Lightweight UiO-66 MOF/CNT composites achieving high electromagnetic wave absorption DOI
Z. Liu,

Yuanyuan Zeng,

Lan Long

et al.

Diamond and Related Materials, Journal Year: 2025, Volume and Issue: unknown, P. 112500 - 112500

Published: June 1, 2025

Language: Английский

Mobile Constituent-Boosted Dynamic Separation of C2H2/C2H4/CO2 Ternary Mixtures in Metal–Organic Frameworks DOI
Qixing Liu, Junyu Ren, Zhaoqiang Zhang

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: March 5, 2025

The separation of acetylene (C2H2), ethylene (C2H4), and carbon dioxide (CO2) is critical in the chemical industry, driven by increasing demand for high-purity C2H2 C2H4. While metal-organic frameworks (MOFs) offer an energy-efficient approach adsorptive gas separation, achieving sub-angstrom precision pore size adjustment remains challenging. In this work, we leverage two synergistic mechanisms a double-interpenetrated framework: (1) global structural flexibility, arising from dynamic displacement subnetworks to tailor dimensions, (2) local enabled counterion ligand rotation, modulate aperture binding affinity precise molecular discrimination. A series isostructural MOFs, NUS-33-CF3SO3 NUS-34-BF4, were designed enable one-step purification C2H4 concurrent recovery ternary mixtures. Within pores optimal interplay between counterion-mediated host-guest interactions framework adaptability enables simultaneous regulation static kinetic adsorption properties. Notably, NUS-34-BF4 achieves productivity 2.62 mmol/g uptake 1.26 mmol/g. This study highlights pivotal yet underexplored role counterions as gatekeepers, offering tunable strategy engineer environments flexible MOFs advanced separations.

Language: Английский

Citations

1
Plastic Pores for Switchable and Optimized Adsorption Behaviors DOI Creative Commons

Xuewen Zhang,

Ronghua Wang, Jie‐Peng Zhang

et al.

ACS Central Science, Journal Year: 2025, Volume and Issue: unknown

Published: March 13, 2025

Similar to conventional solids, porous materials have demonstrated rigid and flexible behaviors. Here, we show that pores can be not just elastic but also plastic. By variation of the hydrogen-bonding ability steric hindrance ligand side groups, energy difference barrier between metastable states a framework are fine-tuned enable plastic behavior. All pore structures transform target ones in atmospheres guests with sufficiently high pressures, all shaped remain unchanged after guest removal, resulting optimized host-guest recognitions for guests. Up 6-fold increase adsorption selectivity 9-fold purification productivity CO2 capture coalmine CH4 upgrading, even inversion CO2/C2H2 selectivity, been achieved by reversible pore-shaping single plastic-pore adsorbent. The realization creates an opportunity on-demand switching separation functions performances.

Language: Английский

Citations

0
Three-Dimensional Covalent Organic Framework for Efficient Hydrogen Storage through Polarization-Wall Engineering DOI
Jia Chen,

Zhuozhuo Tang,

Da Zhu

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Covalent organic frameworks (COFs), characterized by high surface areas and tunable pore structures/environments, are regarded as a promising alternative to physisorption H2 storage materials. However, their interaction with hydrogen is often too weak, necessitating the exploration of strategies enhance sorption heat. Herein, we strengthened adsorption induction COF on through polarized wall engineering. The fluorine groups three-dimensional COFs polarize surrounding regions, resulting in heat sites. Due enhanced heat, total uptake 3D-F-COF up 5.96 wt % at 77 K 90 bar. Moreover, enhancement effect polar group does not involve chemisorption, material exhibits excellent cycling stability. These results reveal that modulating incorporating strategy for achieving efficient porous

Language: Английский

Citations

0
Recent advances in stimuli-responsive framework materials: Understanding their response and searching for materials with targeted behavior DOI Creative Commons
François‐Xavier Coudert

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 539, P. 216760 - 216760

Published: May 6, 2025

Language: Английский

Citations

0
Renewable Electrochemical Sensors Based on Copper-Organic Frameworks for Highly Sensitive and Selective Detection of Tetrabromobisphenol A DOI

Caoling Li,

Lei Ling, Wenbo Huang

et al.

Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 138596 - 138596

Published: May 1, 2025

Language: Английский

Citations

0
Advancements in adsorption and membrane technologies for hydrogen isotope separation: Exploring new materials and emerging techniques DOI Creative Commons

Mehrasa Yassari,

Arash Bagherzadeh, Aristides Docoslis

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: 374, P. 133666 - 133666

Published: May 21, 2025

Language: Английский

Citations

0
Post-combustion carbon capture and conversion using advanced materials of Zn-based metal-organic frameworks: A mini review DOI
Yuhui Jin, Fasheng Li, Yun Zheng

et al.

Frontiers in Energy, Journal Year: 2025, Volume and Issue: unknown

Published: May 15, 2025

Language: Английский

Citations

0
Lightweight UiO-66 MOF/CNT composites achieving high electromagnetic wave absorption DOI
Z. Liu,

Yuanyuan Zeng,

Lan Long

et al.

Diamond and Related Materials, Journal Year: 2025, Volume and Issue: unknown, P. 112500 - 112500

Published: June 1, 2025

Language: Английский

Citations

0