Integrated Strategies Toward the Capture and Electrochemical Conversion of Low‐Concentration Carbon Dioxide DOI Creative Commons
Zhenyi Yang, Xingqiu Li, Xianglong Cui

et al.

Exploration, Journal Year: 2025, Volume and Issue: unknown

Published: May 4, 2025

ABSTRACT Electrochemical reduction of carbon dioxide (CO 2 ) has been considered a promising route to reduce net emissions and thus mitigate global warming issues. In practice, it mainly involves two processes including the CO capture subsequent electrochemical conversion. From perfective feasible economic benefits, is practical significance develop integrated conversion systems in an efficient way. However, majority studies have currently focusing on independent process, development strategies still initial stage. This review covers recent progress technologies conversion, integration strategies, mechanisms, corresponding The advantages disadvantages those are particularly discussed, aiming identify viable routes for future applications. To conclude, challenges prospects terms research direction this field provided, with hope promoting utilization from fundamental aspects.

Language: Английский

Catalyst design for the electrochemical reduction of carbon dioxide: from copper nanoparticles to copper single atoms DOI Open Access
Qianwen Li, Jingjing Jiang, Shanshan Jiang

et al.

Microstructures, Journal Year: 2025, Volume and Issue: 5(1)

Published: Jan. 17, 2025

Carbon dioxide reduction reaction (CO2RR) is an efficacious method to mitigate carbon emissions and simultaneously convert CO2 into high-value products. The efficiency of CO2RR depends on the development highly active selective catalysts. Copper (Cu)-based catalysts can effectively reduce hydrocarbons oxygen-containing compounds because their unique geometric electronic structures. Most importantly, Cu multiple products (C2+). Therefore, this review aims outline recent research progress in Cu-based for CO2RR. After introducing mechanism electroreduction reaction, we summarize influence size, morphology, coordination environment single component performance, especially performance control that contain nano or single-atom sites. Then, synergistic regulation strategies doping other metals are summarized. Finally, supports used reviewed. prospects challenges discussed.

Language: Английский

Citations

1
Scalable Low-Temperature CO2 Electrolysis: Current Status and Outlook DOI Creative Commons
Hojeong Lee,

Seontaek Kwon,

Namgyoo Park

et al.

JACS Au, Journal Year: 2024, Volume and Issue: 4(9), P. 3383 - 3399

Published: Aug. 24, 2024

The electrochemical CO2 reduction (eCO2R) in membrane electrode assemblies (MEAs) has brought e-chemical production one step closer to commercialization because of its advantages minimized ohmic resistance and stackability. However, the current performance reported eCO2R MEAs is still far below threshold for economic feasibility where low overall cell voltage (<2 V) extensive stability (>5 years) are required. Furthermore, while cost e-chemicals heavily relies on carbon capture product separation processes, these areas have received much less attention compared electrolysis, itself. In this perspective, we examine status technologies from both academic industrial points view. We highlight gap between capabilities standards offer future research directions with hope achieving industrially viable production.

Language: Английский

Citations

4
Advances in copper nanocrystals: Synthesis, anti-oxidation strategies, and multiple applications DOI
Zexian Chen, Yuanjun Song, Ruo‐Zhou Li

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 529, P. 216455 - 216455

Published: Jan. 17, 2025

Language: Английский

Citations

0
Progress in Cu‐Based Catalyst Design for Sustained Electrocatalytic CO2 to C2+ Conversion DOI Creative Commons
Dan Li, Jin‐Yuan Liu, Bin Wang

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 27, 2025

Abstract The electrocatalytic conversion of CO 2 into valuable multi‐carbon (C 2+ ) products using Cu‐based catalysts has attracted significant attention. This review provides a comprehensive overview recent advances in catalyst design to improve C selectivity and operational stability. It begins with an analysis the fundamental reaction pathways for formation, encompassing both established emerging mechanisms, which offer critical insights design. In situ techniques, essential validating these by real‐time observation intermediates material evolution, are also introduced. A key focus this is placed on how enhance through manipulation, particularly emphasizing catalytic site construction promote C─C coupling via increasing * coverage optimizing protonation. Additionally, challenge maintaining activity under conditions discussed, highlighting reduction active charged Cu species materials reconstruction as major obstacles. To address these, describes strategies preserve sites control including novel utilization mitigation reconstruction. By presenting developments challenges ahead, aims guide future conversion.

Language: Английский

Citations

0
Cu-based Bimetallic Catalysts for Electrochemical CO2 Reduction: Before and Beyond the Tandem Effect DOI
Dan Luo,

Weidong Dai,

Keying Wu

et al.

