Perovskite‐Coupled NIR Organic Hybrid Solar Cells Achieving an 84.2% Fill Factor and a 25.2% Efficiency: A Comprehensive Mechanistic Exploration
Chieh‐Ming Hung,
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Chia‐Jen Chih,
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Kuo‐Hsiu Huang
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et al.
Angewandte Chemie,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 12, 2025
Abstract
The
integration
of
organic
dyes
in
perovskite
solar
cells
(PSCs)
to
utilize
near‐infrared
(NIR)
photons
remains
a
challenge.
In
this
study,
selenium‐incorporated
ortho‐benzodipyrrole‐based
NIR
dye
CB‐2Se
was
developed.
CB‐2Se,
featuring
lower
bandgap
1.35
eV,
blended
with
PCBM
form
bulk‐heterojunction
layer
PSCs
for
electron
extraction
and
transport.
Compared
Y6‐16
acceptor,
the
removal
Tz
unit
suppresses
self‐aggregation,
improving
its
compatibility
PCBM.
A
CB‐2Se:PCBM‐incorporated
PSC
achieved
remarkable
power
conversion
efficiency
(PCE)
25.18%
V
OC
1.164
V,
J
SC
25.71
mA/cm
2
,
Fill
Factor
84.15%,
outperforming
that
PCBM‐only
reference
device
(24.35%)
PCBM:Y6‐16‐based
(24.49%).
PCBM:CB‐2Se
enhanced
long‐term
stability
PSCs,
retaining
88%
initial
after
1000
h
under
ambient
air
thermal
conditions.
photophysical
interactions
between
have
been
comprehensively
investigated
by
using
femtosecond
transient
absorption
spectroscopy.
Ultrafast
exciton
separation
into
free
charges
occurs
within
200
femtoseconds
at
interfaces
CB‐2Se.
For
first
time,
transfer
holes
from
back
detected,
providing
valuable
insights
charge
dynamics
utilizing
dyes.
Language: Английский
Application of Metamaterial Perfect Absorber for Performance Enhancement in Photovoltaic Devices
Minho Lee,
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Sung‐Tae Kim,
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Seongin Hong
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et al.
Journal of Flexible and Printed Electronics,
Journal Year:
2024,
Volume and Issue:
3(2), P. 221 - 230
Published: Dec. 1, 2024
With
the
advancement
of
highly
optimized
photovoltaic
devices,
there
is
a
pressing
need
for
extensive
strategies
to
drive
further
improvements
in
efficiency.
Extensive
research
has
focused
on
sub-wavelength
structures
with
anti-reflection
and
light-trapping
properties,
though
an
optimal
design
remains
elusive.
This
study
explores
potential
artificial
optical
structures,
known
as
metamaterials,
address
these
challenges.
Metamaterials,
gaining
attention
their
perfect
absorber
capabilities,
are
integrated
into
solar
cells
boost
absorption
quantum
paper
highlights
recent
advancements
applying
metamaterials
organic
perovskite
cells,
next-generation
technologies,
emphasizing
role
improving
device
performance
Language: Английский