Abstract
Photodetector
(PD),
an
indispensable
component
in
radio‐over‐fiber
(RoF)
systems,
functions
as
interface
between
the
optical
fiber
backbone
and
wireless
radio
branches.
The
power‐handling
capability
is
paramount
to
determine
both
coverage
linearity
of
RoF
link,
it
predominantly
constrained
by
space‐charge
effect
that
limits
output
photocurrent.
Consequently,
electronic
power
amplifiers
are
required
ensure
reliable
for
end‐users,
albeit
at
expense
degraded
signal
linearity,
increased
energy
consumption,
bulky
system.
On
other
hand,
increasing
demand
co‐integration
with
silicon
microelectronics
indicates
CMOS‐compatible
germanium‐silicon
(Ge─Si)
PDs
hold
significant
promise.
Herein,
ultrahigh‐power
Ge─Si
PD
designed
implemented
unprecedented
high
saturation
photocurrent
471.4
mA
a
responsivity
1.12
A
W
−1
.
remarkable
high‐power
performance
achieved
through
enhancing
absorption
promoting
photo‐generated
carrier
transit
comprehensively.
For
proof‐of‐concept
demonstration,
amplifier‐free
communication
driven
proposed
PD,
enabling
range‐capacity
product
20
m·Gb
s
,
third‐order
intermodulation
32.3
dBm
5
GHz,
along
real‐time
video
stream
transmission.
This
work
exhibits
promising
solution
on‐chip
photodetection,
represents
advancement
toward
high‐quality
fiber‐wireless
access
network.
Advanced Optical Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 25, 2025
Abstract
Noise
current,
detectivity,
quantum
efficiency,
and
response
speed
are
critical
metrics
in
evaluating
organic/inorganic
photodiodes.
Herein,
these
simultaneously
advanced
poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)
(PEDOT:PSS)/native
SiO
x
/n‐Si
hybrid
photodetectors,
achieving
excellent
performance
detecting
broadband
faint
light.
Wave‐interference
photonic
crystals,
comprising
periodic
microstructured
inverse
pyramids
with
nanometer‐scale
mesa
widths,
integrated
into
the
Si
absorber
to
effectively
couple
incident
light
for
increased
absorption,
thereby
balancing
optics
conformal
contact
coverage.
The
developed
photodetector
comprises
a
deep
depletion
region
interfacial
layer,
enabling
diffusion‐mitigated
photocarrier
transport
effective
charge
collection,
suppressing
carrier
tunneling
processes
low‐noise.
An
ultralow
reverse
dark
current
density
of
≈2.46
×
10
−8
A
cm
−2
at
−0.4
V
is
realized
nanowatt‐level
detection.
showcases
superlative
properties
among
reported
PEDOT:PSS–based
inorganic
heterojunctions,
including
external
efficiency
>≈80%
from
340
960
nm
(internal
>≈90%
380
840
nm),
detectivity
>≈10
12
Jones
300
1140
nm,
microsecond
speed.
This
study
provides
practical
insight
combining
high‐absorption
microstructures
space
engineering
development
high‐performance
photodetectors.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 19, 2025
Abstract
Near‐infrared
organic
photodetectors
(NIR‐OPDs)
have
emerged
as
increasingly
significant
in
optoelectronics,
offering
unparalleled
advantages
for
applications
health
monitoring
and
night
vision.
The
development
of
self‐powered
devices
with
low
dark
currents
enhanced
NIR
sensitivity
involves
complex
engineering
that
requires
careful
material
selection,
defect
state
density
control,
environmental
consideration.
In
this
study,
an
innovative
approach
is
introduced
utilizes
solid
additive
(DIB)
to
induce
improvements
the
J‐aggregation
morphology
exciton
delocalization
acceptor
molecules.
goal
broaden
response
spectrum
device
augment
its
detection
capabilities.
key
findings
revealed
exhibit
electrostatic
affinity
acceptors,
which
facilitates
their
orderly
face‐to‐face
stacking
controls
π–π
distance.
These
intermolecular
interactions
lead
electron–hole
pairs,
reduced
recombination,
increased
charge
separation
efficiency.
Consequently,
modified
exhibited
exceptional
specific
detectivity,
exceeding
10
14
Jones
across
wavelength
range
695–860
nm,
thereby
establishing
a
new
standard
photodetection.
Overall,
study
successfully
addressed
compatibility
challenges
associated
NIR‐OPDs,
expanding
potential
various
settings.
