution reduce costs catalysts enhance safety

Language: Английский

Progress and challenges of transition metal-based catalysts regulation for Li-CO2 batteries DOI

Shasha Xiao,

Ying Xiao,

Shilin Hu

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104047 - 104047

Published: Jan. 1, 2025

Language: Английский

Citations

2
Advanced hard carbon materials for practical applications of sodium-ion batteries developed by combined experimental, computational, and data analysis approaches DOI
Zongfu Sun, Huawei Liu, Wen Li

et al.

Progress in Materials Science, Journal Year: 2024, Volume and Issue: unknown, P. 101401 - 101401

Published: Oct. 1, 2024

Language: Английский

Citations

8
Catalyzed carbon-based materials for CO2-battery utilization DOI Open Access

Yulian Dong,

Changfan Xu, Yonghuan Fu

et al.

Energy Materials, Journal Year: 2025, Volume and Issue: 5(4)

Published: Jan. 23, 2025

Increasing atmospheric CO2 levels and global carbon neutrality goals have driven interest in technologies that both mitigate emissions provide sustainable energy storage solutions. Metal-carbon dioxide (M-CO2) batteries offer significant promise due to their high density potential utilize CO2. A key challenge advancing M-CO2 lies optimizing CO2-breathing cathodes, which are essential for adsorption, diffusion, conversion. Carbon-based cathodes play a critical role facilitating redox batteries, owing cost-effectiveness, conductivity, tunable microstructure, porosity. However, there is lack of current systematic understanding the relationship between structure, composition, catalytic properties carbon-based as well impact on overall efficiency, stability, durability batteries. In this review, we will give an insightful review analysis recent advances various materials, including commercial carbons, single-atom catalysts, transition metal/carbon composites, metal-organic frameworks, etc. , focusing structure-function-property relationships. comprehensive pivotal played by materials optimization strategies be provided. Moreover, future perspectives research suggestions presented advance development innovation

Language: Английский

Citations

1
Toward unlocking the potential of aqueous Zn-CO2 batteries: What factors affect the electrochemical performance? DOI
Hongyang Zhao, Yue Li, Wang Jian-hu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161736 - 161736

Published: March 1, 2025

Language: Английский

Citations

0
Unveiling the reaction selectivity mechanism of molybdenum and tungsten carbides as cathode catalysts for Li–CO2 batteries DOI
Haonan Xie, Biao Chen, Chunnian He

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The type of catalysts and the adsorption behavior molecules play a decisive role in selectivity lithium–CO 2 battery reaction.

Language: Английский

Citations

0
Strain‐Mediated Sabatier Principle‐Guided the Design of Bimetallic Catalysts for High‐Performance Li‐CO2 Batteries DOI

Yao Dai,

Baoguang Mao, Linjie Zhao

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

Abstract Using PdCu alloy as a model system, winged oxidized carbon nanotube‐confined Pd x Cu y bimetallic catalysts with tunable compressive strain are engineered through atomic incorporation into lattices. This strain‐mediated approach effectively modulates the d‐band center of to optimizes antibonding state occupancy for balanced adsorption landscape CO 2 activation and Li 3 decomposition that aligns Sabatier principle optimal catalytic activity. Systematic investigations reveal 0.73% in 5 optimally behavior both while maintaining weakened Li─O bonding interactions promote , achieving superior stability at high current densities (> 1100 h 1.0 A g −1 ). The findings highlight pivotal role strain‐driven electronic optimization strategy designing high‐efficiency systems advanced metal‐gas batteries.

Language: Английский

Citations

0
Engineering Local Coordination and Electronic Structures of Dual-Atom Catalysts DOI
Xinzhe Li, Xuan Liu, Muzammil Hussain

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: May 1, 2025

Heterogeneous dual-atom catalysts (DACs), defined by atomically precise and isolated metal pairs on solid supports, have garnered significant interest in advancing catalytic processes technologies aimed at achieving sustainable energy chemical production. DACs present board opportunities for atomic-level structural property engineering to enhance performance, which can effectively address the limitations of single-atom catalysts, including restricted active sites, spatial constraints, typically positive charge nature supported single species. Despite rapid progress this field, intricate relationship between local atomic environments behavior dual-metal sites remains insufficiently understood. This review highlights recent major challenges field. We begin discussing modulation coordination electronic structures its impact performance. Through specific case studies, we demonstrate importance optimizing entire ensemble achieve efficient, selective, stable performance both model industrially relevant reactions. Additionally, also outline future research directions, emphasizing synthesis, characterization, practical applications, aiming fully unlock potential these advanced catalysts.

Language: Английский

Citations

0
Recent Advances in Solar‐Driven Artificial Photocatalytic Synthesis of Urea DOI
Ziyi Lu, Rundong Chen,

Gaoxiong Liu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 24, 2025

Abstract Urea (CO(NH 2 ) ), a nitrogen‐rich compound, is widely used as nitrogen fertilizer in agriculture, key component medicine, and raw material chemical production. The continuously growing demand for urea has spurred an escalation Considering the impacts of byproducts during production, it urgent to explore cost‐effective environmentally benign synthesis methods. Artificial photosynthesis, which utilizes renewable solar power convert carbon dioxide (CO (N not only provides sustainable alternative but also reduces emissions fixes simultaneously. This review delves into C−N coupling pathways, intermediates, their detection methodologies photocatalytic It discusses rational design selection targeted photocatalysts toward synthesis, highlighting characteristics that determine rate‐limiting steps. Furthermore, systematically examines challenges evaluates viable solutions overcome these limitations. By identifying current obstacles proposing potential strategies, this aims advance artificial photosynthesis eco‐friendly approach insights presented herein seek bridge fundamental research with practical applications, ultimately fostering progress energy‐efficient fixation technologies.

Language: Английский

Citations

0
Facile and ecofriendly green synthesis of Co3O4/MgO–SiO2 composites towards efficient asymmetric supercapacitor and oxygen evolution reaction applications DOI Creative Commons

Gulzar Ali,

Aneela Tahira, Asma Hayat

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(51), P. 38009 - 38021

Published: Jan. 1, 2024

The development of low-cost, eco-friendly, and earth-friendly electrode materials for energy storage conversion applications is a highly desirable but challenging task strengthening the existing renewable systems.

Language: Английский

Citations

1
Enhancing the Performance and Stability of Li-CO2 Batteries Through LAGTP Solid Electrolyte and MWCNT/Ru Cathode Integration DOI Creative Commons

Dan Na,

Dohyeon Yu,

Hwan Kim

et al.

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(23), P. 1894 - 1894

Published: Nov. 26, 2024

Li-CO2 batteries (LCBs) have emerged as promising solutions for energy storage, with the added benefit of contributing to carbon neutrality by capturing and utilizing CO2 during operation. In this study, a high-performance LCB was developed using Ge-doped LiAlGeTi (PO4)3 (LAGTP) solid electrolyte, which synthesized via solution-based method doping Ge into NASICON-type LATP. The ionic conductivity LAGTP pellets measured 1.04 × 10−3 S/cm at 25 °C. an MWCNT/Ru cathode maintained stable cycling performance over 200 cycles current density 100 mA/g, cut-off capacity 500 mAh/g. Post-cycle analysis confirmed reversible electrochemical reactions cathode. integration electrolyte effectively enhanced improved cycle life LCB. This study highlights potential electrolytes advanced energy-storage technologies offers pathway developing sustainable LCBs.

Language: Английский

Citations

0