Near‐Infrared Fluorescent Single‐Walled Carbon Nanotubes for Biosensing DOI Creative Commons
Srestha Basu, Gili Bisker

Small, Journal Year: 2025, Volume and Issue: unknown

Published: May 2, 2025

Abstract The objective of this article is to provide a comprehensive overview the recent advancements in biosensing using near‐infrared (NIR) fluorescent single‐walled carbon nanotubes (SWCNTs). SWCNTs are cylindrical structures formed by rolling up graphene layer, with their chiral index (n,m) defining diameter and electronic, mechanical, optical properties, making them metallic, semimetallic, or semiconducting. semiconducting variants feature NIR fluorescence, which offers significant advantages for biological imaging sensing due deep tissue penetration minimal background interference. Moreover, highly photostable, demonstrating resistance photobleaching blinking. Owing these unique have been widely used as probes monitoring broad spectrum analytes, ranging from small molecules macromolecules. This review explores photophysics SWCNTs, suitability biosensing, strategies developing effective SWCNT‐based sensors. begins photophysical highlighting relevance followed key technical concepts. Additionally, principles, methods optimizing functionalized diverse approaches also covered. Overall, intends foundational understanding equipping readers knowledge needed explore apply powerful nanomaterials applications.

Language: Английский

Optical Bionanosensors for Sepsis Diagnostics DOI Creative Commons
Christina Derichsweiler, Svenja Herbertz, Sebastian Kruss

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Sepsis is a global health challenge, characterized by dysregulated immune response, leading to organ dysfunction and death. Despite advances in medical care, sepsis continues claim significant toll on human lives, with mortality rates from 10-25% for 30-50% septic shock, making it cause of death worldwide. Current diagnostic methods rely clinical signs, laboratory parameters, or microbial cultures suffer delays inaccuracies. Therefore, there pressing need novel tools that can rapidly accurately identify sepsis. This review highlights biosensor development could ultimately lead faster more accurate diagnostics. The focus nanomaterial-based optical approaches promise rapid diagnostics without the large equipment trained personnel. An overview provided, highlighting potential molecular targets challenges they present assay development. requirements an ideal point-of-care test (POC) are discussed, including speed, simplicity, cost-effectiveness. Different nanomaterials suitable various detection reviewed innovative nanosensors discussed diagnostics, focusing chemical design increase selectivity multiplexing.

Language: Английский

Citations

3

Comparison of Microfluidic Synthesis of Silver Nanoparticles in Flow and Drop Reactors at Low Dean Numbers DOI Creative Commons
Konstantia Nathanael, Nina M. Kovalchuk, Mark Simmons

et al.

Micromachines, Journal Year: 2025, Volume and Issue: 16(1), P. 75 - 75

Published: Jan. 10, 2025

This study evaluates the performance of continuous flow and drop-based microfluidic devices for synthesis silver nanoparticles (AgNPs) under identical hydrodynamic chemical conditions. Flows at low values Dean number (De < 1) were investigated, where contribution vortices forming inside drop to additional mixing reactor should be most noticeable. In device, discrete aqueous drops serving as reactors generated by focusing using silicone oil phase. Aqueous solutions reagents supplied through two different channels merging just before formed. merged a Tee junction, reaction was carried out in outlet tube. Although systems may face challenges such particle concentration reduction due deposition on channel wall or fouling, they are often more practical research their operational simplicity, primarily elimination need separate nanoparticle dispersion from The results demonstrate that both approaches produced AgNPs similar sizes when conditions defined De residence time within similar.

Language: Английский

Citations

1

Photophysical Properties of Tandem Quantum Defects in Carbon Nanotubes DOI
C. Alexander Schrage, Phillip Galonska, Justus T. Metternich

et al.

The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: unknown, P. 1573 - 1581

Published: Feb. 4, 2025

Single-walled carbon nanotubes (SWCNTs) are versatile near-infrared (NIR) fluorophores that can be chemically functionalized to create biosensors. Numerous noncovalent approaches were developed detect analytes, but these design concepts susceptible nonspecific binding and reduced stability. In contrast, covalent modification of SWCNTs with quantum defects utilized tune their fluorescence properties enable new molecular recognition concepts. Here, we present assess four different synthetic pathways/sequences modify covalently both sp3 DNA-based guanine defects. We find it is possible two defect types without disrupting the optical or chemical Interestingly, emission peak associated (E11*) shifts around 3 nm when combined defects, indicating a coupling between types. However, far lower than red-shift in bandgap-related (E11) by (40 nm). furthermore demonstrate combinations used for (bio)sensing. summary, combination multiple provides platform multifunctional biosensors space explored.

Language: Английский

Citations

1

Near‐Infrared Fluorescent Single‐Walled Carbon Nanotubes for Biosensing DOI Creative Commons
Srestha Basu, Gili Bisker

Small, Journal Year: 2025, Volume and Issue: unknown

Published: May 2, 2025

Abstract The objective of this article is to provide a comprehensive overview the recent advancements in biosensing using near‐infrared (NIR) fluorescent single‐walled carbon nanotubes (SWCNTs). SWCNTs are cylindrical structures formed by rolling up graphene layer, with their chiral index (n,m) defining diameter and electronic, mechanical, optical properties, making them metallic, semimetallic, or semiconducting. semiconducting variants feature NIR fluorescence, which offers significant advantages for biological imaging sensing due deep tissue penetration minimal background interference. Moreover, highly photostable, demonstrating resistance photobleaching blinking. Owing these unique have been widely used as probes monitoring broad spectrum analytes, ranging from small molecules macromolecules. This review explores photophysics SWCNTs, suitability biosensing, strategies developing effective SWCNT‐based sensors. begins photophysical highlighting relevance followed key technical concepts. Additionally, principles, methods optimizing functionalized diverse approaches also covered. Overall, intends foundational understanding equipping readers knowledge needed explore apply powerful nanomaterials applications.

Language: Английский

Citations

0