Advanced Optical Materials,
Journal Year:
2024,
Volume and Issue:
12(19)
Published: May 11, 2024
Abstract
Organic
photodetectors
(OPDs)
have
attracted
immense
interest
as
solution‐processable
optical
signal‐capturing
devices
due
to
their
various
advantages,
such
adjustable
response
range,
excellent
weak
light
response,
lightweight,
flexibility,
and
ease
of
processing
on
diverse
substrates.
Low
dark
current
density
(
J
d
)
high
responsivity
R
are
key
requirements
necessary
for
achieving
a
specific
detectivity
D
*).
Here,
an
effective
strategy
preparing
high‐performance
OPDs
with
potential
micro
p‐i‐n
structure
by
introducing
insulating
poly(aryl
ether)
(PAEN)
into
the
organic
photosensitive
layer
is
reported.
The
PM6:PC
71
BM‐based
capable
significantly
suppressing
while
increasing
,
which
can
be
attributed
multiple
optimizations
morphology
charge
transport
caused
addition
PAEN.
As
result,
value
(3.63
×
10
−10
A
cm
−2
two
orders
magnitude
lower
than
that
device
without
PAEN
(1.00
−8
at
−1
V
bias.
Combined
increased
0.376
W
optimized
achieves
*of
3.45
13
Jones
(−1
620
nm).
demonstrate
performance
comparable
commercial
Si
(Hamamatsu
S1133),
paving
way
direct
market
development
this
cost‐effective
photodetection
technology.
Giant,
Journal Year:
2024,
Volume and Issue:
19, P. 100291 - 100291
Published: May 28, 2024
Organic
photodetectors
(OPDs)
own
unique
advantages
such
as
light
weight,
flexibility,
low
production
cost,
tunable
detection
wavelength,
and
thus
are
promising
for
a
variety
of
applications.
The
lack
hole-blocking
layer
(HBL)
materials
impedes
the
reduction
dark
current
density
enhancement
performance
OPDs.
Herein,
we
employed
an
n-type
polythiophene
n-PT1
HBL
material
inverted
specific
solubility
in
o-dichlorobenzene
facilitates
solution
processing
enables
multilayer
device
fabrication.
ultradeep-lying
highest
occupied
molecular
orbital
energy
level
ensures
large
hole
injection
barrier
between
cathode
active
that
suppresses
current.
As
result,
compared
to
control
devices
without
n-PT1,
OPD
with
demonstrate
two-order-of-magnitude
one-order-of-magnitude
increase
detectivity.
To
best
our
knowledge,
this
is
first
processable
Journal of Materials Chemistry C,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
The
incorporation
of
the
third
component
PBDTDPP
and
utilization
PFN-Br/ZnO
double
electron
transport
layer
have
enhanced
performance
organic
photodetectors,
thereby
improving
signal
resolution
in
health
monitoring
applications.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 31, 2025
Abstract
Organic
photodiodes
(OPDs)
have
shown
great
promises
for
large‐area
optical
imagers
attributed
to
ease
of
processing
and
tunable
performance
in
a
wide
wavelength
range.
A
biphasic
heterojunction
(BPHJ)
OPD
design,
having
bulky
structure
on
top
monophasic
donor
layer,
is
proposed
this
work.
The
BPHJ
spontaneously
formed
self‐assembled
monolayer
(SAM)
treated
indium
tin
oxide
surface
by
depositing
the
acceptor
layers
sequentially.
fabricated
OPDs
present
significantly
reduced
dark
current
meanwhile
improved
specific
detectivity
with
larger
linear
dynamic
range
faster
response
compared
conventional
devices.
This
strategy
proved
be
universal
various
donor/acceptor
combinations,
covering
from
visible
near‐infrared.
Such
well
compatible
back‐end‐of‐line
integration
processes
TFT
backplane
semiconductor
display
fab.
An
active‐matrix
imager
an
ultralow
detection
limit
can
reproduce
ideal
image
quality
under
ultra‐low
light
intensity
nW
cm
−2
level.
Advanced Optical Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 17, 2025
Abstract
Stability
is
crucial
for
the
practical
applications
of
organic
photodetectors
(OPDs).
In
this
work,
it
reported
that
near‐infrared
(NIR)
OPDs
without
device
encapsulation
can
exhibit
excellent
stability
at
ambient
conditions.
The
unencapsulated
a
T
90
lifetime,
which
defined
as
time
required
responsivity
to
decay
90%
its
initial
value,
exceeding
1000
h
conditions
under
600
lux
light
irradiation.
attributed
all‐fused‐ring
skeleton
acceptor
in
active
layer
and
hydrophobicity
crosslinked
cathode
interlayer.
addition,
specific
detectivity
1.65
×
10
13
Jones
920
nm
−0.1
V
bias,
among
highest
so
far
NIR
OPDs.
This
work
demonstrates
promising
future
applications.