Intramolecular Charge Transfer‐Regulated Isomeric Covalent Organic Frameworks for Multiple Solvent‐Response
Ke Shi,
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Yujin Chen,
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Han Peng
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et al.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 25, 2025
Stimulus-responsive
covalent
organic
frameworks
(COFs)
own
color-switching
characteristics
when
exposed
to
external
stimuli.
However,
the
investigations
on
multiple
solvent-responsive
COFs
remain
a
challenge
due
synthetic
difficulties
and
uncontrollable
charge
transfer
process
toward
various
solvents.
In
this
contribution,
two
novel
isomeric
with
regulated
intramolecular
(ICT)
by
modulating
distance
between
donor/acceptor
linkage
are
synthesized.
The
as-prepared
exhibited
significantly
distinct
solvatochromic
behaviors
in
water,
acid,
halogenated
solvents,
respectively.
These
functions
attributed
enhancement
degrees
of
ICT
hydrogen
bond
interactions,
protonation
halogen/π
addition,
employed
as
stimulation-responsive
powder
or
ink,
displaying
excellent
image
data
encryption
performances.
work
can
not
only
offer
viewpoint
for
creation
but
also
expand
COFs'
potential
applications
information
anti-counterfeiting.
Language: Английский
Flexible Single‐Atom Cesium Sites on Amorphous MgO Nano‐Cushions for Enhanced CO2‐Involved Multi‐Step Reactions
Qiuyan Cao,
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Wenqiang Sun,
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Zhen Yin
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et al.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 24, 2025
Abstract
Single
atomic
sites
(SAs)
face
challenges
in
catalyzing
complex
chemical
processes
involving
multiple
intermediates
due
to
rigid
coordination
environments,
steric
hindrances,
and
limited
activation
behaviors.
Herein,
an
alloying‐mediated
element
repartition
method
is
developed
synthesize
flexible
cesium
single‐atom
catalysts,
anchoring
Cs
single
on
precisely
controlled
amorphous‐MgO/crystalline
NbC
hetero‐phase
nano‐supports.
The
amorphousMgO(a‐MgO)
equipped
1
‐a‐MgO/NbC
achieves
91%
yield
the
cyclization
of
CO
2
with
2‐aminobenzonitrile
within
a
gas–liquid–solid
triphasic
system,
outperforming
its
counterpart
fabricated
crystalline
MgO,
‐c‐MgO/NbC
catalyst
(only
23%).
shows
excellent
tolerance
various
functional
groups
sustainable
catalysis,
especially
removing
traditional
requirement
for
high‐pressure
conditions
additives.
Operando
spectroscopic
characterizations
theoretical
calculations
demonstrate
that
sandwich‐structural
enhances
consecutive
through
vertically
adsorbed
configurations
during
C‐N
coupling
N‐heterocyclic
ring
formation.
SAs
supported
by
a‐MgO
nano‐cushions
allow
adaptability
dynamic
transformations
via
tensile
Cs‐O
compressive
Mg─O
bonds,
ultimately
reducing
energy
barriers
critical
rearrangement
isomerization
steps.
This
study
provides
valuable
insights
into
designing
SACs
overcome
limitations
support
interfaces,
thereby
enhancing
performance
toward
multi‐intermediate
conversion
heterogeneous
catalytic
transformations.
Language: Английский
Asymmetric heterogeneous catalysis using crystalline porous materials
Chemical Society Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
This
review
discusses
the
design
and
synthesis
methods
asymmetric
catalytic
applications
of
chiral
crystalline
porous
materials,
focusing
on
heterogeneous
reactions
control
mechanisms.
Language: Английский