Nanoscale, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Cu-based bimetallic catalysts show enhanced electrochemical CO 2 reduction performance via the tandem effect. This review traces their progress, highlighting design advances, mechanisms, and challenges to guide efficient conversion.

Language: Английский

Citations

0
Cu‐Based Tandem Architectures for CO2 Electrolysis to Multicarbon Products DOI
Ruizhe Yang,

Lu Xia,

Wulyu Jiang

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 10, 2025

Abstract Carbon dioxide electroreduction reaction (CO 2 RR) offers a pathway to convert CO into valuable multicarbon products (C 2+ ), potential clean energy, and chemical vectors, using renewable electricity. Copper catalysts are, so far, the most selective in this process, but still face challenges such as high overpotentials insufficient selectivity stability when used alone. One strategy tackle these is use of Cu‐based tandem structures, which incorporate tailored sites drive segment RR reaction, more favorable way, within same electrode. Recent examples have shown how Cu‐tandem can lead voltage savings improvements selectivity. This review analyses various catalysts, focusing on alloys, heterostructures (especially highlighting role polymer coatings achieving effects through environmental control), metal–organic frameworks (MOFs). It covers synthetic strategies achieve tandem‐enabling configurations their suggested impact mechanisms performance improvement toward C electrosynthesis. The concludes by offering roadmap design efficient electrodes for CO₂RR beyond.

Language: Английский

Citations

0
A synergic investigation of experimental and computational dual atom electrocatalysis for CO2 conversion to C1 and C2+ products DOI
Saurabh Vinod Parmar, Damanpreet Kaur,

Vidya Avasare

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(30), P. 18774 - 18814

Published: Jan. 1, 2024

This review delves into the applications of DACs for eCO 2 RR, highlighting their pivotal role in producing a range diverse Cn products. DACs, through synergistic interactions.

Language: Английский

Citations

3
Development of catalysts and reactor designs for CO2 electroreduction towards C2+ products DOI Open Access

Joonhee Ma,

Soo Young Kim

Energy Materials, Journal Year: 2025, Volume and Issue: 5(5)

Published: Feb. 25, 2025

Recent research on the electrocatalytic CO2 reduction reaction (eCO2RR) has garnered significant attention given its capability to address environmental issues associated with emissions while harnessing clean energy produce high-value-added products. Compared C1 products, C2+ products provide greater densities and are highly sought after as chemical feedstocks. However, formation of C-C bond is challenging due competition H-H C-H bonds. Therefore, elevate selectivity yield fuels, it essential develop more advanced electrocatalysts optimize design electrochemical cell configurations. Of materials investigated for CO2RR, Cu-based stand out their wide availability, affordability, compatibility. Moreover, catalysts exhibit promising capabilities in adsorption activation, facilitating compounds via coupling. This review examines recent both cells electroreduction compounds, introducing core principles eCO2RR pathways involved generating A key focus categorization catalyst designs, including defect engineering, surface modification, nanostructure tandem catalysis. By analyzing studies catalysts, we aim elucidate mechanisms behind enhanced compounds. Additionally, various types electrolytic discussed. Lastly, prospects limitations utilizing highlighted future research.

Language: Английский

Citations

0
Tailoring of single copper atoms anchored on N, P co-doped carbon for electrochemical CO2 reduction DOI
David Ríos-Ruiz, P. Arévalo-Cid, Jesús Cebollada

et al.

Catalysis Today, Journal Year: 2025, Volume and Issue: unknown, P. 115284 - 115284

Published: March 1, 2025

Language: Английский

Citations

0
Atomic Layered ZnO Between Cu Nanoparticles and a PVP Polymer Layer Enable Exceptional Selectivity and Stability in Electrocatalytic CO2 Reduction to C2H4 DOI Creative Commons
Lihui Zhou,

Hung‐Wei Tsai,

Ting‐Wei Kuo

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Abstract This study employs a chemically controlled strategy to construct few‐atomic‐layer ZnO structure integrated with polyvinylpyrrolidone (PVP) and nanoscale metallic copper on active carbon. Hydrogen‐bond interactions from PVP's N‐vinylpyrrolidone allow retain specific proportion of metal atoms, confining electrons at the Cu/ZnO interface form CuZn nanoalloy clusters. The nanoalloy's dual role in promoting CO adsorption C─C coupling synergistically boosts C 2 H 4 production during electrochemical reduction (ECR). Rapid Cu regeneration further increases adsorbed hydrogen (H ads ) water splitting, achieving remarkable selectivity ≈50.2% stable performance over 10 h. Zn→Cu electron confinement interfacial synergy organic‐oxide‐metal heterojunction underscore catalyst's superior efficiency, offering promising pathway for sustainable ‐to‐C conversion.

Language: Английский

Citations

0