Boosting Oxygen Evolution via Lattice Oxygen Activation in High-Entropy Perovskite Oxides DOI
Xinyang Jiao, Yu Lei, Ying Liu

et al.

Journal of Materials Chemistry A, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A novel high-entropy perovskite oxide (LaPrSr)(FeCoNi)O 3 exhibited excellent oxygen evolution reaction (OER) performance via a lattice oxygen-mediated mechanism (LOM), which underscoring its potential for advanced energy conversion applications.

Language: Английский

Advances in Starch-Based Nanocomposites for Functional Food Systems: Harnessing AI and Nuclear Magnetic Resonance Technologies for Tailored Stability and Bioactivity DOI Creative Commons
Yue Sun, Ziyu Wang,

Jian Ye

et al.

Foods, Journal Year: 2025, Volume and Issue: 14(5), P. 773 - 773

Published: Feb. 24, 2025

Starch-based nanocomposites (SNCs) are at the forefront of innovations in food science, offering unparalleled opportunities for enhancing stability, bioactivity, and overall functionality systems. This review delves into potential SNCs to address contemporary challenges formulation, focusing on synergistic effects their components. By integrating cutting-edge technologies, such as artificial intelligence (AI) nuclear magnetic resonance (NMR), we explore new avenues precision, predictability, SNCs. AI is applied optimize design SNCs, leveraging predictive modeling fine-tune material properties streamline production processes. The role NMR also critically examined, with particular emphasis its capacity provide high-resolution structural insights, monitor stability over time, elucidate molecular interactions within matrices. Through detailed examples, highlights impact unraveling complex behaviors bioactive compounds encapsulated Additionally, discuss integration functional assays AI-driven analytics assessing bioactivity sensory these systems, providing a robust framework rational advanced products. synergy between AI, NMR, opens pathways developing tailored, high-performance formulations that both health consumer preferences.

Language: Английский

Citations

2

High-Entropy Engineering for Multivalency-Induced Stability in SnSb-Based Anodes DOI

Wei Ran,

Gao Cheng,

Jiajin Luo

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 10, 2025

Achieving high energy density and long cycle life in alloy-type anodes remains a significant challenge due to the large volume changes during cycling. Here, we introduce high-entropy engineering approach using SnSb-based oxides codoped with Ti Al (SSBTA-600), designed promote formation of efficient oxygen vacancies at calcination temperature 600 °C. This results remarkable performance capacity 1012 mAh g-1 0.5 A 297 5 after 500 cycles, superior retention 99% 83.5%, respectively. LiFePO4||SSBTA full cell achieves 134 100 cycles 89.4% retention, demonstrating its practical potential for lithium-ion batteries. The concentration SSBTA-600, induced by multivalency Al, is validated electron paramagnetic resonance (EPR) X-ray absorption spectroscopy (XAS). significantly improves cyclic stability high-rate provides promising strategy enhancing anodes.

Language: Английский

Citations

1

High entropy materials as electrode materials for supercapacitors: A review DOI
Penggang Ren, Guofang Yang, Yanling Jin

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180153 - 180153

Published: March 1, 2025

Language: Английский

Citations

1

Multi-principal element nanoparticles: Synthesis strategies and machine learning prediction DOI

Wail Al Zoubi,

Yujun Sheng,

Iftikhar Hussain

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 535, P. 216656 - 216656

Published: April 3, 2025

Language: Английский

Citations

1

Ultrafine Pt-based high-entropy alloy nanooctahedra deliver enhanced methanol oxidation reaction activity and durability DOI
Chengyu Li, Qin Peng,

Gongao Peng

et al.

Matter, Journal Year: 2025, Volume and Issue: unknown, P. 102096 - 102096

Published: April 1, 2025

Language: Английский

Citations

1

Toward refinement and homogenization of heterogeneous metal nanoparticle prepared by electrical explosion with spatial filter DOI
Ruoyu Han, Shuhan Liu, Jingran Li

et al.

Powder Technology, Journal Year: 2025, Volume and Issue: unknown, P. 120836 - 120836

Published: Feb. 1, 2025

Language: Английский

Citations

0

Rapid synthesis of metastable materials for electrocatalysis DOI
Qiao Chen,

Zichao Xi,

Ziyuan Xu

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Metastable materials are considered promising electrocatalysts for clean energy conversions by virtue of their structural flexibility and tunable electronic properties. However, the exploration synthesis metastable via traditional equilibrium methods face challenges because requirements high precise control. In this regard, rapid method (RSM), with efficiency ultra-fast heating/cooling rates, enables production under non-equilibrium conditions. relationship between RSM properties remains largely unexplored. review, we systematically examine unique benefits various techniques mechanisms governing formation materials. Based on these insights, establish a framework, linking electrocatalytic performance Finally, outline future directions emerging field highlight importance high-throughput approaches autonomous screening optimal electrocatalysts. This review aims to provide an in-depth understanding electrocatalysts, opening up new avenues both fundamental research practical applications in electrocatalysis.

Language: Английский

Citations

0

Optimization elements ratio of oxides (Fe-Co-Ni-Cu-Zn-O) for enhanced photocatalytic hydrogen evolution and degradation of rhodamine B DOI

Yung-Chang Chiao,

Wenwei Wu, Yu‐Cheng Chang

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180173 - 180173

Published: April 1, 2025

Language: Английский

Citations

0

Unveiling the Synthesis, Characterization, and Multifunctional Applications of Ca₅(PO₄)₃F@Ca₅P₈ Nanocomposites From Phosphate Waste for Antioxidant Activity and Evans Bleu Decomposition DOI

Amina Tabet,

Abderrhmane Bouafia,

Khansaa Al‐Essa

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(16)

Published: April 1, 2025

Abstract This study explores the innovative synthesis and versatile applications of Ca₅(PO₄)₃F@Ca₅P₈ nanocomposites (NCs), crafted from phosphate waste sourced Djebel Onk, Algeria, advancing sustainable material use environmental remediation. FTIR analysis unveiled distinct functional groups, including C─H, P─H, P─O, F─Ca, underscoring material's chemical richness, while XRD revealed a crystalline architecture blending hexagonal (Ca₅(PO₄)₃F) monoclinic (Ca₅P₈) phases, with precise crystallite size 22.45 ± 1.18 nm. SEM EDS showcased uniform spherical particles averaging 24 nm, brimming Ca, P, O, F elements. Optical properties dazzled peak absorption at 391 direct indirect bandgaps 1.62 2.98 eV, an Urbach energy 0.435 signaling exceptional UV–visible capabilities. Beyond its structural elegance, nanocomposite exhibited remarkable antioxidant prowess, neutralizing nearly 100% hydrogen peroxide, delivered striking photocatalytic performance, degrading 99.2% Evans Blue dye in just 140 min (rate constant 0.01334 −1 ). Antibacterial assays further highlighted potency, effectively combating S. aureus , C. albicans other microbes. These compelling results position NCs as multifunctional powerhouse for water treatment, photocatalysis, antibacterial applications, paving way technological breakthroughs.

Language: Английский

Citations

0

A multifunctional IL hydrogel electrolyte for zinc anode-stabilized flexible zinc-air batteries over a wide temperature range DOI
Juan Zhang, Xi‐Ming Song, Zhenyu Sun

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 125, P. 116985 - 116985

Published: May 14, 2025

Language: Английский

Citations

0