Materials,
Journal Year:
2023,
Volume and Issue:
16(19), P. 6531 - 6531
Published: Oct. 1, 2023
Polyhedral
oligomeric
silsesquioxanes
(POSS)
and
hybrid
organo-halide
perovskites
are
two
important
types
of
nanoscale
frameworks
with
great
potential
in
materials
chemistry.
Both
currently
under
intensive
investigation
for
a
wide
range
possible
applications.
Recent
results
suggest
that
POSS
can
be
attractive
passivating
structure-controlling
agents
perovskite
materials.
In
this
review,
we
present
the
importance
engineering
structures
inorganic
cesium-halide
CsPbX3
(X
=
Cl,
Br,
I)
to
create
new
class
derivatives
improved
properties.
The
combination
these
components
an
effective
strategy
controlling
crystallization
process.
addition,
passivation
surface
defects/bulk
energy
optoelectronic
properties
perovskite-based
achieved
following
method.
minireview,
summarized
existing
literature
reports
on
structural
specificity
perovskites.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 5, 2025
Abstract
Multifunctional
polymer
materials
are
extensively
applied
to
regulate
the
crystallization
process
of
perovskite
films.
However,
a
comprehensive
understanding
correlations
among
spatial
structure
polymers,
modulation,
and
device
performance
is
still
lacking.
Here,
restricted
assembly
strategy
proposed
prepare
high‐quality
films
by
systematically
studying
effect
space
configurations
polymers
on
modulating
cesium
lead
triiodide
(CsPbI
3
)
perovskite.
The
results
confirm
importance
high
backbone
coplanar
in
promoting
nucleation,
accelerating
phase
transitions,
enhancing
crystalline
orientation.
with
not
only
facilitates
formation
uniform
dense
nucleation
sites
precisely
controlling
distribution
colloidal
particles
but
also
enhances
crystal
orientation
through
orientational
growth
induced
structure.
As
result,
efficiency
CsPbI
solar
cells
increases
from
17.84%
20.39%.
Additionally,
unencapsulated
devices
show
excellent
storage
operational
stability.
Angewandte Chemie,
Journal Year:
2024,
Volume and Issue:
136(35)
Published: May 28, 2024
Abstract
Mixed
Br/Cl
perovskite
nanocrystals
(PeNCs)
exhibit
bright
pure‐blue
emission
benefiting
for
fulfilling
the
Rec.
2100
standard.
However,
phase
segregation
remains
a
significant
challenge
that
severely
affects
stability
and
spectrum
of
light‐emitting
diodes
(PeLEDs).
Here,
we
demonstrate
optimization
spacing
between
polydentate
functional
groups
polymer
ligands
to
match
surface
pattern
CsPbBr
1.8
Cl
1.2
PeNCs,
resulting
in
effective
synergistic
passivation
effect
improvements
PeLED
performances.
The
block
alternating
copolymers
with
different
inter‐functional
group
are
facilely
synthesized
as
PeNCs.
Surprisingly,
higher
density
do
not
while
enable
efficient
PeNCs
high
photoluminescence
intensity,
low
non‐radiative
recombination
rate
exciton
binding
energy.
Density
theory
calculations
clearly
confirm
almost
perfect
Finally,
PeLEDs
achieved
at
467
nm
Commission
Internationale
de
l′Eclairage
(CIE)
coordinates
(0.131,
0.071),
external
quantum
efficiency
(9.1
%)
record
spectral
operational
stabilities
(~80
mins)
mixed‐halide
PeLEDs.
Overall,
this
study
contributes
designing
promoting
development
high‐performance
stable
pure‐color
towards
display
applications.
Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
12(27), P. 9944 - 9949
Published: Jan. 1, 2024
The
rapid
advancement
of
self-powered
perovskite
photodetectors
(PDs)
in
recent
years
has
been
hindered
by
numerous
defects
present
solution-processed
polycrystalline
films,
significantly
impacting
device
performance.
Macromolecular Rapid Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 13, 2024
This
comprehensive
review
addresses
the
self-healing
phenomenon
in
perovskite
solar
cells
(PSCs),
emphasizing
reversible
reactions
of
dynamic
bonds
as
pivotal
mechanism.
The
crucial
role
polymers
both
enhancing
inherent
properties
and
inducing
phenomena
grain
boundaries
films
are
exhibited.
initiates
with
an
exploration
various
stability
problems
that
PSCs
encounter,
underscoring
imperative
to
develop
extended
lifespans
capable
self-heal
following
damage
from
moisture
mechanical
stress.
Owing
strong
compatibility
brought
by
polymer
characteristics,
many
additive
strategies
can
be
employed
through
artful
molecular
design.
These
aim
limit
ion
migration,
prevent
ingress,
alleviate
stress,
enhance
charge
carrier
transport.
By
scrutinizing
conditions,
efficiency,
types
behavior,
encapsulates
principles
PSCs.
meticulously
designed
not
only
improve
lifespan
action
but
also
their
environmental
functional
groups.
In
addition,
outlook
on
is
provided,
offering
strategic
guidance
for
future
research
directions
this
specialized
area.
Journal of Materials Chemistry C,
Journal Year:
2024,
Volume and Issue:
12(30), P. 11242 - 11264
Published: Jan. 1, 2024
This
review
article
provides
a
comprehensive
overview
of
the
advantages
and
latest
progress
MHP
materials
for
plant
lighting.
Efforts
to
enhance
stability
lighting
applications
are
explored.
Materials,
Journal Year:
2023,
Volume and Issue:
16(19), P. 6531 - 6531
Published: Oct. 1, 2023
Polyhedral
oligomeric
silsesquioxanes
(POSS)
and
hybrid
organo-halide
perovskites
are
two
important
types
of
nanoscale
frameworks
with
great
potential
in
materials
chemistry.
Both
currently
under
intensive
investigation
for
a
wide
range
possible
applications.
Recent
results
suggest
that
POSS
can
be
attractive
passivating
structure-controlling
agents
perovskite
materials.
In
this
review,
we
present
the
importance
engineering
structures
inorganic
cesium-halide
CsPbX3
(X
=
Cl,
Br,
I)
to
create
new
class
derivatives
improved
properties.
The
combination
these
components
an
effective
strategy
controlling
crystallization
process.
addition,
passivation
surface
defects/bulk
energy
optoelectronic
properties
perovskite-based
achieved
following
method.
minireview,
summarized
existing
literature
reports
on
structural
specificity
perovskites.
